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Organic electronics a two-way street, thanks to new plastic semiconductor
August 18, 2009Plastic that conducts electricity holds promise for cheaper, thinner and more flexible electronics. This technology is already available in some gadgets -- the new Sony walkman that was introduced earlier this summer and the Microsoft Zune HD music player released last week both incorporate organic light-emitting electronic displays.
Until now, however, circuits built with organic materials have allowed only one type of charge to move through them. New research from the University of Washington makes charges flow both ways. The cover article in an upcoming issue of the journal Advanced Materials describes an approach to organic electronics that allows transport of both positive and negative charges.
"The organic semiconductors developed over the past 20 years have one important drawback. It's very difficult to get electrons to move through," said lead author Samson Jenekhe, a UW professor of chemical engineering. "By now having polymer semiconductors that can transmit both positive and negative charges, it broadens the available approaches. This would certainly change the way we do things."
Co-authors are Felix Kim, a doctoral student working with Jenekhe, and graduate student Xugang Guo and assistant professor Mark Watson at the University of Kentucky. The research was funded by the National Science Foundation, the Department of Energy and the Ford Foundation.
Silicon Valley got its name for a reason: Silicon is the "workhorse" of today's electronics industry, Jenekhe said. Silicon is fairly expensive and requires costly manufacturing, however, and because its rigid crystal form does not allow flexible devices.
About 30 years ago it was discovered that some plastics, or polymers, can conduct electricity. Since then researchers have been working to make them more efficient. Organic, or carbon-based, electronics are now used in such things as laptop computers, car audio systems and mp3 players.
A major drawback with existing organic semiconductors is most transmit only positive charges (called "holes" because the moving areas of positive charge are actually places where an electron is missing). In the last decade a few organic materials have been developed that can transport only electrons. But making a working organic circuit has meant carefully layering two complicated patterns on top of one another, one that transports electrons and another one that transports holes.
"Because current organic semiconductors have this limitation, the way they're currently used has to compensate for that, which has led to all kinds of complex processes and complications," Jenekhe said.
For more than a decade Jenekhe's lab has been a leader in developing organic semiconductors that can transmit electrons. Over the past few years the group has created polymers with a donor and an acceptor part, and carefully adjusted the strength of each one. In collaboration with Watson's lab, they have now developed an organic molecule that works to transport both positive and negative charges.
"What we have shown in this paper is that you don't have to use two separate organic semiconductors," Jenekhe said. "You can use one material to create electronic circuits."
The material would allow organic transistors and other information-processing devices to be built more simply, in a way that is more similar to how inorganic circuits are now made.
The group used the new material to build a transistor designed in the same way as a silicon model and the results show that both electrons and holes move through the device quickly.
The results represent the best performance ever seen in a single-component organic polymer semiconductor, Jenekhe said. Electrons moved five to eight times faster through the UW device than in any other such polymer transistor. A circuit, which consists of two or more integrated devices, generated a voltage gain two to five times greater than previously seen in a polymer circuit.
"We expect people to use this approach," Jenekhe said. "We've opened the way for people to know how to do it."
University of Washington
Co-authors are Felix Kim, a doctoral student working with Jenekhe, and graduate student Xugang Guo and assistant professor Mark Watson at the University of Kentucky. The research was funded by the National Science Foundation, the Department of Energy and the Ford Foundation.
Silicon Valley got its name for a reason: Silicon is the "workhorse" of today's electronics industry, Jenekhe said. Silicon is fairly expensive and requires costly manufacturing, however, and because its rigid crystal form does not allow flexible devices.
About 30 years ago it was discovered that some plastics, or polymers, can conduct electricity. Since then researchers have been working to make them more efficient. Organic, or carbon-based, electronics are now used in such things as laptop computers, car audio systems and mp3 players.
A major drawback with existing organic semiconductors is most transmit only positive charges (called "holes" because the moving areas of positive charge are actually places where an electron is missing). In the last decade a few organic materials have been developed that can transport only electrons. But making a working organic circuit has meant carefully layering two complicated patterns on top of one another, one that transports electrons and another one that transports holes.
"Because current organic semiconductors have this limitation, the way they're currently used has to compensate for that, which has led to all kinds of complex processes and complications," Jenekhe said.
For more than a decade Jenekhe's lab has been a leader in developing organic semiconductors that can transmit electrons. Over the past few years the group has created polymers with a donor and an acceptor part, and carefully adjusted the strength of each one. In collaboration with Watson's lab, they have now developed an organic molecule that works to transport both positive and negative charges.
"What we have shown in this paper is that you don't have to use two separate organic semiconductors," Jenekhe said. "You can use one material to create electronic circuits."
The material would allow organic transistors and other information-processing devices to be built more simply, in a way that is more similar to how inorganic circuits are now made.
The group used the new material to build a transistor designed in the same way as a silicon model and the results show that both electrons and holes move through the device quickly.
The results represent the best performance ever seen in a single-component organic polymer semiconductor, Jenekhe said. Electrons moved five to eight times faster through the UW device than in any other such polymer transistor. A circuit, which consists of two or more integrated devices, generated a voltage gain two to five times greater than previously seen in a polymer circuit.
"We expect people to use this approach," Jenekhe said. "We've opened the way for people to know how to do it."
University of Washington
Organic Semiconductors Current Events and Organic Semiconductors News RSSUGA researchers achieve breakthrough in effort to develop tiny biological fuel cells
University of Georgia researchers have developed a successful way to grow molecular wire brushes that conduct electrical charges, a first step in developing biological fuel cells that could power pacemakers, cochlear implants and prosthetic limbs. The journal Chemical Science calls the technique "a significant breakthrough for nanotechnology."
Bottoms up: Better organic semiconductors for printable electronics
Researchers from the National Institute of Standards and Technology (NIST) and Seoul National University (SNU) have learned how to tweak a new class of polymer-based semiconductors to better control the location and alignment of the components of the blend.
Toward plastic spin transistors
University of Utah physicists successfully controlled an electrical current using the "spin" within electrons - a step toward building an organic "spin transistor": a plastic semiconductor switch for future ultrafast computers and electronics.
Model for the assembly of advanced, single-molecule-based electronic components developed at Pitt
Researchers based at the University of Pittsburgh have created the best method so far of assembling wire-like structures only a single molecule wide, a significant step in science's increasing attempts to reduce the circuitry size of electronic devices to the single molecule scale and provide smaller, faster, and more energy efficient electronics.
UA Physicists Discover 'Super Crystals' in a Semiconductor
University of Arizona physicists have discovered that "super crystals" -- crystals which are hundreds to thousands times larger than conventional crystals -- exist in certain organic semiconducting solids.
Carnegie Mellon U. chemists advance organic semiconductor processing
Any machinist will tell you that a little grease goes a long way toward making a tool work better. And that may soon hold true for plastic electronics as well.
Sensor of plastic can be produced in a printing press
Electrochemical transistors made of plastic open myriad possibilities. Since both electrons and ions are active, they can function as a bridge between traditional electronics and biological systems. A new dissertation from Linköping University in Sweden describes a simple and inexpensive humidity sensor that can be manufactured in a printing press.
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