# Phase change in fluids finally simulated after decades of effort

January 17, 2006

Everyone knows what happens to water when it boils--everyone, that is, except computers. Modeling the transformation process of matter moving from one phase to another, such as from liquid to gas, has been all but impossible near the critical point. This is due to the increasingly complex way molecules behave as they approach the change from one phase to another. Researchers at the University of Rochester, however, have now created a mathematical model that will allow scientists to simulate and understand phase changes, which could have an impact on everything from decaffeinating coffee to improving fuel cell efficiency in automobiles of the future. The findings have been published in Physical Review Letters.

"This problem has baffled scientists for decades," says Yonathan Shapir, professor of physics and chemical engineering at the University of Rochester, and co-author of the paper. "This is the first time a computer program could simulate a phase transition because the computers would always bog down at what's known as the 'critical slowdown.' We figured out a way to perform a kind of end-run around that critical point slowdown and the results allow us to calculate certain critical point properties for the first time."

"Critical slowdown" is a phenomenon that happens as matter moves from one phase to another near the critical point. As molecules in a gas, for instance, are cooled, they lose some of their motion, but are still moving around and bumping into each other. As the temperature drops to where the gas will change into a liquid, the molecules' motion becomes correlated, or connected, across larger and larger distances. That correlation is a bit like deciding where to go to dinner--quick and easy with two people, but takes forever for a group of 20 to take action. The broadening correlation dramatically increases the time it takes for the gas to reach an overall equilibrium, and that directly leads to an increase in computing time required, approaching infinity and bogging down as the gas crosses the point of phase change.

To illustrate the effect, imagine a perfectly pure and still lake. If you drop a pebble into this lake, its ripples would spread outward, dissipating until the lake had returned to a calm equilibrium again. But, if you were to take this impossibly perfect lake just barely above the critical point and drop your pebble, the ripples would remain as ripples much longer--likely bouncing off the distant shores. This imaginary lake would take seemingly forever to return to its calm equilibrium again.

The research team of Shapir, Eldred Chimowitz, professor in the Department of Chemical Engineering, and physics graduate student Subhranil De created a novel approach to tackle the phase-change process. They devised a computational model consisting of two separate reservoirs of fluid at equilibrium and near the critical point threshold. One reservoir was slightly more pressurized than its neighbor. The reservoirs were opened to each other and the pressure difference caused the fluids to mix. The team let the simulation run until the entire system reached thermodynamic equilibrium. By watching the rate that equilibrium returned, the team was able to calculate the behavior at the critical point. Their simulation findings match predictions and experimental results, including very precise measurements performed in microgravity on the Space Shuttle.

"In principle, it's a difficult calculation," says Chimowitz. "Fluid systems require a different class of models than the common lattice models used by researchers who have studied dynamic critical behavior. These different classes give rise to different dynamic critical exponents and we found them, for the first time, in real fluid systems."

The best known examples of phase changes are perhaps water to ice and water to steam. Phase changes of many different physical types occur, however, such as the separation of a liquid mixture to its components, which should also abide by the Rochester team's results.

The team's simulation approach will likely be used by industry in a variety of ways, not the least of which will be to derive more power from a fuel cell. Since fuel cells rely on the transportation of protons through a membrane separating two electrodes, Shapir and Chimowitz believe it should be possible to use their work to find the most efficient configurations for a fuel cell. Other applications, such as removing the caffeine from coffee, work in a similar way and will likely also benefit.

Chimowitz also has just published a much-praised book about the subject, called Introduction to Critical Phenomena in Fluids from Oxford University Press. The book has been nominated for the Association of American Publishers' Award for Excellence in Professional and Scholarly Publishing.
-end-
This research was funded by a grant from the National Science Foundation.

University of Rochester

## Related Fuel Cell Articles from Brightsurf:

INRS researchers develop a new membraneless fuel cell
The research team of INRS (Institut national de la recherche scientifique) professor Mohamed Mohamedi has designed a green membraneless fuel cell that uses oxygen from the air.

Washington State University researchers have made a key advance in solid oxide fuel cells (SOFCs) that could make the highly energy-efficient and low-polluting technology a more viable alternative to gasoline combustion engines for powering cars.

Niobium used as catalyst in fuel cell
Glycerol fuel cell can replace batteries in cell phones and laptops, and could be used in future to run electric cars and supply power to homes.

Inside the fuel cell -- Imaging method promises industrial insight
Hydrogen-containing substances are important for many industries, but scientists have struggled to obtain detailed images to understand the element's behavior.

Selenium anchors could improve durability of platinum fuel cell catalysts
Researchers at the Georgia Institute of Technology have developed a new platinum-based catalytic system that is far more durable than traditional commercial systems and has a potentially longer lifespan.

Activity of fuel cell catalysts doubled
An interdisciplinary research team at the Technical University of Munich (TUM) has built platinum nanoparticles for catalysis in fuel cells: The new size-optimized catalysts are twice as good as the best process commercially available today.

More flexible nanomaterials can make fuel cell cars cheaper
A new method of increasing the reactivity of ultrathin nanosheets, just a few atoms thick, can someday make fuel cells for hydrogen cars cheaper, finds a new Johns Hopkins study.

Developed self-controlling 'smart' fuel cell electrode material
A research team led by Professor Kang Taek Lee in the Department of Energy Science and Engineering developed electrode material for a new form of high-performance solid oxide fuel cell.

Finally, a robust fuel cell that runs on methane at practical temperatures
Either exorbitantly expensive fuel or insanely hot temperatures have made fuel cells a boutique proposition, but now there's one that runs on cheap methane and at much lower temperatures.

New fuel cell concept brings biological design to better electricity generation
Fuel cells have long been viewed as a promising power source.

Read More: Fuel Cell News and Fuel Cell Current Events
Brightsurf.com is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to Amazon.com.