'Electrospray' droplet research yields surprising, practical resultsJanuary 08, 2008Chemical engineers at Purdue University are the first to mathematically describe precisely how droplets form when liquids are exposed to electric fields, an advance that could have applications in areas ranging from manufacturing to medical diagnostics. The technique of using small droplets created by subjecting liquids to electric fields is vital for a variety of applications, from a type of industrial painting called electrospraying, to a method for analyzing molecules in analytical chemistry, to manufacturing tiny micro- and nanoparticles for research and industry. "Despite its importance, industry doesn't really understand exactly how the drops form," said Osman Basaran, the Reilly Professor of Fluid Mechanics in Purdue's School of Chemical Engineering. New findings showed that a liquid's viscosity plays a vital role in drop formation and size, a discovery that contradicts conventional wisdom, Basaran said. The researchers first created simulations to describe droplet formation mathematically, and then they performed experiments to support the computational work. "Computational simulations are now making it possible to understand such phenomena," he said. "But you always want to back up simulations with experimental data if at all possible." The findings are detailed in a paper appearing in the January issue of Nature Physics. The paper was written by doctoral student Robert T. Collins, undergraduate student Jeremy J. Jones, professor Michael T. Harris, and Basaran, all in the School of Chemical Engineering. Researchers have known for decades that applying an electric field to liquid drops causes the formation of structures that have a perfect cone at the leading edge. "Each drop takes on the shape of a chocolate kiss," Basaran said. Then, a thin ribbonlike strand of fluid is emitted from the leading edge of the droplet and breaks up into smaller droplets. "This was discovered about a century ago," Basaran said. "Nobody could really show precisely how it happened, but technologically it became very important." The method could make possible future technologies for creating flexible electronic circuits and solar cells by spraying material in ultra-thin layers. "Making small drops and controlling drop size is a big deal, and there are many techniques that people are working on to be able to model these computationally or theoretically," Basaran said. "There are many applications that would benefit by knowing the drop size. You cannot predict the drop sizes unless you have simulations to tell you how the strand is going to develop and break up into little droplets." The same phenomenon occurs in rain clouds. As rain droplets pick up an electrical charge, they take on an elongated football shape. Thin strands form at each end of the football, and those strands, in turn, form small droplets. "Again, the ends shoot these little strands or jets, which break up into drops," Basaran said. "And this has been suspected for a century to play a major role in how thunderstorms work." Understanding how the drops form is difficult because the strands are many times thinner than the original liquid from which they formed, which makes the mathematics especially challenging. "Others had not solved these equations in their full form before because they are very difficult, and we have now solved them without any approximations," Basaran said. Conventional modeling methods use "diffuse interface" techniques, which do not precisely predict how the strands and droplets form, he said. The Purdue researchers used a more precise method called finite elements with elliptic mesh generation. The technique breaks down a material into many small segments and solves the mathematical equations governing the behavior of each segment separately. Using the method enables researchers to understand the dynamic, changing shapes of each segment making up the drop-forming strands and the droplets. The technique allowed the engineers to negotiate the dramatic size differences between the strands and original liquid, a process that falls in the realm of "multi-scale modeling." "Our approach allowed us to do this multi-scale modeling in one big calculation," Basaran said. In the experiments, an electric voltage was applied to a small metal rod positioned about an inch from a puddle of liquid. The liquid was pulled toward the tip of the rod and took on a conical appearance. Strands of liquid, which subsequently broke into droplets, were then emitted from the liquid cone. The Purdue researchers conducted experiments using liquids with large viscosities, including those similar to fuels, whereas past research has concentrated on lower viscosity fluids like water. "This may prove to be important in combustion applications because fuel is sprayed into engine cylinders using fuel injectors," Basaran said. "We studied higher viscosity fluids to see the effect of viscosity, which other people had never seen before. It turns out that the viscosity actually has a big effect on droplet size." Future research will continue to study how droplet formation is influenced by other characteristics of a liquid. These characteristics include the electrical conductivity of fluids and the surface tension, the latter being responsible for the beading of water droplets on a recently waxed car. "We are just scratching the surface because there is such a large range of viscosities and other characteristics of fluids that affect droplet formation and size," Basaran said. "There could be many surprises." The research has been funded by the U.S. Department of Energy. Purdue University |
|||||||||||||||||||||
| Related Droplets Current Events and Droplets News Articles Tiny bubbles clean oil from water Small amounts of oil leave a fluorescent sheen on polluted water. Oil sheen is hard to remove, even when the water is aerated with ozone or filtered through sand. New paper describes connections between Circadian and metabolic systems A paper by University of Notre Dame biologist Giles Duffield and a team of researchers offers new insights into a gene that plays a key role in modulating the body's Circadian system and may also simultaneously modulate its metabolic system. Climate studies to benefit from 12 years of satellite aerosol data Aerosols, very small particles suspended in the air, play an important role in the global climate balance and in regulating climate change. New American Chemical Society podcast: Tiny sea creature and a new medical adhesive Scientists questing after a long-sought new medical adhesive describe copying the natural glue secreted by a tiny sea creature called the sandcastle worm in the latest episode in the American Chemical Society's (ACS) award-winning podcast series, "Global Challenges/Chemistry Solutions." Mushrooms, water-repellants more similar than you might think What do spore-launching mushrooms have in common with highly water-repellant surfaces? The lotus's clever way of staying dry An ancient Confucian philosopher once said, "I love the lotus because while growing from mud, it is unstained." Synthetic cells shed biological insights while delivering battery power Trying to understand the complex workings of a biological cell by teasing out the function of every molecule within it is a daunting task. Caltech scientists solve decade-long mystery of nanopillar formations Scientists at the California Institute of Technology (Caltech) have uncovered the physical mechanism by which arrays of nanoscale (billionths-of-a-meter) pillars can be grown on polymer films with very high precision, in potentially limitless patterns. Redefining obesity's health risks The body mass index (BMI) has long been the yardstick in deciding who is at risk because of their weight. BMI is essentially a measure of density, identifying 'under-' and 'over-weight' risk groups. Simulation suggests rocky exoplanet has bizarre atmosphere So accustomed are we to the sunshine, rain, fog and snow of our home planet that we find it next to impossible to imagine a different atmosphere and other forms of precipitation. More Droplets Current Events and Droplets News Articles |
|||||||||||||||||||||
|
|||||||||||||||||||||
|
|||||||||||||||||||||