Molybdenum telluride nanosheets enable selective electrochemical production of hydrogen peroxide

May 19, 2020

H2O2 is an important commodity chemical and potential energy carrier, and is widely used for various environmental, medical and household applications. At present, about 99% H2O2 is produced from energy-intensive anthraquinone oxidation process. Its centralized production in this way produces highly concentrated H2O2 that often has to be distributed to and diluted at the site of use, bringing additional complexity and challenges. In addition, H2O2 can also be produced from the direct reaction between H2 and O2 in the presence of Pd-based catalysts. The potential explosion hazard of this approach, however, hinders its practical application.

Electrochemical oxygen reduction reaction via a two-electron pathway represents a novel and decentralized strategy to produce H2O2. It relies on the development of active and selective electrocatalysts. The state-of-the-art candidates are Pt-Hg and Pd-Hg alloys. Despite their relatively high mass activity and selectivity in acids, these precious metal alloys are unlikely to be used on a large scale due to their prohibitive costs and toxicity (because of the inclusion of Hg). More recently, carbon-based materials emerge and demonstrate appreciable activity and selectivity for H2O2 production in alkaline solution. Unfortunately, their potentials are also limited since H2O2 is subjected to rapid decomposition in alkaline medium. For practical applications, H2O2 is more widely used in acidic media with stronger oxidation ability. As a result, it is highly desirable to pursue high-performance electrocatalysts for selective H2O2 production in acids.

In a new research published in the Beijing-based National Science Review, scientists from Soochow University (Suzhou, China), the University of Chinese Academy of Sciences (Beijing, China), Nanjing Normal University (Nanjing, China) and Trinity College Dublin (Dublin, Ireland) worked together, and reported for the first time that molybdenum telluride (MoTe2) nanoflakes had a remarkable performance for H2O2 production in acids.

MoTe2 nanoflakes were prepared via the well-established liquid phase exfoliation method from bulk MoTe2. X-ray diffraction and Raman analyses evidenced that the product had a hexagonal 2H phase. Scanning electron microscopy and transmission electron microscopy imaging revealed that exfoliated MoTe2 nanoflakes had lateral size distribution from 50 to 350 nm. Moreover, the authors used aberration-corrected scanning transmission electron microscopy to elucidate the atomic structure of MoTe2 nanoflakes, and observed that their exposed edges, though not atomically sharp, were mostly along the zigzag directions with abundant bonding unsaturated Mo and Te sites.

When investigated as the electrocatalyst materials in O2-satuated 0.5 M H2SO4 solution, MoTe2 nanoflakes mixed with graphene nanosheets exhibited positive onset potential of 0.56 V versus reversible hydrogen electrode and outstanding H2O2 selectivity up to 93%. The mass activity was also calculated by normalizing the catalytic current with respect to the catalyst mass. The authors found that the value was in the range of ~10-102 A g-1 between 0.3-0.45 V for MoTe2, which, although not as magnificent as the state-of-the-art Pt-Hg and Pd-Hg alloys, was superior to Au alloys and carbon-based materials. Prof. Yanguang Li who led the electrochemical experiments noted that "the mass activity of exfoliated MoTe2 nanosheets at 0.4 V was 27 A g-1 -- approximately 7-10 times greater than those of Au-Pd alloys and N-doped carbon." In addition to its impressive activity and selectivity, MoTe2 nanoflakes also exhibited decent stability with negligible performance loss even after the accelerated durability test and overnight aging experiment.

In order to understand the experimental result, the authors conducted density functional theory calculations to simulate the absorption energies of key reaction intermediates on the catalyst surface. They found that the zigzag edge of 2H MoTe2 had suitable binding for HOO* and weak binding for O*, and therefore would promote the reduction of O2 to H2O2 but retard its further reduction to H2O. Prof. Yafei Li who led the theoretical work said "MoTe2 was really unique for its capability for two-electron oxygen reduction, which was not found in other transition metal dichalcogenides including MoS2 and MoSe2"

"Our study here unveiled the unexpected potential of MoTe2 nanoflakes as a non-precious metal based electrocatalyst for H2O2 production in acids, and might open a new pathway toward the catalyst design for this challenging electrochemical reaction." Prof. Yanguang Li finally commented on their interesting discovery.
-end-
Y.G.L. acknowledges the support from the Ministry of Science and Technology of China (2017YFA0204800), the Priority Academic Program Development of Jiangsu Higher Education Institutions, and Collaborative Innovation Center of Suzhou Nano Science and Technology. Y.F.L. acknowledges the support from the National Natural Science Foundation of China (21873050). W.Z. thanks the financial support from the National Natural Science Foundation of China (51622211) and the CAS Pioneer Hundred Talents Program.

See the article:

Xuan Zhao, Yu Wang, Yunli Da, Xinxia Wang, Tingting Wang, Mingquan Xu, Xiaoyun He, Wu Zhou, Yafei Li, Jonathan N. Coleman and Yanguang Li

Selective electrochemical production of hydrogen peroxide at zigzag edges of exfoliated aolybdenum telluride nanoflakes

Natl Sci Rev 2020; DOI: 10.1093/nsr/nwaa084

https://doi.org/10.1093/nsr/nwaa084

The National Science Review is the first comprehensive scholarly journal released in English in China that is aimed at linking the country's rapidly advancing community of scientists with the global frontiers of science and technology. The journal also aims to shine a worldwide spotlight on scientific research advances across China.

Science China Press

Related China Articles from Brightsurf:

China 2050: How the US should prepare for an ascendant China -- RAND Report
New RAND report says US should prepare for a triumphant or ascending People's Republic of China -- scenarios that not only align with current PRC national development trends but also represent the most challenging future scenarios for the US military.

The GDP fudge: China edition
By linking GDP growth to promotions, the Chinese government has inadvertently created incentives for provincial officials to report inaccurate financial data, a study says.

Opportunity blows for offshore wind in China
If China is to meet and exceed its Paris Climate Agreement goal by 2030, it's going to need to find a way to increase its wind capacity.

Cesarean delivery rates in China
This study assessed changes between 2008 and 2018 in the rate of cesarean deliveries in China.

Environmental pollution in China begins decreasing
For decades pollution in China has paralleled economic growth. But this connection has been weakened in recent years, according to a new international research study published in the Science Advances journal.

Farming for natural profits in China
Expanding monoculture threatens valuable services from land, such as flood control, water purification and climate stabilization.

Cardiovascular disease in China
This study analyzed data from the Global Burden of Disease Study to look at the rate of cardiovascular disease (CVD) in China along with death and disability from CVD from 1990 to 2016.

New integrative stratigraphy and timescale for China released
A special issue, edited by professor SHEN Shuzhong and professor RONG Jiayu of the Nanjing Institute of Geology and Palaeontology of the Chinese Academy of Sciences, summarizes the latest advances in stratigraphy and timescale as well as discusses the correlation among different blocks in China and with international timescales.

Cambrian integrative stratigraphy and timescale of China
The review paper briefly summarizes the historical narrative of the present international chronostratigraphic framework of the Cambrian System and recent advances and problems of the undefined Cambrian stage GSSPs, in particular the authors challenge the global correlation of the GSSP for the Cambrian base, in addition to Cambrian chemostratigraphy and geochronology.

What causes extreme heat in North China?
A collaborative research team from China has published a new analysis that shows the horizontal heat flux in the mixed layer plays a crucial role in extreme heat events in the North China Plain region.

Read More: China News and China Current Events
Brightsurf.com is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to Amazon.com.