Nav: Home

Graphene coating could help prevent lithium battery fires

April 09, 2019

Lithium batteries are what allow electric vehicles to travel several hundred miles on one charge. Their capacity for energy storage is well known, but so is their tendency to occasionally catch on fire - an occurrence known to battery researchers as "thermal runaway." These fires occur most frequently when the batteries overheat or cycle rapidly. With more and more electric vehicles on the road each year, battery technology needs to adapt to reduce the likelihood of these dangerous and catastrophic fires.

Researchers from the University of Illinois at Chicago College of Engineering report that graphene -- wonder material of the 21st century -- may take the oxygen out of lithium battery fires. They report their findings in the journal Advanced Functional Materials.

The reasons lithium batteries catch fire include rapid cycling or charging and discharging, and high temperatures in the battery. These conditions can cause the cathode inside the battery -- which in the case of most lithium batteries is a lithium-containing oxide, usually lithium cobalt oxide -- to decompose and release oxygen. If the oxygen combines with other flammable products given off through decomposition of the electrolyte under high enough heat, spontaneous combustion can occur.

"We thought that if there was a way to prevent the oxygen from leaving the cathode and mixing with other flammable products in the battery, we could reduce the chances of a fire occurring," said Reza Shahbazian-Yassar, associate professor of mechanical and industrial engineering in the UIC College of Engineering and corresponding author of the paper.

It turns out that a material Shahbazian-Yassar is very familiar with provided a perfect solution to this problem. That material is graphene -- a super-thin layer of carbon atoms with unique properties. Shahbazian-Yassar and his colleagues previously had used graphene to help modulate lithium buildup on electrodes in lithium metal batteries.

Shahbazian-Yassar and his colleagues knew that graphene sheets are impermeable to oxygen atoms. Graphene is also strong, flexible and can be made to be electrically conductive. Shahbazian-Yassar and Soroosh Sharifi-Asl, a graduate student in mechanical and industrial engineering at UIC and lead author of the paper, thought that if they wrapped very small particles of the lithium cobalt oxide cathode of a lithium battery in graphene, it might prevent oxygen from escaping.

First, the researchers chemically altered the graphene to make it electrically conductive. Next, they wrapped the tiny particles of lithium cobalt oxide cathode electrode in the conductive graphene.

When they looked at the graphene-wrapped lithium cobalt oxide particles using electron microscopy, they saw that the release of oxygen under high heat was reduced significantly compared with unwrapped particles.

Next, they bound together the wrapped particles with a binding material to form a usable cathode, and incorporated it into a lithium metal battery. When they measured released oxygen during battery cycling, they saw almost no oxygen escaping from cathodes even at very high voltages. The lithium metal battery continued to perform well even after 200 cycles.

"The wrapped cathode battery lost only about 14% of its capacity after rapid cycling compared to a conventional lithium metal battery where performance was down about 45% under the same conditions," Sharifi-Asl said.

"Graphene is the ideal material for blocking the release of oxygen into the electrolyte," Shahbazian-Yassar said. "It is impermeable to oxygen, electrically conductive, flexible, and is strong enough to withstand conditions within the battery. It is only a few nanometers thick so there would be no extra mass added to the battery. Our research shows that its use in the cathode can reliably reduce the release of oxygen and could be one way that the risk for fire in these batteries -- which power everything from our phones to our cars -- could be significantly reduced."
-end-
Soroosh Sharifi-Asl, Tara Foroozan, Mohammad Asadi, Yifei Yuan, Ramasubramonian Deivanayagam, Ramin Rojaee, Boao Song and Amin Salehi-Khojin of the UIC College of Engineering; Fernando Soto and Perla Balbuena of Texas A & M University; and Xuanxuan Bi, Khalil Amine and Jun Lu of Argonne National Laboratory are co-authors on the paper.

This research was supported in part by the National Science Foundation award CMMI-1619743.

University of Illinois at Chicago

Related Graphene Articles:

New 'brick' for nanotechnology: Graphene Nanomesh
Researchers at Japan advanced institute of science and technology (JAIST) successfully fabricated suspended graphene nanomesh (GNM) by using the focused helium ion beam technology.
Flatter graphene, faster electrons
Scientists from the Swiss Nanoscience Institute and the Department of Physics at the University of Basel developed a technique to flatten corrugations in graphene layers.
Graphene Flagship publishes handbook of graphene manufacturing
The EU-funded research project Graphene Flagship has published a comprehensive guide explaining how to produce and process graphene and related materials (GRMs).
How to induce magnetism in graphene
Graphene, a two-dimensional structure made of carbon, is a material with excellent mechani-cal, electronic and optical properties.
Graphene: The more you bend it, the softer it gets
New research by engineers at the University of Illinois combines atomic-scale experimentation with computer modeling to determine how much energy it takes to bend multilayer graphene -- a question that has eluded scientists since graphene was first isolated.
How do you know it's perfect graphene?
Scientists at the US Department of Energy's Ames Laboratory have discovered an indicator that reliably demonstrates a sample's high quality, and it was one that was hiding in plain sight for decades.
Graphene is 3D as well as 2D
Graphene is actually a 3D material as well as a 2D material, according to a new study from Queen Mary University of London.
How to purify water with graphene
Scientists from the National University of Science and Technology 'MISIS' together with their colleagues from Derzhavin Tambov State University and Saratov Chernyshevsky State University have figured out that graphene is capable of purifying water, making it drinkable, without further chlorination.
Decoupled graphene thanks to potassium bromide
The use of potassium bromide in the production of graphene on a copper surface can lead to better results.
1 + 1 does not equal 2 for graphene-like 2D materials
Physicists from the University of Sheffield have discovered that when two atomically thin graphene-like materials are placed on top of each other their properties change, and a material with novel hybrid properties emerges, paving the way for design of new materials and nano-devices.
More Graphene News and Graphene Current Events

Trending Science News

Current Coronavirus (COVID-19) News

Top Science Podcasts

We have hand picked the top science podcasts of 2020.
Now Playing: TED Radio Hour

Making Amends
What makes a true apology? What does it mean to make amends for past mistakes? This hour, TED speakers explore how repairing the wrongs of the past is the first step toward healing for the future. Guests include historian and preservationist Brent Leggs, law professor Martha Minow, librarian Dawn Wacek, and playwright V (formerly Eve Ensler).
Now Playing: Science for the People

#566 Is Your Gut Leaking?
This week we're busting the human gut wide open with Dr. Alessio Fasano from the Center for Celiac Research and Treatment at Massachusetts General Hospital. Join host Anika Hazra for our discussion separating fact from fiction on the controversial topic of leaky gut syndrome. We cover everything from what causes a leaky gut to interpreting the results of a gut microbiome test! Related links: Center for Celiac Research and Treatment website and their YouTube channel
Now Playing: Radiolab

The Third. A TED Talk.
Jad gives a TED talk about his life as a journalist and how Radiolab has evolved over the years. Here's how TED described it:How do you end a story? Host of Radiolab Jad Abumrad tells how his search for an answer led him home to the mountains of Tennessee, where he met an unexpected teacher: Dolly Parton.Jad Nicholas Abumrad is a Lebanese-American radio host, composer and producer. He is the founder of the syndicated public radio program Radiolab, which is broadcast on over 600 radio stations nationwide and is downloaded more than 120 million times a year as a podcast. He also created More Perfect, a podcast that tells the stories behind the Supreme Court's most famous decisions. And most recently, Dolly Parton's America, a nine-episode podcast exploring the life and times of the iconic country music star. Abumrad has received three Peabody Awards and was named a MacArthur Fellow in 2011.