Nav: Home

Self-assembling nanomaterial offers pathway to more efficient, affordable harnessing of solar power

January 24, 2019

NEW YORK, January 24, 2019 - Solar rays are a plentiful, clean source of energy that is becoming increasingly important as the world works to shift away from power sources that contribute to global warming. But current methods of harvesting solar charges are expensive and inefficient--with a theoretical efficiency limit of 33 percent. New nanomaterials developed by researchers at the Advanced Science Research Center (ASRC) at The Graduate Center of The City University of New York (CUNY) could provide a pathway to more efficient and potentially affordable harvesting of solar energy.

The materials, created by scientists with the ASRC's Nanoscience Initiative, use a process called singlet fission to produce and extend the life of harvestable light-generated electrons. The discovery is described in a newly published paper in the Journal of Physical Chemistry. Early research suggests these materials could create more usable charges and increase the theoretical efficiency of solar cells up to 44 percent.

"We modified some of the molecules in commonly used industrial dyes to create self-assembling materials that facilitate a greater yield of harvestable electrons and extend the electrons' xcited-state lifetimes, giving us more time to collect them in a solar cell," said Andrew Levine, lead author of the paper and a Ph.D. student at The Graduate Center.

The self-assembly process, Levine explained, causes the dye molecules to stack in a particular way. This stacking allows dyes that have absorbed solar photons to couple and share energy with --or "excite"--neighboring dyes. The electrons in these dyes then decouple so that they can be collected as harvestable solar energy.

Methodology and Findings

To develop the materials, researchers combined various versions of two frequently used industrial dyes--diketopyrrolopyrrole (DPP) and rylene. This resulted in the formation of six self-assembling superstructures, which scientists investigated using electron microscopy and advanced spectroscopy. They found that each combination had subtle differences in geometry that affected the dyes' excited states, the occurrence of singlet fission, and the yield and lifetime of harvestable electrons. Significance

"This work provides us with a library of nanomaterials that we can study for harvesting solar energy," said Professor Adam Braunschweig, lead researcher on the study and an associate professor with the ASRC Nanoscience Initiative and the Chemistry Departments at Hunter College and The Graduate Center. "Our method for combining the dyes into functional materials using self-assembly means we can carefully tune their properties and increase the efficiency of the critical light-harvesting process."

The materials' ability to self-assemble could also shorten the time for creating commercially viable solar cells, said the researchers, and prove more affordable than current fabrication methods, which rely on the time-consuming process of molecular synthesis.

The research team's next challenge is to develop a method of harvesting the solar charges created by their new nanomaterials. Currently, they are working to design a rylene molecule that can accept the electron from the DPP molecule after the singlet fission process. If successful, these materials would both initiate the singlet fission process and facilitate charge-transfer into a solar cell.
-end-
Organizational Attribution

Our correct name is the Advanced Science Research Center at The Graduate Center of The City University of New York. For the purpose of space, Advanced Science Research Center, GC/CUNY is acceptable. On second reference, ASRC is correct.

About the Advanced Science Research Center

The ASRC at The Graduate Center elevates scientific research and education at CUNY and beyond through initiatives in five distinctive, but increasingly interconnected disciplines: environmental sciences, nanoscience, neuroscience, photonics, and structural biology. The ASRC promotes a collaborative, interdisciplinary research culture with renowned researchers from each of the initiatives working side-by-side in the ASRC's core facilities, sharing equipment that is among the most advanced available.

About The Graduate Center of The City University of New York

The Graduate Center of The City University of New York (CUNY) is a leader in public graduate education devoted to enhancing the public good through pioneering research, serious learning, and reasoned debate. The Graduate Center offers ambitious students more than 40 doctoral and master's programs of the highest caliber, taught by top faculty from throughout CUNY -- the nation's largest public urban university. Through its nearly 40 centers, institutes, and initiatives, including its Advanced Science Research Center (ASRC), The Graduate Center influences public policy and discourse and shapes innovation. The Graduate Center's extensive public programs make it a home for culture and conversation.

Advanced Science Research Center, GC/CUNY

Related Solar Cells Articles:

Solar cells with new interfaces
Scientists from NUST MISIS (Russia) and University of Rome Tor Vergata found out that a microscopic quantity of two-dimensional titanium carbide called MXene significantly improves collection of electrical charges in a perovskite solar cell, increasing the final efficiency above 20%.
Welcome indoors, solar cells
Swedish and Chinese scientists have developed organic solar cells optimised to convert ambient indoor light to electricity.
Mapping the energetic landscape of solar cells
A new spectroscopic method now makes it possible to measure and visualize the energetic landscape inside solar cells based on organic materials.
Solar energy becomes biofuel without solar cells
Soon we will be able to replace fossil fuels with a carbon-neutral product created from solar energy, carbon dioxide and water.
A good first step toward nontoxic solar cells
A team of engineers at Washington University in St. Louis has found what they believe is a more stable, less toxic semiconductor for solar applications, using a novel double mineral discovered through data analytics and quantum-mechanical calculations.
Organic solar cells will last 10 years in space
Scientists from the Skoltech Center for Energy Science and Technology, the Institute for Problems of Chemical Physics of RAS, and the Department of Chemistry of MSU presented solar cells based on conjugated polymers and fullerene derivatives, that demonstrated record-high radiation stability and withstand gamma radiation of >6,000 Gy raising hopes for their stable operation on the near-earth orbit during 10 years or even longer.
Next-gen solar cells spin in new direction
A nanomaterial made from phosphorus, known as phosphorene, is shaping up as a key ingredient for more sustainable and efficient next-generation perovskite solar cells.
Caffeine gives solar cells an energy boost
Scientists from the University of California, Los Angeles (UCLA) and Solargiga Energy in China have discovered that caffeine can help make a promising alternative to traditional solar cells more efficient at converting light to electricity.
New properties of perovskite solar cells
Perovskite solar cells are lighter and cheaper than silicon, their production is non-toxic.
Making solar cells is like buttering bread
Formamidinium lead iodide is a very good material for photovoltaic cells, but getting the correct and stable crystal structure is a challenge.
More Solar Cells News and Solar Cells Current Events

Best Science Podcasts 2019

We have hand picked the best science podcasts for 2019. Sit back and enjoy new science podcasts updated daily from your favorite science news services and scientists.
Now Playing: TED Radio Hour

Rethinking Anger
Anger is universal and complex: it can be quiet, festering, justified, vengeful, and destructive. This hour, TED speakers explore the many sides of anger, why we need it, and who's allowed to feel it. Guests include psychologists Ryan Martin and Russell Kolts, writer Soraya Chemaly, former talk radio host Lisa Fritsch, and business professor Dan Moshavi.
Now Playing: Science for the People

#538 Nobels and Astrophysics
This week we start with this year's physics Nobel Prize awarded to Jim Peebles, Michel Mayor, and Didier Queloz and finish with a discussion of the Nobel Prizes as a way to award and highlight important science. Are they still relevant? When science breakthroughs are built on the backs of hundreds -- and sometimes thousands -- of people's hard work, how do you pick just three to highlight? Join host Rachelle Saunders and astrophysicist, author, and science communicator Ethan Siegel for their chat about astrophysics and Nobel Prizes.