Liquid metals break down organic fuels into ultra-thin graphitic sheets

June 10, 2020

For the first time, FLEET researchers at UNSW, Sydney show the synthesis of ultra-thin graphitic materials at room temperature using organic fuels (which can be as simple as basic alcohols such as ethanol).

Graphitic materials, such as graphene, are ultra-thin sheets of carbon compounds that are sought after materials with great promises for battery storage, solar cells, touch panels and even more recently fillers for polymers.

These researchers were able to synthesize ultra-thin carbon-based materials on the surface of liquid metals at room temperature electrochemically. Before this report, others had shown electro-formation of such carbon-based materials only by transferring sheets onto the electrodes or electrode exfoliation of naturally-occurring carbon crystals from mines.

"Using gallium liquid metal, we could catalytically break down the fuels and form carbon-carbon bonds (the base of graphitic sheets) from organic fuels at room temperature. The ultra-smooth surface of liquid metals could then template atomically-thin carbon based sheets. Removal of these sheets was easy as they do not stick to the liquid metal surface," suggested Prof Kalantar-Zadeh, the lead of this project and the Director of the Centre for Advanced Solid and Liquid based Electronics and Optics (CASLEO) at UNSW.

"It is simple. Why has room temperature electro-synthesis of two-dimensional graphitic materials not been achieved before? We cannot offer a definitive answer. Perhaps disregarding ultra-catalysts such as liquid metals and too much emphasis on solid electrodes which are inherently not smooth." added Dr Mohannad Mayyas the first author of the paper.
The paper Liquid-Metal-Templated Synthesis of 2D Graphitic Materials at Room Temperature was published in highly reputed journal of Advanced Materials on the 8th of June 2020 (DOI: 10.1002/adma.202001997)

Researchers from RMIT, University of California Los Angeles (UCLA) and the Center for Multidimensional Carbon Materials, Institute for Basic Science (IBS), Korea are the other collaborators of the research and authors of the manuscript.

Contact detail: Dr. Mohannad Mayyas,

ARC Centre of Excellence in Future Low-Energy Electronics Technologies

Related Carbon Articles from Brightsurf:

The biggest trees capture the most carbon: Large trees dominate carbon storage in forests
A recent study examining carbon storage in Pacific Northwest forests demonstrated that although large-diameter trees (21 inches) only comprised 3% of total stems, they accounted for 42% of the total aboveground carbon storage.

Carbon storage from the lab
Researchers at the University of Freiburg established the world's largest collection of moss species for the peat industry and science

Carbon-carbon covalent bonds far more flexible than presumed
A Hokkaido University research group has successfully demonstrated that carbon-carbon (C-C) covalent bonds expand and contract flexibly in response to light and heat.

Metal wires of carbon complete toolbox for carbon-based computers
Carbon-based computers have the potential to be a lot faster and much more energy efficient than silicon-based computers, but 2D graphene and carbon nanotubes have proved challenging to turn into the elements needed to construct transistor circuits.

Cascades with carbon dioxide
Carbon dioxide (CO(2)) is not just an undesirable greenhouse gas, it is also an interesting source of raw materials that are valuable and can be recycled sustainably.

Two-dimensional carbon networks
Lithium-ion batteries usually contain graphitic carbons as anode materials. Scientists have investigated the carbonic nanoweb graphdiyne as a novel two-dimensional carbon network for its suitability in battery applications.

Can wood construction transform cities from carbon source to carbon vault?
A new study by researchers and architects at Yale and the Potsdam Institute for Climate Impact Research predicts that a transition to timber-based wood products in the construction of new housing, buildings, and infrastructure would not only offset enormous amounts of carbon emissions related to concrete and steel production -- it could turn the world's cities into a vast carbon sink.

Investigation of oceanic 'black carbon' uncovers mystery in global carbon cycle
An unexpected finding published today in Nature Communications challenges a long-held assumption about the origin of oceanic black coal, and introduces a tantalizing new mystery: If oceanic black carbon is significantly different from the black carbon found in rivers, where did it come from?

First fully rechargeable carbon dioxide battery with carbon neutrality
Researchers at the University of Illinois at Chicago are the first to show that lithium-carbon dioxide batteries can be designed to operate in a fully rechargeable manner, and they have successfully tested a lithium-carbon dioxide battery prototype running up to 500 consecutive cycles of charge/recharge processes.

How and when was carbon distributed in the Earth?
A magma ocean existing during the core formation is thought to have been highly depleted in carbon due to its high-siderophile (iron loving) behavior.

Read More: Carbon News and Carbon Current Events is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to