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Nano 'sandwich' offers unique properties

February 27, 2017

Rice University researchers have modeled a nanoscale sandwich, the first in what they hope will become a molecular deli for materials scientists.

Their recipe puts two slices of atom-thick graphene around nanoclusters of magnesium oxide that give the super-strong, conductive material expanded optoelectronic properties.

Rice materials scientist Rouzbeh Shahsavari and his colleagues built computer simulations of the compound and found it would offer features suitable for sensitive molecular sensing, catalysis and bio-imaging. Their work could help researchers design a range of customizable hybrids of two- and three-dimensional structures with encapsulated molecules, Shahsavari said.

The research appears this month in the Royal Society of Chemistry journal Nanoscale.

The scientists were inspired by experiments elsewhere in which various molecules were encapsulated using van der Waals forces to draw components together. The Rice-led study was the first to take a theoretical approach to defining the electronic and optical properties of one of those "made" samples, two-dimensional magnesium oxide in bilayer graphene, Shahsavari said.

"We knew if there was an experiment already performed, we would have a great reference point that would make it easier to verify our computations, thus allowing more reliable expansion of our computational results to identify performance trends beyond the reach of experiments," Shahsavari said.

Graphene on its own has no band gap - the characteristic that makes a material a semiconductor. But the hybrid does, and this band gap could be tunable, depending on the components, Shahsavari said. The enhanced optical properties are also tunable and useful, he said.

"We saw that while this single flake of magnesium oxide absorbed one kind of light emission, when it was trapped between two layers of graphene, it absorbed a wide spectrum. That could be an important mechanism for sensors," he said.

Shahsavari said his group's theory should be applicable to other two-dimensional materials, like hexagonal boron-nitride, and molecular fillings. "There is no single material that can solve all the technical problems of the world," he said. "It always comes down to making hybrid materials to synergize the best features of multiple components to do a specific job. My group is working on these hybrid materials by tweaking their components and structures to meet new challenges."
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Farzaneh Shayeganfar, a visiting research scientist at Rice and researcher at Shahid Rajaee Teacher Training University, Tehran, Iran, is lead author of the paper. Co-authors are Javad Beheshtiyan and Mehdi Neek-Amal, both of Shahid Rajaee and the University of Antwerp, Belgium.

Rice University and the Iran Science Elites Federation supported the research. Computing resources were supplied by Rice's National Science Foundation-supported DAVinCI supercomputer administered by Rice's Center for Research Computing and were procured in partnership with Rice's Ken Kennedy Institute for Information Technology.

Read the abstract at http://pubs.rsc.org/en/content/articlelanding/2017/nr/c6nr08586e#!divAbstract

This news release can be found online at http://news.rice.edu/2017/02/27/nano-sandwich-offers-unique-properties/

Follow Rice News and Media Relations via Twitter @RiceUNews

Related materials:

Multiscale Materials Laboratory home page: http://rouzbeh.rice.edu/

George R. Brown School of Engineering: http://engineering.rice.edu

Rice Department of Civil and Environmental Engineering: http://www.ceve.rice.edu

Rice Department of Materials Science and NanoEngineering: https://msne.rice.edu

Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation's top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,879 undergraduates and 2,861 graduate students, Rice's undergraduate student-to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice is ranked No. 1 for happiest students and for lots of race/class interaction by the Princeton Review. Rice is also rated as a best value among private universities by Kiplinger's Personal Finance. To read "What they're saying about Rice," go to http://tinyurl.com/RiceUniversityoverview.

Rice University

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