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The longest carbon nanotubes you've ever seen
May 11, 2007Crafted with breakthrough manufacturing technique, centimeter-long fibers are visible to the naked eye
Using techniques that could revolutionize manufacturing for certain materials, researchers have grown carbon nanotubes that are the longest in the world. While still slightly less than 2 centimeters long, each nanotube is 900,000 times longer than its diameter.
The fibers--which have the potential to be longer, stronger and better conductors of electricity than copper and many other materials--could ultimately find use in smart fabrics, sensors and a host of other applications.
To grow the aligned bundles of tiny tubes, the researchers combined advantages of chemical vapor deposition (CVD), a technique for creating thin coatings that is especially common in the semiconductor industry, with a novel substrate and catalyst onto which the carbon attaches.
Supported by the National Science Foundation (NSF) and the Office of Naval Research, University of Cincinnati (UC) professors Vesselin Shanov and Mark Schulz collaborated with post-doctoral researcher Yun Yeo Heung and students to develop the technique.
The researchers partnered with First Nano, a division of CVD Equipment Corp. of Ronkonkoma, N.Y., to use their laboratory and a specialized furnace called the EasyTube 3000. With the equipment, the researchers were able to break apart hydrocarbons to create a vapor of carbon-atom starting material. Within the vapor sat the new substrate--a catalyst made of alternating metal and ceramic layers atop an oxidized-silicon wafer base--which served as the foundation for growth.
"This process is revolutionary because it allows us to keep the catalyst 'alive' for a long period of time thus, providing fast and continuous transport of the carbon 'building blocks' to the carbon nanotube growth zone," said Shanov.
The carbon nanotubes are extremely long compared to predecessors--the longest is 3 millimeters beyond the prior world record. More important for manufacturing, the research team grew a 12-millimeters-thick, uniform carpet of aligned carbon nanotubes on a roughly 10-centimeter silicon substrate, opening the door for scaling-up the process.
The inventions were presented in April 2007 at the Single Wall Carbon Nanotube Nucleation and Growth Mechanisms workshop organized by NASA and Rice University. The research was supported by NSF grant 0510823, in addition to support from the Office of Naval Research through North Carolina A&T SU.
National Science Foundation
To grow the aligned bundles of tiny tubes, the researchers combined advantages of chemical vapor deposition (CVD), a technique for creating thin coatings that is especially common in the semiconductor industry, with a novel substrate and catalyst onto which the carbon attaches.
Supported by the National Science Foundation (NSF) and the Office of Naval Research, University of Cincinnati (UC) professors Vesselin Shanov and Mark Schulz collaborated with post-doctoral researcher Yun Yeo Heung and students to develop the technique.
The researchers partnered with First Nano, a division of CVD Equipment Corp. of Ronkonkoma, N.Y., to use their laboratory and a specialized furnace called the EasyTube 3000. With the equipment, the researchers were able to break apart hydrocarbons to create a vapor of carbon-atom starting material. Within the vapor sat the new substrate--a catalyst made of alternating metal and ceramic layers atop an oxidized-silicon wafer base--which served as the foundation for growth.
"This process is revolutionary because it allows us to keep the catalyst 'alive' for a long period of time thus, providing fast and continuous transport of the carbon 'building blocks' to the carbon nanotube growth zone," said Shanov.
The carbon nanotubes are extremely long compared to predecessors--the longest is 3 millimeters beyond the prior world record. More important for manufacturing, the research team grew a 12-millimeters-thick, uniform carpet of aligned carbon nanotubes on a roughly 10-centimeter silicon substrate, opening the door for scaling-up the process.
The inventions were presented in April 2007 at the Single Wall Carbon Nanotube Nucleation and Growth Mechanisms workshop organized by NASA and Rice University. The research was supported by NSF grant 0510823, in addition to support from the Office of Naval Research through North Carolina A&T SU.
National Science Foundation
Carbon Nanotubes Current Events and Carbon Nanotubes News RSSEmpa scientists synthesize graphene-like material
Two-dimensional carbon layers, so-called graphenes, are regarded as a possible substitute for silicon in the semiconductor industry.
Caltech scientists develop DNA origami nanoscale breadboards for carbon nanotube circuits
In work that someday may lead to the development of novel types of nanoscale electronic devices, an interdisciplinary team of researchers at the California Institute of Technology (Caltech) has combined DNA's talent for self-assembly with the remarkable electronic properties of carbon nanotubes, thereby suggesting a solution to the long-standing problem of organizing carbon nanotubes into nanoscale electronic circuits.
Breakthrough in industrial-scale nanotube processing
Rice University scientists today unveiled a method for the industrial-scale processing of pure carbon-nanotube fibers that could lead to revolutionary advances in materials science, power distribution and nanoelectronics.
Next-generation microcapsules deliver 'chemicals on demand'
Scientists in California are reporting development of a new generation of the microcapsules used in carbon-free copy paper, in which capsules burst and release ink with pressure from a pen.
Study shows how carbon nanotubes can affect lining of the lungs
Carbon nanotubes are being considered for use in everything from sports equipment to medical applications, but a great deal remains unknown about whether these materials cause respiratory or other health problems.
Advance in 'nano-agriculture': Tiny stuff has huge effect on plant growth
With potential adverse health and environmental effects often in the news about nanotechnology, scientists in Arkansas are reporting that carbon nanotubes (CNTs) could have beneficial effects in agriculture.
A recipe for controlling carbon nanotubes
Nanoscopic tubes made of a lattice of carbon just a single atom deep hold promise for delivering medicines directly to a tumor, sensors so keen they detect the arrival or departure of a single electron, a replacement for costly platinum in fuel cells or as energy‐saving transistors and wires.
Friction force differences could offer a new means for sorting and assembling nanotubes
Nanotubes and nanowires are promising building blocks for future integrated nanoelectronic and photonic circuits, nanosensors, interconnects and electro-mechanical nanodevices. But some fundamental issues remain to be resolved - among them, how to position and manipulate the tiny tubes.
New biosensor can detect bacteria instantaneously
A research group from the Rovira i Virgili University (URV) in Tarragona has developed a biosensor that can immediately detect very low levels of Salmonella typhi, the bacteria that causes typhoid fever.
Researchers design new graphene-based, nano-material with magnetic properties
An international team of researchers has designed a new graphite-based, magnetic nano-material that acts as a semiconductor and could help material scientists create the next generation of electronic devices like microchips.
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