Articles tagged with Chemical Bonding
Comprehensive exploration of living organisms, biological systems, and life processes across all scales from molecules to ecosystems. Encompasses cutting-edge research in biology, genetics, molecular biology, ecology, biochemistry, microbiology, botany, zoology, evolutionary biology, genomics, and biotechnology. Investigates cellular mechanisms, organism development, genetic inheritance, biodiversity conservation, metabolic processes, protein synthesis, DNA sequencing, CRISPR gene editing, stem cell research, and the fundamental principles governing all forms of life on Earth.
Comprehensive medical research, clinical studies, and healthcare sciences focused on disease prevention, diagnosis, and treatment. Encompasses clinical medicine, public health, pharmacology, epidemiology, medical specialties, disease mechanisms, therapeutic interventions, healthcare innovation, precision medicine, telemedicine, medical devices, drug development, clinical trials, patient care, mental health, nutrition science, health policy, and the application of medical science to improve human health, wellbeing, and quality of life across diverse populations.
Comprehensive investigation of human society, behavior, relationships, and social structures through systematic research and analysis. Encompasses psychology, sociology, anthropology, economics, political science, linguistics, education, demography, communications, and social research methodologies. Examines human cognition, social interactions, cultural phenomena, economic systems, political institutions, language and communication, educational processes, population dynamics, and the complex social, cultural, economic, and political forces shaping human societies, communities, and civilizations throughout history and across the contemporary world.
Fundamental study of the non-living natural world, matter, energy, and physical phenomena governing the universe. Encompasses physics, chemistry, earth sciences, atmospheric sciences, oceanography, materials science, and the investigation of physical laws, chemical reactions, geological processes, climate systems, and planetary dynamics. Explores everything from subatomic particles and quantum mechanics to planetary systems and cosmic phenomena, including energy transformations, molecular interactions, elemental properties, weather patterns, tectonic activity, and the fundamental forces and principles underlying the physical nature of reality.
Practical application of scientific knowledge and engineering principles to solve real-world problems and develop innovative technologies. Encompasses all engineering disciplines, technology development, computer science, artificial intelligence, environmental sciences, agriculture, materials applications, energy systems, and industrial innovation. Bridges theoretical research with tangible solutions for infrastructure, manufacturing, computing, communications, transportation, construction, sustainable development, and emerging technologies that advance human capabilities, improve quality of life, and address societal challenges through scientific innovation and technological progress.
Study of the practice, culture, infrastructure, and social dimensions of science itself. Addresses how science is conducted, organized, communicated, and integrated into society. Encompasses research funding mechanisms, scientific publishing systems, peer review processes, academic ethics, science policy, research institutions, scientific collaboration networks, science education, career development, research programs, scientific methods, science communication, and the sociology of scientific discovery. Examines the human, institutional, and cultural aspects of scientific enterprise, knowledge production, and the translation of research into societal benefit.
Comprehensive study of the universe beyond Earth, encompassing celestial objects, cosmic phenomena, and space exploration. Includes astronomy, astrophysics, planetary science, cosmology, space physics, astrobiology, and space technology. Investigates stars, galaxies, planets, moons, asteroids, comets, black holes, nebulae, exoplanets, dark matter, dark energy, cosmic microwave background, stellar evolution, planetary formation, space weather, solar system dynamics, the search for extraterrestrial life, and humanity's efforts to explore, understand, and unlock the mysteries of the cosmos through observation, theory, and space missions.
Comprehensive examination of tools, techniques, methodologies, and approaches used across scientific disciplines to conduct research, collect data, and analyze results. Encompasses experimental procedures, analytical methods, measurement techniques, instrumentation, imaging technologies, spectroscopic methods, laboratory protocols, observational studies, statistical analysis, computational methods, data visualization, quality control, and methodological innovations. Addresses the practical techniques and theoretical frameworks enabling scientists to investigate phenomena, test hypotheses, gather evidence, ensure reproducibility, and generate reliable knowledge through systematic, rigorous investigation across all areas of scientific inquiry.
Study of abstract structures, patterns, quantities, relationships, and logical reasoning through pure and applied mathematical disciplines. Encompasses algebra, calculus, geometry, topology, number theory, analysis, discrete mathematics, mathematical logic, set theory, probability, statistics, and computational mathematics. Investigates mathematical structures, theorems, proofs, algorithms, functions, equations, and the rigorous logical frameworks underlying quantitative reasoning. Provides the foundational language and tools for all scientific fields, enabling precise description of natural phenomena, modeling of complex systems, and the development of technologies across physics, engineering, computer science, economics, and all quantitative sciences.
