Nav: Home

Metallic hydrogen, once theory, becomes reality

January 26, 2017

Nearly a century after it was theorized, Harvard scientists have succeeded in creating the rarest - and potentially one of the most valuable - materials on the planet.

The material - atomic metallic hydrogen - was created by Thomas D. Cabot Professor of the Natural Sciences Isaac Silvera and post-doctoral fellow Ranga Dias. In addition to helping scientists answer fundamental questions about the nature of matter, the material is theorized to have a wide range of applications, including as a room-temperature superconductor. The creation of the rare material is described in a January 26 paper published in Science.

"This is the holy grail of high-pressure physics," Silvera said. "It's the first-ever sample of metallic hydrogen on Earth, so when you're looking at it, you're looking at something that's never existed before."

To create it, Silvera and Dias squeezed a tiny hydrogen sample at 495 gigapascal, or more than 71.7 million pounds-per-square inch - greater than the pressure at the center of the Earth. At those extreme pressures, Silvera explained, solid molecular hydrogen -which consists of molecules on the lattice sites of the solid - breaks down, and the tightly bound molecules dissociate to transforms into atomic hydrogen, which is a metal.

While the work offers an important new window into understanding the general properties of hydrogen, it also offers tantalizing hints at potentially revolutionary new materials.

"One prediction that's very important is metallic hydrogen is predicted to be meta-stable," Silvera said. "That means if you take the pressure off, it will stay metallic, similar to the way diamonds form from graphite under intense heat and pressure, but remains a diamond when that pressure and heat is removed."

Understanding whether the material is stable is important, Silvera said, because predictions suggest metallic hydrogen could act as a superconductor at room temperatures.

"That would be revolutionary," he said. "As much as 15 percent of energy is lost to dissipation during transmission, so if you could make wires from this material and use them in the electrical grid, it could change that story."

Among the holy grails of physics, a room temperature superconductor, Dias said, could radically change our transportation system, making magnetic levitation of high-speed trains possible, as well as making electric cars more efficient and improving the performance of many electronic devices.

The material could also provide major improvements in energy production and storage - because superconductors have zero resistance energy could be stored by maintaining currents in superconducting coils, and then be used when needed.

Though it has the potential to transform life on Earth, metallic hydrogen could also play a key role in helping humans explore the far reaches of space, as the most powerful rocket propellant yet discovered.

"It takes a tremendous amount of energy to make metallic hydrogen," Silvera explained. "And if you convert it back to molecular hydrogen, all that energy is released, so it would make it the most powerful rocket propellant known to man, and could revolutionize rocketry."

The most powerful fuels in use today are characterized by a "specific impulse" - a measure, in seconds, of how fast a propellant is fired from the back of a rocket - of 450 seconds. The specific impulse for metallic hydrogen, by comparison, is theorized to be 1,700 seconds.

"That would easily allow you to explore the outer planets," Silvera said. "We would be able to put rockets into orbit with only one stage, versus two, and could send up larger payloads, so it could be very important."

To create the new material, Silvera and Dias turned to one of the hardest materials on Earth - diamond.

But rather than natural diamond, Silvera and Dias used two small pieces of carefully polished synthetic diamond which were then treated to make them even tougher and then mounted opposite each other in a device known as a diamond anvil cell.

"Diamonds are polished with diamond powder, and that can gouge out carbon from the surface," Silvera said. "When we looked at the diamond using atomic force microscopy, we found defects, which could cause it to weaken and break."

The solution, he said, was to use a reactive ion etching process to shave a tiny layer - just five microns thick, or about one-tenth of a human hair - from the diamond's surface. The diamonds were then coated with a thin layer of alumina to prevent the hydrogen from diffusing into their crystal structure and embrittling them.

After more than four decades of work on metallic hydrogen, and nearly a century after it was first theorized, seeing the material for the first time, Silvera said, was thrilling.

"It was really exciting," he said. "Ranga was running the experiment, and we thought we might get there, but when he called me and said, 'The sample is shining,' I went running down there, and it was metallic hydrogen.

"I immediately said we have to make the measurements to confirm it, so we rearranged the lab...and that's what we did," he said. "It's a tremendous achievement, and even if it only exists in this diamond anvil cell at high pressure, it's a very fundamental and transformative discovery."
-end-


Harvard University

Related Hydrogen Articles:

Hydrogen boride nanosheets: A promising material for hydrogen carrier
Researchers at Tokyo Institute of Technology, University of Tsukuba, and colleagues in Japan report a promising hydrogen carrier in the form of hydrogen boride nanosheets.
World's fastest hydrogen sensor could pave the way for clean hydrogen energy
Hydrogen is a clean and renewable energy carrier that can power vehicles, with water as the only emission.
Chemical hydrogen storage system
Hydrogen is a highly attractive, but also highly explosive energy carrier, which requires safe, lightweight and cheap storage as well as transportation systems.
Observing hydrogen's effects in metal
Microscopy technique could help researchers design safer reactor vessels or hydrogen storage tanks.
The 'Batman' in hydrogen fuel cells
In a study published in Nature on Jan. 31, researchers at the University of Science and Technology of China (USTC) report advances in the development of hydrogen fuel cells that could increase its application in vehicles, especially in extreme temperatures like cold winters.
Paving the way for more efficient hydrogen cars
Hydrogen-powered vehicles emit only water vapor from their tailpipes, offering a cleaner alternative to fossil-fuel-based transportation.
New catalyst produces cheap hydrogen
QUT chemistry researchers have discovered cheaper and more efficient materials for producing hydrogen for the storage of renewable energy that could replace current water-splitting catalysts.
The faint glow of cosmic hydrogen
A study published recently in Nature magazine, in which Ana Monreal-Ibero, a researcher at the Instituto de Astrofísica de Canarias (IAC) is a participant, reveals the presence of a hitherto undetected component of the universe: large masses of gas surrounding distant galaxies.
New technology improves hydrogen manufacturing
INL researchers demonstrated high-performance electrochemical hydrogen production at a lower temperature than had been possible before.
Hydrogen transfer: One thing after the other
Hydride transfer is an important reaction for chemistry (e.g., fuel cells), as well as biology (e.g., respiratory chain and photosynthesis).
More Hydrogen News and Hydrogen Current Events

Top Science Podcasts

We have hand picked the top science podcasts of 2019.
Now Playing: TED Radio Hour

Accessing Better Health
Essential health care is a right, not a privilege ... or is it? This hour, TED speakers explore how we can give everyone access to a healthier way of life, despite who you are or where you live. Guests include physician Raj Panjabi, former NYC health commissioner Mary Bassett, researcher Michael Hendryx, and neuroscientist Rachel Wurzman.
Now Playing: Science for the People

#544 Prosperity Without Growth
The societies we live in are organised around growth, objects, and driving forward a constantly expanding economy as benchmarks of success and prosperity. But this growing consumption at all costs is at odds with our understanding of what our planet can support. How do we lower the environmental impact of economic activity? How do we redefine success and prosperity separate from GDP, which politicians and governments have focused on for decades? We speak with ecological economist Tim Jackson, Professor of Sustainable Development at the University of Surrey, Director of the Centre for the Understanding of Sustainable Propserity, and author of...
Now Playing: Radiolab

An Announcement from Radiolab