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Up-scale: Frequency converter enables ultra-high sensitivity infrared spectrometry
August 27, 2009
In what may prove to be a major development for scientists in fields ranging from forensics to quantum communications, researchers at the National Institute of Standards and Technology (NIST) have developed a new, highly sensitive, low-cost technique for measuring light in the near-infrared range. The technique can measure the spectrum of the specific wavelengths of near infrared light used widely in telecommunications as well as the very weak infrared light at single-photon levels given off by fragile biomaterials and nanomaterials. They described their results in a recent issue of Optics Express.* A single photon detector is the key device needed to build highly sensitive instruments for measuring spectra. For the past 30 years, scientists have made steady progress increasing the efficiency and sensitivity of visible and ultraviolet photon detectors while methods for detecting elusive single photons in the near-infrared (NIR) range have faltered. The methods presently in use are too static-laden, inefficient and slow, or depend on superconducting detectors, which require expensive, low-temperature operating environments. The NIST group, Lijun Ma, Oliver Slattery and Xiao Tang, wanted to develop a way to use existing detectors such as avalanche photodiode detectors (APD), which work very well for detecting visible light and are widely used, but are ineffective for the detection of NIR.
Their approach was to adapt a technique developed two years ago at NIST for quantum cryptography that "up converts" photons at one frequency to a higher frequency. The technique promotes the infrared photons up to the visible range using a strong, tunable laser. During the frequency conversion process, the narrow-band pump laser scans the infrared signal photons and converts only those that have the desired polarization and wavelength to visible light. Once converted to visible light, the signal photons are easily detected by commercially available APDs. According to Tang, the new system enables the measurement of spectra with sensitivity of more than 1,000 times that of common commercial optical spectral instruments.
"Our key achievement here was to reduce the noise, but our success would not have been possible without the many years of work by others in this field," says Tang. "We hope that our discovery will open doors for researchers studying diseases, pharmaceuticals, secure communications and even solving crimes. We are very excited to make this technology available to the larger scientific community."
National Institute of Standards and Technology (NIST)
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Fourier Transform Infrared Spectrometry (Chemical Analysis: A Series of Monographs on Analytical Chemistry and Its Applications)
by Peter Griffiths (Author), James A. De Haseth (Author)
A bestselling classic reference, now expanded and updated to cover the latest instrumentation, methods, and applications The Second Edition of Fourier Transform Infrared Spectrometry brings this core reference up to date on the uses of FT-IR spectrometers today. The book starts with an in-depth description of the theory and current instrumentation of FT-IR spectrometry, with full chapters devoted to signal-to-noise ratio and photometric accuracy. Many diverse types of sampling techniques and data processing routines, most of which can be performed on even the less expensive instruments, are then described. Extensively updated, the Second Edition: * Discusses improvements in optical components * Features a full chapter on FT...
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Chemical Infrared Fourier Transform Spectroscopy (Chemical Analysis)
by Peter R. Griffiths (Author)
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![Detection of volatile organic compounds by temperature-programmed desorption combined with mass spectrometry and Fourier transform infrared spectroscopy [An article from: Analytica Chimica Acta]](http://ecx.images-amazon.com/images/I/415FBN4EPVL._SL160_.jpg)
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Detection of volatile organic compounds by temperature-programmed desorption combined with mass spectrometry and Fourier transform infrared spectroscopy [An article from: Analytica Chimica Acta]
by R.A. Ketola (Author), J.T. Kiuru (Author), V. Tarkiainen (Author), Kokkonen (Author)
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in . The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description: A temperature-programmed desorption (TPD) device connected to a mass spectrometer was used to detect volatile organic compounds from air samples. The main aim was to develop an analytical method, by which both non-polar and polar organic components can be detected in the same run. In TPD, the adsorbed compounds are desorbed from the resin more slowly than in the conventional trapping techniques, such as purge-and-trap technique, in which the resin is flash-heated and the compounds are desorbed at the same time to a...
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![A method for determination of COD in a domestic wastewater treatment plant by using near-infrared reflectance spectrometry of seston [An article from: Analytica Chimica Acta]](http://ecx.images-amazon.com/images/I/415FBN4EPVL._SL160_.jpg)
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A method for determination of COD in a domestic wastewater treatment plant by using near-infrared reflectance spectrometry of seston [An article from: Analytica Chimica Acta]
by A.C. Sousa (Author), M.M.L.M. Lucio (Author), O.F.B. Neto (Author), Marcone (Author)
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2007. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description: This paper proposes a method for determination of chemical oxygen demand (COD) in domestic wastewater. The proposed method is based on near-infrared reflectance (NIRR) measurements of seston collected from wastewater samples by filtration. The analysis does not require any special reagent, catalyst or solvent. Inherent baseline and noise features present in NIRR spectra are removed by a Savitzky-Golay derivative procedure followed by wavelet denoising. The resulting wavelet approximation coefficients are used...