Mannitol outperforms other green additives in slowing re-polymerisation of cellulose-lignin linkages, cutting molecular weight and raising hydrogenolysis monomer yield. The additive forms an average of 28 hydrogen bonds per simulation box, effectively capping sites where carbocations normally form.
Researchers found that a faster rate of binding does not always translate to greater potency, as the study's lead author David Heppner explained. The team proposed a two-step design process balancing inactivation efficiency rates with target selectivity and other parameters to identify promising compounds.
Researchers synthesized three porphyrin-based COF materials with tunable structural distortion, revealing correlations between linker distortion and material properties. The NN-Por-COF photocatalyst exhibits exceptional CO2 reduction performance under simulated industrial flue gas conditions.
A new microscopy technique, SIMIP, combines structured illumination with mid-infrared photothermal detection to achieve high-speed chemical imaging with superior resolution. The method outperforms conventional methods in terms of spatial resolution and chemical contrast.
Researchers developed a new viscoelastic model of enzymes, elucidating the intertwined effects of elastic forces and friction forces on enzyme function. This breakthrough allows proteins to be perceived as soft robots or programmable active matter, revolutionizing our understanding of enzymatic catalysis.
Researchers created a high-performance p-n junction using atomic-level Pt-doped CeO2 and 2D metalloporphyrins nanosheets, significantly boosting charge transfer efficiency. The study achieved a 2.5-fold enhancement in photoelectric performance compared to the conventional system.
Mechanochemistry enables efficient generation of organolithium compounds, solving traditional synthesis challenges with simplified, solvent-free method. The new protocol achieves high conversion rates and reduces handling risks for technicians with limited experience.
Researchers developed AshPhos, a ligand that facilitates the formation of carbon-nitrogen bonds using inexpensive materials. The tool has potential applications in pharmaceuticals, nanomaterials, and degrading PFAS pollutants.
Researchers at Colorado State University have developed a stronger, biodegradable adhesive polymer that can replace common superglues. The new polymer, made from P3HB, offers tunable adhesion strength and is biodegradable under various conditions.
Researchers reaffirm collective bond theory, demonstrating its stability through computational tools. The LiCF3 molecule's unique arrangement challenges traditional understanding of chemical bonds.
Scientists visualized the ultrafast dynamics of molecule dissociation using a new analytical method at BESSY II. The results show that lighter atom groups are ejected first, followed by heavier fragments. This process unfolds rapidly, similar to a 'molecular catapult' effect.
Researchers at Colorado State University have developed a new method to break down PFAS, a group of human-made 'forever' chemicals. The system uses an LED light-based photocatalytic approach that can be used at room temperature, offering a more sustainable and efficient solution than traditional chemical manufacturing processes.
A team of scientists has synthesized a highly complex natural molecule using a novel strategy that functionalizes normally nonreactive C–H bonds. The new method opens up possibilities for synthesizing previously unavailable chemicals, representing a whole new way for chemists to create materials.
Researchers at York University have developed a novel technique to measure gaseous fluorine, revealing that up to 99% of airborne PFAS are unaccounted for. This discovery highlights the need for further research into the sources and environmental implications of PFAS, which can contribute to climate change.
Researchers at Osaka Metropolitan University used CRISPR/Cas9 to create a strain of Euglena that produces wax esters with shorter carbon chains, improving their cold flow and suitability as a biofuel feedstock. This breakthrough could potentially replace petroleum-based production of wax esters with biological sources.
A team of scientists used synchrotron light to explore low-valent uranium compounds, accurately identifying the three-valent oxidation state in uranium. The findings shed new light on actinide bonding and demonstrate how uranium's 5f electrons respond to changes in their environment.
The distribution of outermost shell electrons was experimentally observed in organic molecules, revealing a fragmented electron cloud distribution. This demonstrates the quantum mechanical wave nature of electrons and validates a theoretical model proposed by quantum chemistry.
Scientists have created a polymer that selectively attracts specific substances from solutions when electrically activated, opening the door to sustainable chemical separation. This breakthrough could minimize waste and benefit from renewable energy sources in industrial settings.
Scientists at Hokkaido University have created a new technique for building nanoparticles using enzymes, enabling the production of various nanomaterials with controlled size and properties. This method has potential applications in technology, medicine, and quantum computing.
The researchers investigated photoinduced molecular dynamics involving SCO of the [Fe(Iqsal)2]2+ cations and dimerization of the [Ni(dmit)2]- anions, revealing a transient intermediate state. Quantum chemistry calculations showed that halogen bonds guide sequential dynamics.
