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Molecule properties change through light

September 09, 2019

In the field of computer engineering, magnetically switchable materials play a significant role in data storage. A team from the Cluster of Excellence Ruhr Explores Solvation at Ruhr-Universität Bochum (RUB) has developed and manufactured a novel molecule called 3-methoxy-9-fluorenylidene. What's special about it: its magnetic properties can be controlled through light of different colours. This might be of use for computer industry.

The researchers working with Professor Wolfram Sander at the Chair of Organic Chemistry II outline their findings in the journal "Angewandte Chemie" on 14 August 2019.

Broad application range of magnetic materials

Magnetism is indispensable in computer engineering. Magnetism controls, for example, the information flow from the computer to magnetic storage media such as hard disks. Moreover, magnetic storage devices use read/write heads in the form of magnets that identify (i.e. read), or alter (i.e. write) the magnetisation patterns on the hard disk.

Methoxy group controls magnetic properties

Developed by Wolfram Sander and his team, the organic molecule 3-methoxy-9-fluorenylidene is based on a fluorine scaffold with a methoxy group attached in the shape of a rotational tail.

The researchers have figured out that the molecule's magnetic properties are determined by the orientation of the methoxy group, which changes its conformation depending on the kind of light that hits it.

Blue light switches the methoxy group into the "up" conformation forming the diamagnetic and less reactive singlet state. Whereas green light rotates the methoxy group down at the molecule, which results in the paramagnetic triplet state that has a higher reactivity against molecular hydrogen.

Interesting for research and industry

Because of its properties, 3-methoxy-9-fluorenylidene is of great interest to research. "Using this group of atoms, we can study the spin dependence of reactions. It could also play a role in the development of novel switchable magnetic materials and chemical sensors," predicts Sander.

Compared with traditional ferromagnetic materials, 3-methoxy-9-fluorenylidene offers considerable advantages: magnetism can be switched on and off through visible light. Moreover, organic magnets are not brittle like conventional magnets, but flexible and can be processed like plastics.

The snag

However, the molecule does have one drawback: it is stable only at extremely low temperatures. "This is why we are researching into magnetically switchable materials that can be used under ambient conditions," says Wolfram Sander.
Original publication

Iris Trosien, Enrique Mendez-Vega, Tobias Thomanek, Wolfram Sander: Conformational spin switching and spin?selective hydrogenation of a magnetically bistable carbene, in: Angewandte Chemie, 2019, DOI: 10.1002/anie.201906579


The German Research Foundation supported the work as part of the Cluster of Excellence Resolv (EXC 2033, project number 390677874).

Press contact

Prof. Dr. Wolfram Sander
Chair of Organic Chemistry II
Faculty of Chemistry and Biochemistry
Ruhr-Universität Bochum
Phone: +49 234 32 24593

Ruhr-University Bochum

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