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ISO 13884:2003, Animal and vegetable fats and oils - Determination of isolated trans isomers by infrared spectrometry
by ISO/TC 34/SC 11 (Author)
ISO 13884:2003 specifies a method for the accurate determination of isolated trans bonds in natural or processed long-chain fatty acids, fatty acid esters and triglycerides with trans isomer levels greater than or equal to 5 %.The method is not applicable, or is applicable only with specific precautions, to fats and oils containing high levels (over 5 %) of conjugated unsaturation (e.g. tung oil); materials containing functional groups which modify the intensity of the C-H deformation about the trans double bond [e.g. castor oil containing ricinoleic acid or its geometrical isomer, ricinelaidic acid (12-hydroxy-9-octadecenoic acid)]; mixed triglycerides having long- and short-chain moieties (such as diacetostearin); or in general, any materials containing constituents which have...
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![A comparison of pyrolysis-gas chromatography-mass spectrometry and fourier transform infrared spectroscopy for the characterisation of automative paint ... [An article from: Analytica Chimica Acta]](http://ecx.images-amazon.com/images/I/415FBN4EPVL._SL160_.jpg)
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A comparison of pyrolysis-gas chromatography-mass spectrometry and fourier transform infrared spectroscopy for the characterisation of automative paint ... [An article from: Analytica Chimica Acta]
by D.T. Burns (Author), K.P. Doolan (Author)
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2005. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description: It has been shown that by using pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), it is possible to discriminate between a variety of base coat, solid paint and clear coat samples of automotive paints in commercial use from a wide range of car manufacturers. Some of the solid paints and clear coats were pairs of samples indistinguishable by fourier transform infrared spectroscopy (FT-IR).
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![Development of a simple and low cost device for vapour phase Fourier Transform Infrared spectrometry determination of ethanol in mouthwashes [An article from: Analytica Chimica Acta]](http://ecx.images-amazon.com/images/I/415FBN4EPVL._SL160_.jpg)
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Development of a simple and low cost device for vapour phase Fourier Transform Infrared spectrometry determination of ethanol in mouthwashes [An article from: Analytica Chimica Acta]
by S. Armenta (Author), F.A. Esteve-Turrillas (Author), G. Quintas (Author), Gar (Author)
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description: A new vapour phase manifold coupled with Fourier Transform Infrared (FTIR) spectroscopy was developed for ethanol determination in mouthwashes. Two microliters of samples were injected, without any previous pre-treatment into a reactor heated at 70^oC, and the vapour phase generated transported to the FTIR spectrometer using a carrier nitrogen flow of 6mlmin^-^1. FTIR spectra were continuously recorded, as a function of time, by accumulating two scans and employing 8cm^-^1 nominal resolution. Analytical...
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Practical Hints on Infrared Spectrometry with Particular Reference to Forensic Analysis
by M.J.De Faubert Maunder (Author)
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![Optimization of transmission near infrared spectrometry procedures for [An article from: Analytica Chimica Acta]](http://ecx.images-amazon.com/images/I/415FBN4EPVL._SL160_.jpg)
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Optimization of transmission near infrared spectrometry procedures for [An article from: Analytica Chimica Acta]
by S. Armenta (Author), S. Garrigues (Author), M. de la Guardia (Author)
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description: The use of different response functions to be optimized in the frame of the use of near infrared spectrometry for quality control of active principles in agrochemical formulations has been evaluated. Both, simple functions, based on parameters like sensitivity, repeatability, accuracy, signal to noise ratio, limit of detection or sample throughput, and a complex function, considering all the aforementioned aspects, were employed in the development of a new method for Iprodione determination in agrochemicals....
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ISO 16794:2003, Nuclear energy - Determination of carbon compounds and fluorides in uranium hexafluoride infrared spectrometry
by ISO/TC 85/SC 5 (Author)
ISO 16794: 2003 specifies a test method for the determination of hydrocarbons, chlorocarbons and partially or completely substituted halocarbons or halohydrocarbons contained as impurities in uranium hexafluoride (UF6) by infrared spectrometry.This method cannot be used for compounds giving IR rays with interference by UF6 (for example CF4).The test method is quantitative and applicable in the mole fraction from 0,000 1 % or 0,001 0 %, depending on the type of impurity, up to 0,100 %.The test method can also be used for the determination of hydrofluoric acid (HF) and several elements existing as fluorides; boron in BF3, silicon in SiF4, phosphorus in PF5, molybdenum in MoF6 and tungsten in WF6. This title may contain less than 24 pages of technical content.
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