Nav: Home

Real-time analysis of MOF adsorption behavior

June 19, 2019

Researchers have developed a technology to analyze the adsorption behavior of molecules in each individual pore of a metal organic framework (MOF). This system has large specific surface areas, allowing for the real-time observation of the adsorption process of an MOF, a new material effective for sorting carbon dioxide, hydrogen, and methane.

Accurate measurements and assessments of gas adsorption isotherms are important for characterizing porous materials and developing their applications. The existing technology is only able to measure the amount of gas molecules adsorbed to the material, without directly observing the adsorption behavior.

The research team led by Professor Jeung Ku Kang from the Graduate School of Energy, Environment, Water and Sustainability (EEWS) prescribed a real time gas adsorption crystallography system by integrating an existing X-ray diffraction (XRD) measurement device that can provide structural information and a gas adsorption measurement device.

Specifically, the system allowed the observation of a mesoporous MOF that has multiple pores rather than a single pore structure. The research team categorized the adsorption behaviors of MOF molecules by pore type, followed by observations and measurements, resulting in the identification of a stepwise adsorption process that was previously not possible to analyze.

Further, the team systematically and quantitatively analyzed how the pore structure and the type of adsorption molecule affect the adsorption behavior to suggest what type of MOF structure is appropriate as a storage material for each type of adsorption behavior.

Professor Kang said, "We quantitatively analyzed each pore molecule in real time to identify the effects of chemical and structural properties of pores on adsorption behavior." He continued, "By understanding the real-time adsorption behavior of molecules at the level of the pores that form the material, rather than the whole material, we will be able to apply this technology to develop a new high-capacity storage material."
This research was published in Nature Chemistry online on May 13, 2019 under the title 'Isotherms of Individual Pores by Gas Adsorption Crystallography'.

The Korea Advanced Institute of Science and Technology (KAIST)

Related Molecules Articles:

The inner lives of molecules
Researchers from Canada, the UK and Germany have developed a new experimental technique to take 3-D images of molecules in action.
Novel technique helps ID elusive molecules
Stuart Lindsay, a researcher at Arizona State University's Biodesign Institute, has devised a clever means of identifying carbohydrate molecules quickly and accurately.
How solvent molecules cooperate in reactions
Molecules from the solvent environment that at first glance seem to be uninvolved can be essential for chemical reactions.
A new way to display the 3-D structure of molecules
Berkeley Lab and UC Berkeley Researchers have developed nanoscale display cases that enables new atomic-scale views of hard-to-study chemical and biological samples.
Bending hot molecules
Hot molecules are found in extreme environments such as the edges of fusion reactors.
At attention, molecules!
University of Iowa chemists have learned about a molecular assembly that may help create quicker, more responsive touch screens, among other applications.
Folding molecules into screw-shaped structures
An international research team describes the methods of winding up molecules into screw-shaped structures.
Artificial molecules
A new method allows scientists at ETH Zurich and IBM to fabricate artificial molecules out of different types of microspheres.
Molecules that may keep you young and alive
A new study may have uncovered the fountain of youth: plant extracts containing the six best groups of anti-aging molecules ever seen.
Fun with Lego (molecules)
A great childhood pleasure is playing with Legos® and marveling at the variety of structures you can create from a small number of basic elements.

Related Molecules Reading:

Best Science Podcasts 2019

We have hand picked the best science podcasts for 2019. Sit back and enjoy new science podcasts updated daily from your favorite science news services and scientists.
Now Playing: TED Radio Hour

Digital Manipulation
Technology has reshaped our lives in amazing ways. But at what cost? This hour, TED speakers reveal how what we see, read, believe — even how we vote — can be manipulated by the technology we use. Guests include journalist Carole Cadwalladr, consumer advocate Finn Myrstad, writer and marketing professor Scott Galloway, behavioral designer Nir Eyal, and computer graphics researcher Doug Roble.
Now Playing: Science for the People

#529 Do You Really Want to Find Out Who's Your Daddy?
At least some of you by now have probably spit into a tube and mailed it off to find out who your closest relatives are, where you might be from, and what terrible diseases might await you. But what exactly did you find out? And what did you give away? In this live panel at Awesome Con we bring in science writer Tina Saey to talk about all her DNA testing, and bioethicist Debra Mathews, to determine whether Tina should have done it at all. Related links: What FamilyTreeDNA sharing genetic data with police means for you Crime solvers embraced...