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Genetically engineered blood protein can be used to split water into oxygen and hydrogen
December 01, 2006Scientists have combined two molecules that occur naturally in blood to engineer a molecular complex that uses solar energy to split water into hydrogen and oxygen, says research published today in the Journal of the American Chemical Society.
This molecular complex can use energy from the sun to create hydrogen gas, providing an alternative to electrolysis, the method typically used to split water into its constituent parts. The breakthrough may pave the way for the development of novel ways of creating hydrogen gas for use as fuel in the future.
Professors Tsuchida and Komatsu from Waseda University, Japan, in collaboration with Imperial College London, synthesised a large molecular complex from albumin, a protein molecule that is found at high levels in blood serum, and porphyrin, a molecule which is used to carry oxygen around the body and gives blood its deep red colour. Porphyrin molecules are normally found combined with metals, and in their natural state in the blood they have an iron atom at their centre. The scientists modified the porphyrin molecule to swap the iron for a zinc atom in the middle, which completely changed the chemistry and characteristics of the molecule.
This modified porphyrin molecule was then combined with albumin; with the albumin molecule itself being modified by genetic engineering to enhance the efficiency of the process. The resulting molecular complex was proven to be sensitive to light, and can capture light energy in a way that allows water molecules to be split into molecules of hydrogen and oxygen.
Dr Stephen Curry, a structural biologist from Imperial College London's Division of Cell and Molecular Biology who participated in the research explains: "This work has shown that it is possible to manipulate molecules and proteins that occur naturally in the human body by changing one small detail of their make-up, such as the type of metal at the heart of a porphyrin molecule, as we did in this study.
"It's very exciting to prove that we can use these biological structures as a conduit to harness solar energy to separate water out into hydrogen and oxygen. In the long term, these synthetic molecules may provide a more environmentally friendly way of producing hydrogen, which can be used as a 'green' fuel.\\\
Imperial College London
This modified porphyrin molecule was then combined with albumin; with the albumin molecule itself being modified by genetic engineering to enhance the efficiency of the process. The resulting molecular complex was proven to be sensitive to light, and can capture light energy in a way that allows water molecules to be split into molecules of hydrogen and oxygen.
Dr Stephen Curry, a structural biologist from Imperial College London's Division of Cell and Molecular Biology who participated in the research explains: "This work has shown that it is possible to manipulate molecules and proteins that occur naturally in the human body by changing one small detail of their make-up, such as the type of metal at the heart of a porphyrin molecule, as we did in this study.
"It's very exciting to prove that we can use these biological structures as a conduit to harness solar energy to separate water out into hydrogen and oxygen. In the long term, these synthetic molecules may provide a more environmentally friendly way of producing hydrogen, which can be used as a 'green' fuel.\\\
Imperial College London
Hydrogen Current Events and Hydrogen News RSSWPI Researchers Take Aim at Hard-to-Treat Fungal Infections
A team of researchers at the Worcester Polytechnic Institute (WPI) Life Sciences and Bioengineering Center at Gateway Park has developed a new model system to study fungal infections.
Proton's party pals may alter its internal structure
A recent experiment at the Department of Energy's Thomas Jefferson National Accelerator Facility has found that a proton's nearest neighbors in the nucleus of the atom may modify the proton's internal structure.
Berkeley Researchers Take the Lead Out of Piezoelectrics
There is good news for the global effort to reduce the amount of lead in the environment and for the growing array of technologies that rely upon the piezoelectric effect.
Vibrations key to efficiency of green fluorescent protein
University of California, Berkeley, chemists have discovered the secret to the success of a jellyfish protein whose green glow has made it the darling of biologists and the subject of the 2008 Nobel Prize in Physiology or Medicine.
Earth's early ocean cooled more than a billion years earlier than thought: Stanford study
The scalding-hot sea that supposedly covered the early Earth may in fact never have existed, according to a new study by Stanford University researchers who analyzed isotope ratios in 3.4 billion-year-old ocean floor rocks.
UT Knoxville and ORNL researchers turn algae into high-temperature hydrogen source
In the quest to make hydrogen as a clean alternative fuel source, researchers have been stymied about how to create usable hydrogen that is clean and sustainable without relying on an intensive, high-energy process that outweighs the benefits of not using petroleum to power vehicles.
Central Africa's tropical Congo Basin was arid, treeless in Late Jurassic
The Congo Basin - with its massive, lush tropical rain forest - was far different 150 million to 200 million years ago. At that time Africa and South America were part of the single continent Gondwana.
Engineers image nanostructure of a solid acid catalyst and boost its catalytic activity
The catalytic processes that facilitate the production of many chemicals and fuels could become much more environmentally friendly thanks to a breakthrough achieved by researchers from Lehigh and Rice Universities.
'Dropouts' pinpoint earliest galaxies
Astronomers, conducting the broadest survey to date of galaxies from about 800 million years after the Big Bang, have found 22 early galaxies and confirmed the age of one by its characteristic hydrogen signature at 787 million years post Big Bang.
Computer predicts reactions between molecules and surfaces, with 'chemical precision'
Good news for heterogeneous catalysis and the hydrogen economy: computers can now be used to make accurate predictions of the reactions of (hydrogen) molecules with surfaces. An international team of researchers, headed by Leiden theoretical chemist Geert-Jan Kroes, published on this subject this week in the journal Science.
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