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Recycling of poly(ethylene terephthalate) as polymer-polymer composites (*).(Abstract): An article from: Polymer Engineering and Science


by M. Evstatiev, S. Fakirov, B. Krasteva, K. Friedrich, J.A. Covas, A.M. Cunha

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Studio: Society of Plastics Engineers, Inc.
Binding: Digital
Publication Date: April 01, 2002
Publisher: Society of Plastics Engineers, Inc.


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This digital document is an article from Polymer Engineering and Science, published by Society of Plastics Engineers, Inc. on April 1, 2002. The length of the article is 5431 words. The page length shown above is based on a typical 300-word page. The article is delivered in HTML format and is available in your Amazon.com Digital Locker immediately after purchase. You can view it with any web browser.

From the author: Microfibrillar reinforced composites (MFC) comprising an isotropic matrix from a lower melting polymer reinforced by microfibrils of a higher melting polymer were manufactured under industrially relevant conditions and processed via injection molding. Low density polyethylene (LDPE) (matrix) and recycled poly(ethylene terephthalate) (PET) (reinforcing material) from bottles were melt blended (in 30/70 and 50/50 PET/LDPE wt ratio) and extruded, followed by continuous drawing, pelletizing and injection molding of dogbone samples. Samples of each stage of MFC manufacturing and processing were characterized by means of scanning electron microscopy (SEM). wide-angle X-ray scattering (WAXS), dynamic mechanical thermal analysis (DMTA), and mechanical testing. SEM and WAXS showed that the extruded blend is isotropic but becomes highly oriented after drawing, being converted into a polymer-polymer composite upon injection molding at temperatures below the melting temperature of PET. This MFC is characterized by an iso tropic LDPE matrix reinforced by randomly distributed PET microfibrils, as concluded from the WAXS patterns and SEM observations. The MFC dogbone samples show impressive mechanical properties--the elastic modulus is about 10 times higher than that of LDPE and about three times higher than reinforced LDPE with glass spheres, approaching the modulus of LDPE reinforced with 30 wt% short-glass fibers (GF). The tensile strength is at least two times higher than that of LDPE or of reinforced LDPE with glass spheres, approaching that of reinforced LDPE with 30 wt% GF. The impact strength of LDPE increases by 50% after reinforcement with PET. It is concluded that: (i) the MEC approach can be applied in industrially relevant conditions using various blend partners, and (ii) the MFC concept represents an attractive alternative for recycling of PET as well as other polymers.

Citation Details
Title: Recycling of poly(ethylene terephthalate) as polymer-polymer composites (*).(Abstract)
Author: M. Evstatiev
Publication: Polymer Engineering and Science (Refereed)
Date: April 1, 2002
Publisher: Society of Plastics Engineers, Inc.
Volume: 42 Issue: 4 Page: 826(10)

Article Type: Abstract

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