Blue-light stride in perovskite-based LEDs

January 13, 2021

Researchers at Linköping University, Sweden, have developed efficient blue light-emitting diodes based on halide perovskites. "We are very excited about this breakthrough", says Feng Gao, professor at Linköping University. The new LEDs may open the way to cheap and energy-efficient illumination.

Illumination is responsible for approximately 20% of global electricity consumption, a figure that could be reduced to 5% if all light sources consisted of light-emitting diodes (LEDs). The blue-white LEDs currently in use, however, need complicated manufacturing methods and are expensive, which makes it more difficult to achieve a global transition.

LEDs manufactured from halide perovskites could be a cheaper and more eco-friendly alternative for both illumination and LED-based monitors. Perovskites are a family of semiconducting materials defined by their cubic crystal structure. They have good light-emitting properties and are easy to manufacture. Using elements from the halogen group, i.e. fluorine, chlorine, bromine and iodine, perovskites can be given properties that depend on the chemical composition of the crystal.

LEDs for green and red light have already been created with perovskites, but one colour, blue, has so far been lacking, making it impossible to achieve white light.

"Blue light is the key to bringing light-emitting perovskites to practical applications. Our most recent breakthrough is one step on the way", says Feng Gao, professor at the Department of Physics, Chemistry and Biology at Linköping University.

Feng Gao's research group, in collaboration with colleagues in Lund, Great Britain, Germany, China and Denmark, has managed to create halide perovskites that give stable emission in the wavelength range 451-490 nanometres - corresponding to deep blue to sky blue colours. Max Karlsson is doctoral student at Linköping University and joint first author of the article now published in Nature Communications. He says:

"Metal-halide perovskites are easily colour-tuneable over the whole visible spectrum by simple alloying. Unfortunately, they exhibit demixing and a blue LED turns green during operation. We have found a method that can prevent this colour shift by controlling the film crystallisation dynamics when creating the perovskite. These findings pave the way for stable perovskite alloys, not only for LEDs but also for solar cells."

The challenge of creating blue light in perovskites is that it requires a chemical composition with a large fraction of chloride, which makes the perovskite unstable. Blue perovskite-based LEDs have previously been created with using what is known as the "quantum confinement technique", which gives low-intensity LEDs with poor efficiency. However, stable perovskites with the desired amount of chloride can be created with the aid of the "vapour-assisted crystallisation technique". Furthermore, the Linköping University researchers have achieved an energy efficiency of up to 11% for the blue perovskite-based LEDs.

"We have shown that blue light-emitting diodes based on halide perovskites can be both efficient and stable across a broad spectrum, without using quantum confinement. We have managed to create one of the most efficient blue perovskite-based LEDs so far known", says Weidong Xu, postdoc at Linköping University.

The science of perovskites is a relatively new research field that has aroused major international interest, since it offers a great potential for developing cheap and efficient materials. Feng Gao, however, is quick to point out that the work they have done is basic research, and applications are still some way off in future.

"Perovskite LEDs are a young technology and have some way to go before they see the light of day. Currently, the short lifetime and poor performance of blue LEDs are the main obstacles for perovskite light-emitting diodes before they can start to compete with existing technologies such as light-emitting diodes based on organic and inorganic semiconductors. We will keep working on that to make PeLEDs comparable to the other technologies", says Feng Gao.
Sources of research finance include an ERC Starting Grant, the Swedish Research Council, the Swedish Energy Agency, and through the Swedish Strategic Research Area in Advanced Functional Materials (AFM) at Linköping University.

The article:

Mixed Halide Perovskites for Spectrally Stable and High-Efficiency Blue Light-Emitting Diodes
Max Karlsson, Ziyue Yi, Sebastian Reichert, Xiyu Luo, Weihua Lin, Zeyu Zhang, Chunxiong Bao, Rui Zhang, Sai Bai, Guanhaojie Zheng, Pengpeng Teng, Lian Duan, Yue Lu, Kaibo Zheng, Tönu Pullerits, Carsten Deibel, Weidong Xu, Richard Friend, and Feng Gao. Nature Communications 2021. DOI: 10.1038/s41467-020-20582-6

Linköping University

Related Energy Efficiency Articles from Brightsurf:

Customizable smart window technology could improve energy efficiency of buildings
Scientists combined solar cell technology with a novel optimization approach to develop a smart window prototype that maximizes design across a wide range of criteria.

Boosting energy efficiency of 2D material electronics using topological semimetal
SUTD researchers discover a new way to boost the energy efficiency of 2D semiconductor electronics by synergizing 2D materials and topological semimetals.

New 5G switch provides 50 times more energy efficiency than currently exists
As 5G hits the market, new US Army-funded research has developed a radio-frequency switch that is more than 50 times more energy efficient than what is used today.

Development of electrode material improving the efficiency of salinity gradient energy
Dr. Jeong Nam-Jo of Korea Institute of Energy Research(KIER) Marine Energy Convergence and Integration Research Team developed synthesis technologies of electrode material that can directly synthesize molybdenum disulfide thin films on the electrode current collector surface to contribute improving the efficiency and economic feasibility of salt gradient power generation using reverse electrodialysis.

Mandatory building energy audits alone do not overcome barriers to energy efficiency
A pioneering law may be insufficient to incentivize significant energy use reductions in residential and office buildings, a new study finds.

Towards a sustainable future -- Novel technology to measure energy conversion efficiency
Conversion of energy is a constant process but measuring the efficiency of this conversion is not an easy task.

How preprocessing methods affect the conversion efficiency of biomass energy production
Research on energy production from biomass usually focuses on the amount of energy generated.

Microgrids can help maximize efficiency of renewable energy consumption
A group of Italian researchers has developed a method that enables more efficient use of energy by smart homes that are connected to a microgrid -- a web of individualized units that are connected to one another and one common energy source.

Connection between home energy efficiency and respiratory health in low-income homes
A new study finds people living in drafty homes in low-income, urban communities are at a higher risk of respiratory health issues.

Merging antenna and electronics boosts energy and spectrum efficiency
By integrating the design of antenna and electronics, researchers have boosted the energy and spectrum efficiency for a new class of millimeter wave transmitters, allowing improved modulation and reduced generation of waste heat.

Read More: Energy Efficiency News and Energy Efficiency Current Events is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to