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Tributyltin partitioning in sediments: Effect of aging [An article from: Chemosphere]
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Tributyltin partitioning in sediments: Effect of aging [An article from: Chemosphere] | Digital

by E.D. Burton (Author), I.R. Phillips (Author), D.W. Hawker (Author)

List Price: $8.95  
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Binding:  Digital
Publisher:  Elsevier


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This digital document is a journal article from Chemosphere, published by Elsevier in . The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.Description: The effect of aging on the solid/pore-water partitioning and desorption behaviour of tributyltin (TBT) in sediments was examined. Three sediment samples with contrasting physical and chemical properties were spiked with 10mg/kg TBT and aged under sterile conditions for periods of time ranging from 1 to 84 days. Aging had a negligible effect on partitioning and desorption behaviour in a sandy sample with very low organic carbon content (0.2% w/w). In contrast, for samples with larger amounts of organic carbon (2.6% and 4.8% w/w), aging caused substantial increases in TBT sorption. For these samples, apparent distribution coefficients (K"D","a"p"p) obtained from sequential 2h desorption experiments also exhibited a twofold increase between spiked sediments subjected to aging for 1 day and 84 days. This study demonstrates that aging effects may be an important aspect of TBT fate in contaminated sediments.
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