Nav: Home

Interdisciplinary interactions inspire new discovery

November 07, 2018

Researchers in Japan have found new good catalysts using unique "Heusler" alloys, following an interdisciplinary approach.

Most studies on catalysts have been conducted by researchers in chemistry. However, catalysts also relate to other research fields. For example, materials science including metallurgy is effective for making and analyzing catalysts, and solid state physics is necessary to understand an electronic structure which is an important factor to catalytic properties. Therefore, an approach from different fields would be effective for catalytic studies.

Heusler alloys (formula: X2YZ) are very popular as magnetic (spintronic), thermoelectric, and shape memory materials. Although they are almost unknown as catalysts, they have great features: 1) having so many possible sets of X, Y, and Z; and 2) elemental substitution is possible (e.g. X2YZ1-xZ'x). Feature 1 expects a discovery of new catalysts and feature 2 enables fine-tuning of catalytic properties.

Takayuki Kojima of Tohoku University, whose PhD involved researching magnetic materials, conceived the use of Heusler alloys as catalysts, and has conducted the research with the An Pang Tsai research group that studies catalysts from a metallurgy viewpoint. They found good catalysts, Co2 (Mn or Fe) Ge, for selective hydrogenation of alkyne, based on feature 1. They also demonstrated the precise control of catalysis based on feature 2.

The discovered catalysts do not include precious noble metals unlike industrial Pd-based catalysts. They may replace the Pd catalysts if the surface area is enlarged enough e.g. by making nanoparticles.

In addition, the tuning of catalysis by elemental substitution is hard to do in ordinary alloys. This discovery not only has practical advantage but will also be useful for investigating mechanisms of catalysis on alloys which are still not fully revealed.

As a next step, the team aims to develop practical catalysts with large surface areas and to reveal the mechanisms of good performance in depth. "We believe that this study will inspire many researchers in all related fields to try to find good Heusler catalysts for various reaction processes," said Kojima.
-end-


Tohoku University

Related Research Articles:


Related Research Reading:

Best Science Podcasts 2019

We have hand picked the best science podcasts for 2019. Sit back and enjoy new science podcasts updated daily from your favorite science news services and scientists.
Now Playing: TED Radio Hour

Setbacks
Failure can feel lonely and final. But can we learn from failure, even reframe it, to feel more like a temporary setback? This hour, TED speakers on changing a crushing defeat into a stepping stone. Guests include entrepreneur Leticia Gasca, psychology professor Alison Ledgerwood, astronomer Phil Plait, former professional athlete Charly Haversat, and UPS training manager Jon Bowers.
Now Playing: Science for the People

#524 The Human Network
What does a network of humans look like and how does it work? How does information spread? How do decisions and opinions spread? What gets distorted as it moves through the network and why? This week we dig into the ins and outs of human networks with Matthew Jackson, Professor of Economics at Stanford University and author of the book "The Human Network: How Your Social Position Determines Your Power, Beliefs, and Behaviours".