Shell increases versatility of nanowires

June 26, 2019

Nanowires promise to make LEDs more colorful and solar cells more efficient, in addition to speeding up computers. That is, provided that the tiny semiconductors convert electric energy into light, and vice versa, at the right wavelengths. A research team at the German Helmholtz-Zentrum Dresden-Rossendorf (HZDR) has managed to produce nanowires with operating wavelengths that can be freely selected over a wide range - simply by altering the shell structure. Fine-tuned nanowires could take on several roles in an optoelectronic component. That would make the components more powerful, more cost-effective, and easier to integrate, as the team reports in Nature Communications (doi: 10.1038/s41467-019-10654-7).

Nanowires are extremely versatile. The tiny elements can be used for miniaturized photonic and electronic components in nanotechnology. Applications include optical circuits on chips, novel sensors, LEDs, solar cells and innovative quantum technologies. It is the free-standing nanowires that ensure the compatibility of more recent semiconductor technologies with conventional silicon-based technologies. Since contact to the silicon substrate is tiny, they surmount typical difficulties in combining different materials.

For their study, which lasted several years, the Dresden researchers first set about growing nanowires from the semiconductor material gallium arsenide on silicon substrates. The next step involved enclosing the wafer-thin wires in another layer of material to which they added indium as an additional element. Their goal: the mismatched crystal structure of the materials was intended to induce a mechanical strain in the wire core, which changes the electronic properties of gallium arsenide. For instance, the semiconductor bandgap becomes smaller and the electrons become more mobile. To magnify this effect, the scientists kept adding more indium to the shell, or increased the shell's thickness. The result went way beyond expectations.

Taking a known effect to extremes

"What we did was take a known effect to extremes," explained Emmanouil Dimakis, leader of the study that involved researchers from HZDR, TU Dresden and DESY in Hamburg. "The seven percent of strain achieved was tremendous."

At this level of strain, Dimakis had expected to see disorders occurring in the semiconductors: in their experience, the wire core bends or defects arise. The researchers believe that the special experimental conditions were the reason for the absence of such disorders: First, they grew extremely thin gallium arsenide wires - around five thousand times finer than a human hair. Second, the team managed to produce the wire shell at unusually low temperatures. Surface diffusion of atoms is then more or less frozen, forcing the shell to grow evenly around the core. The team of researchers reinforced their discovery by conducting several independent series of measurements at facilities in Dresden, as well as at the high-brilliance X-ray light sources PETRA III in Hamburg and Diamond in England.

The extraordinary results led the researchers to undertake further investigations: "We shifted our focus to the question of what triggers the extremely high strain in the nanowire core, and how this can be used for certain applications," Dimakis recollected. "Scientists have been aware of gallium arsenide as a material for years, but nanowires are special. A material may exhibit completely new properties at the nanoscale."

Potential applications for fiber-optic networks

The researchers realized that the high strain let them shift the bandgap of the gallium arsenide semiconductor to very low energies, making it compatible even for wavelengths of fiber-optic networks. A technological milestone. After all, this spectral range could previously only be achieved via special alloys containing indium, which caused a number of technological problems due to the material mix.

High-precision methods are required to produce nanowires. Four years ago, a special system was installed at HZDR for this purpose: the molecular beam epitaxy laboratory. The self-catalyzed growth of nanowires from beams of atoms or molecules is achieved in the lab; the beams are directed onto silicon substrates in ultra-high-vacuum. Emmanouil Dimakis played a major part in setting up the lab. Most of the studies reported in the current publication were carried out by Leila Balaghi as part of her doctorate.

Helmholtz-Zentrum Dresden-Rossendorf

Related Solar Cells Articles from Brightsurf:

Solar cells of the future
Organic solar cells are cheaper to produce and more flexible than their counterparts made of crystalline silicon, but do not offer the same level of efficiency or stability.

A blast of gas for better solar cells
Treating silicon with carbon dioxide gas in plasma processing brings simplicity and control to a key step for making solar cells.

Record efficiency for printed solar cells
A new study reports the highest efficiency ever recorded for full roll-to-roll printed perovskite solar cells.

Next gen solar cells perform better when there's a camera around
A literal ''trick of the light'' can detect imperfections in next-gen solar cells, boosting their efficiency to match that of existing silicon-based versions, researchers have found.

On the trail of organic solar cells' efficiency
Scientists at TU Dresden and Hasselt University in Belgium investigated the physical causes that limit the efficiency of novel solar cells based on organic molecular materials.

Exciting tweaks for organic solar cells
A molecular tweak has improved organic solar cell performance, bringing us closer to cheaper, efficient, and more easily manufactured photovoltaics.

For cheaper solar cells, thinner really is better
Researchers at MIT and at the National Renewable Energy Laboratory (NREL) have outlined a pathway to slashing costs further, this time by slimming down the silicon cells themselves.

Flexible thinking on silicon solar cells
Combining silicon with a highly elastic polymer backing produces solar cells that have record-breaking stretchability and high efficiency.

Perovskite solar cells get an upgrade
Rice University materials scientists find inorganic compounds quench defects in perovskite-based solar cells and expand their tolerance of light, humidity and heat.

Can solar technology kill cancer cells?
Michigan State University scientists have revealed a new way to detect and attack cancer cells using technology traditionally reserved for solar power.

Read More: Solar Cells News and Solar Cells Current Events is a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for sites to earn advertising fees by advertising and linking to