Wavy surfaces for better light control

June 25, 2020

The importance of light-based technologies for our society was demonstrated once more in recent weeks. Thanks to the internet, millions of people can work remotely, enter virtual classrooms, or talk to friends and relatives. The internet, in turn, owes its power to countless light pulses with which enormous amounts of data are sent around the globe via optical fibres.

To steer and control these light pulses, various technologies are employed. One of the oldest and most important is the diffraction grating, which deflects light of different colours in precisely determined directions. For decades, scientists have been trying to improve the design and production of diffraction gratings to make them suitable for today's demanding applications. At ETH Zurich, a group of researchers led by David Norris, professor at the Department of Mechanical and Process Engineering, have developed a completely new method by which more efficient and more precise diffraction gratings can be produced. They did this together with colleagues now at the University of Utrecht and the company Heidelberg Instruments Nano, which was founded as ETH spin-off SwissLitho. The researchers published the results in the scientific journal Nature.

Interference through grooves

Diffraction gratings are based on the principle of interference. When a light wave hits a grooved surface, it is divided into many smaller waves, each emanating from an individual groove. When these waves leave the surface, they can either add together or cancel each other, depending on the direction in which they travel and on their wavelength (which is related to their colour). This explains why the surface of a CD, on which data is stored in tiny grooves, generates a rainbow of reflected colours when it is illuminated by white light.

For a diffraction grating to work properly its grooves need to have a separation similar to the wavelength of the light, which is around one micrometre - a hundred times smaller than the width of a human hair. "Traditionally, those grooves are etched into the surface of a material using manufacturing techniques from the microelectronics industry", says Nolan Lassaline, a PhD student in Norris's group and first author of the study. "This means, however, that the grooves of the grating are rather square in shape. On the other hand, physics tells us that we should have grooves with a smooth and wavy pattern, like ripples on a lake." Grooves made with traditional methods can, therefore, only ever be rough approximations, which in turn means that the diffraction grating will steer light less efficiently. By pursuing a completely new approach Norris and his collaborators have now discovered a solution to that problem.

Surface patterning with a hot probe

Their approach is based on a technology that also has its origins in Zurich. "Our method is a great-grandchild of the scanning tunnelling microscope, which was invented almost forty years ago by Gerd Binnig and Heinrich Rohrer, who would later win the Nobel Prize for their work", says Norris. In such a microscope, material surfaces are scanned by the sharp tip of a probe with high resolution. The images resulting from such a scan can even show the individual atoms of a material.

Conversely, however, one can also use the sharp tip to pattern a material and thus produce wavy surfaces (see picture). To do so, the researchers heat the tip of a scanning probe to almost 1000 degrees centigrade and press it into a polymer surface at certain locations. This causes the molecules of the polymer to break up and evaporate at those locations, allowing the surface to be precisely sculpted. In this way, the scientists can write almost arbitrary surface profiles point by point into the polymer layer with a resolution of a few nanometres. Finally, the pattern is transferred to an optical material by depositing a silver layer onto the polymer. The silver layer can then be detached from the polymer and used as a reflective diffraction grating.

"This allows us to produce arbitrarily shaped diffraction gratings with a precision of just a few atomic distances in the silver layer", says Norris. Unlike traditional square-shaped grooves, such gratings are no longer approximations, but practically perfect and can be shaped in such a way that the interference of the reflected light waves create precisely controllable patterns.

A variety of applications

Such perfect gratings enable new possibilities for controlling light, which has a range of applications, says Norris: "The new technology can be used, for instance, to build tiny diffraction gratings into integrated circuits with which optical signals for the internet can be sent, received and routed more efficiently." Lassaline adds, "Generally, we can use such diffraction gratings to make highly miniaturized optical devices such as on-chip micro-lasers." Those miniaturized devices, he says, range from ultrathin camera lenses to compact holograms with sharper images. They promise a broad impact in optical technologies such as futuristic smartphone cameras, biosensors, or autonomous vision for robots and self-driving cars.
-end-
Reference

Lassaline N, Brechbühler R, Vonk SJW, Ridderbeek K, Spieser M, Bisig S, le Feber B, Rabouw FT, Norris DJ: Optical Fourier surfaces. Nature, 24 June 2020, doi: 10.1038/s41586-020-2390-x [http://dx.doi.org/10.1038/s41586-020-2390-x]

ETH Zurich

Related Polymer Articles from Brightsurf:

Impurities enhance polymer LED efficiencies
New research published in EPJ B reveals that the higher-than-expected efficiency of PLEDs can be reached through interactions between triplet excitons, and impurities embedded in their polymer layers.

Safety of bioabsorbable polymer against durable polymer DES in high-risk PCI patients
A novel study sought to reveal whether drug-eluting stents (DES) coated with bioabsorbable polymer (BP) presented a safety advantage without compromising efficacy compared to durable polymer (DP) formulations.

Polymer membranes could benefit from taking a dip
A new technique developed by a team including researchers from the US Department of Energy (DOE)'s Argonne National Laboratory makes atomic layer deposition possible on nearly any membrane.

New polymer material may help batteries become self-healing, recyclable
Lithium-ion batteries are notorious for developing internal electrical shorts that can ignite a battery's liquid electrolytes, leading to explosions and fires.

Researchers add order to polymer gels
Gel-like materials have a wide range of applications, especially in chemistry and medicine.

Bundlemers (new polymer units) could transform industries
From tires to clothes to shampoo, many ubiquitous products are made with polymers, large chain-like molecules made of smaller sub-units, called monomers, bonded together.

New synthetic polymer degradable under very mild acidic conditions
A new type of degradable synthetic polymer was prepared by Rh-catalyzed three-component polymerization of a bis(diazocarbonyl) compound, bis(1,3-diketone), and tetrahydrofuran.

New polymer tackles PFAS pollution
toxic polyfluorinated alkyl substances (PFAS) pollution -- commonly used in non-stick and protective coatings, lubricants and aviation fire-fighting foams -- can now be removed from the environment thanks to a new low-cost, safe and environmentally friendly polymer.

New polymer films conduct heat instead of trapping it
MIT engineers have flipped the picture of the standard polymer insulator, by fabricating thin polymer films that conduct heat -- an ability normally associated with metals.

Polymer reversibly glows white when stretched
Polymers that change their appearance in response to mechanical forces can warn of damage developing in a material before the stress causes structural failure.

Read More: Polymer News and Polymer Current Events
Brightsurf.com is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to Amazon.com.