Method could help carbon nanotubes become commercially viableOctober 05, 2006EVANSTON, Ill. - Carbon nanotubes are intriguing new materials which have been highly touted for their exceptional mechanical, thermal, optical and electrical properties. Researchers worldwide are striving to apply these nanostructures in electronics, high-resolution displays, high-strength composites and biosensors. A fundamental problem relating to their synthesis, however, has limited their widespread use. Current methods for synthesizing carbon nanotubes produce mixtures of tubes that differ in their diameter and twist. Variations in electronic properties arise from these structural differences, resulting in carbon nanotubes that are unsuitable for most proposed applications. Now, a new method developed at Northwestern University for sorting single-walled carbon nanotubes promises to overcome this problem. The method works by exploiting subtle differences in the buoyant densities of carbon nanotubes as a function of their size and electronic behavior. The results will be published online Wednesday, Oct. 4, in the inaugural issue of the journal Nature Nanotechnology (October 2006). "Carbon nanotubes, because of their ultra-small size and excellent materials properties, have excited the scientific community for the last decade," said Mark Hersam, professor of materials science and engineering at Northwestern's McCormick School of Engineering and Applied Science, who led the research team. "However, due to their inherent heterogeneity, they have not yet realized their full commercial potential," he said. "A scalable and economical method for producing monodisperse carbon nanotubes will enable the proposed applications for these nanomaterials to be explored at an industrially relevant scale." Using the Northwestern method, carbon nanotubes first are encapsulated in water by soap-like molecules called surfactants. Next, the surfactant-coated nanotubes are sorted in density gradients which are spun at tens of thousands of rotations per minute in an ultracentrifuge. By carefully choosing the surfactants utilized during ultracentrifugation, the researchers found that carbon nanotubes could be sorted by diameter and electronic structure. As a part of their study, the researchers demonstrated the fabrication of electrical devices that displayed either semiconducting or metallic behavior, depending on the sorted nanotubes used. The researchers also maintain that their technique can be translated to an industrial scale. "The technique is especially promising for commercial applications," said Hersam, "because large-scale ultracentrifuges have already been developed and shown to be economically viable in the pharmaceutical industry. We anticipate that this precedent can be straightforwardly translated to the production of monodisperse carbon nanotubes." Northwestern University |
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| Related Carbon Nanotubes Current Events and Carbon Nanotubes News Articles Caltech scientists develop DNA origami nanoscale breadboards for carbon nanotube circuits In work that someday may lead to the development of novel types of nanoscale electronic devices, an interdisciplinary team of researchers at the California Institute of Technology (Caltech) has combined DNA's talent for self-assembly with the remarkable electronic properties of carbon nanotubes, thereby suggesting a solution to the long-standing problem of organizing carbon nanotubes into nanoscale electronic circuits. Breakthrough in industrial-scale nanotube processing Rice University scientists today unveiled a method for the industrial-scale processing of pure carbon-nanotube fibers that could lead to revolutionary advances in materials science, power distribution and nanoelectronics. Next-generation microcapsules deliver 'chemicals on demand' Scientists in California are reporting development of a new generation of the microcapsules used in carbon-free copy paper, in which capsules burst and release ink with pressure from a pen. Study shows how carbon nanotubes can affect lining of the lungs Carbon nanotubes are being considered for use in everything from sports equipment to medical applications, but a great deal remains unknown about whether these materials cause respiratory or other health problems. Advance in 'nano-agriculture': Tiny stuff has huge effect on plant growth With potential adverse health and environmental effects often in the news about nanotechnology, scientists in Arkansas are reporting that carbon nanotubes (CNTs) could have beneficial effects in agriculture. A recipe for controlling carbon nanotubes Nanoscopic tubes made of a lattice of carbon just a single atom deep hold promise for delivering medicines directly to a tumor, sensors so keen they detect the arrival or departure of a single electron, a replacement for costly platinum in fuel cells or as energy‐saving transistors and wires. Friction force differences could offer a new means for sorting and assembling nanotubes Nanotubes and nanowires are promising building blocks for future integrated nanoelectronic and photonic circuits, nanosensors, interconnects and electro-mechanical nanodevices. But some fundamental issues remain to be resolved - among them, how to position and manipulate the tiny tubes. New biosensor can detect bacteria instantaneously A research group from the Rovira i Virgili University (URV) in Tarragona has developed a biosensor that can immediately detect very low levels of Salmonella typhi, the bacteria that causes typhoid fever. Researchers design new graphene-based, nano-material with magnetic properties An international team of researchers has designed a new graphite-based, magnetic nano-material that acts as a semiconductor and could help material scientists create the next generation of electronic devices like microchips. Researchers Pinpoint Neural Nanoblockers in Carbon Nanotubes A team of Brown University scientists has pinpointed why carbon nanotubes tend to block a critical signaling pathway in neurons. More Carbon Nanotubes Current Events and Carbon Nanotubes News Articles |
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