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| View Larger Image | A cobalt(II)-selective PVC membrane based on a Schiff base complex of N,N'-bis(salicylidene)-3,4-diaminotoluene [An article from: Analytica Chimica Acta]
by V.K. Gupta, A.K. Singh, S. Mehtab, B. Gupta
| | List Price: | $10.95 |  | | Available: | Available for download now | | | | | Studio: | Elsevier | | | Binding: | Digital | | Number Of Pages: | 5 | | Publication Date: | April 27, 2006 | | Publisher: | Elsevier |
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Product Description
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description:
A new PVC membrane electrode for Co^2^+ based on N,N'-bis(salicylidene)-3,4-diaminotoluene, an excellent neutral carrier, has been fabricated using sodium tetraphenylborate (NaTPB) as an anionic excluder and dioctylphthalte (DOP) as a solvent mediator. The electrode exhibits a linear potential response in the concentration range of 7.9x10^-^8 to 1.0x10^-^1M with a slope of 30+/-0.2mV per decade. The detection limit of the proposed sensor is 5.0x10^-^8M and it can be used over a period of 5 months. The proposed sensor revealed good selectivity over a wide variety of other cations including alkali, alkaline earth, heavy and transition metals and could be used in the pH range of 2.0-9.0. This electrode was successfully applied for the determination of Co^2^+in real samples and as an indicator electrode in potentiometric titration of cobalt ions. |
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