Researchers at Harvard University have successfully demonstrated the survival of quantum coherence in a chemical reaction involving ultracold molecules. The team observed intricate quantum dynamics underlying the reaction process and outcome, revealing that quantum coherence was preserved within the nuclear spin degree of freedom throu...
A German-American research team has developed an innovative idea to improve the properties of ultra-thin magnetic materials by reacting them with hydrogen. The researchers have identified three promising candidates that can be magnetically activated by hydrogen passivation, paving the way for new types of electronic components.
Amino acids from lysine, glutamic acid, leucine, and serine exhibit superior curing properties compared to commercial hardeners. This study demonstrates the potential of these bio-based epoxy curing agents as a renewable alternative to petrochemical-derived amines.
Researchers have developed a copper(II)-alkylperoxo complex that can selectively oxidize unactivated alkanes, showcasing exceptional reactivity and paving the way for sustainable technology. By manipulating the solvent environment, the team uncovered the unique properties of their catalyst.
A research team has synthesized a cutting-edge manganese-fluorine catalyst with exceptional oxidizing power, capable of extracting electrons from compounds. The catalyst facilitates efficient electron loss from toxic toluene derivatives, marking a significant breakthrough in catalytic research.
The Juno spacecraft has directly measured charged oxygen and hydrogen molecules from Europa's atmosphere, providing key constraints on the potential oxygenation of its subsurface ocean. The findings suggest that oxygen is continuously produced in the surface ice shell, with an estimated 12 kg per second, which could support habitability.
Chemical reactions were long thought to occur along minimum energy paths. However, researchers have now observed 'roaming' reactions that stray from this path even in highly excited energy states. This discovery has significant implications for understanding atmospheric chemistry and the production of molecular oxygen.
Researchers at IBS achieve real-time observation of molecular ion formation and structural evolution using MeV-UED, unveiling a stable 'dark state' and ring-shaped intermediate ions. This breakthrough advances understanding of ion chemistry and its applications.
A team at UNC-Chapel Hill has developed a new process for synthesizing amides with 100% atom efficiency, employing environmentally friendly cobalt. This approach offers an attractive alternative to traditional methods, which often generate waste and poor atom economy.
Researchers at UNIST have achieved a significant breakthrough in organic semiconductor synthesis by synthesizing a novel molecule called BNBN anthracene. This derivative exhibits unique properties, including precise modulation of electronic properties without structural changes.
Researchers have created biobased polyesters with superior mechanical properties, exceeding those of polyethylene and polypropylene. The new material can be easily recycled and exhibits increased tensile strength and elongation at break with molecular weight.
A research team has developed a technology that selectively targets and eliminates aging cells, contributing to various inflammatory conditions. This approach represents a new paradigm for treating age-related diseases with minimal toxicity concerns.
Researchers at Ohio State University have discovered that ultrasound can break down harmful PFAS compounds in groundwater, rendering them harmless. The technique works by emitting sound waves that compress and heat up the solution, breaking down the stable carbon-fluorine bonds that make up the toxic chemicals.
Researchers at Tokyo Institute of Technology have developed a new design strategy for creating mechanoresponsive materials with high thermal tolerance. The study identified two key factors that determine the thermal stability of these materials: radical-stabilization energy and Hammett constants.
A recent study by Tokyo Tech researchers explores the structure and electron transport properties of molecular junctions. The findings reveal three distinct structures at the junction, corresponding to high- and low-conductivity states, which hold promise for designing novel electronic devices with unique properties.
Scientists at Heidelberg Institute for Theoretical Studies discovered that collagen's weak sacrificial bonds rupture before the main structure, protecting tissue from excessive force. This mechanism helps to localize damage and promote recovery by dissipating mechanical stress and reducing oxidative stress in the body.
A new enzyme, CtdY, has been identified that can break an amide bond, a fundamental type of bond found in proteins. This discovery holds significant promise for the pharmaceutical industry, as it could enable the creation of new anticancer drugs and improve treatment outcomes.
Researchers discovered a way to strengthen polymers by introducing weaker bonds, increasing resistance to tearing up to tenfold. The approach doesn't alter other physical properties and can be used to improve the toughness of other materials like rubber.
Researchers have created a novel method combining DNA scaffolds and acoustic force spectroscopy to characterize individual protein bonds. This innovation allows for the same bond to be re-tested up to 100 times, providing valuable information on how bond strength changes as molecules age.
A University of Virginia-led study challenges traditional understanding of associative polymers' behavior, revealing that reversible bonds slow down polymer movement without creating a rubbery network. This discovery has implications for materials used in sustainability, health, and engineering applications.
Researchers have visualized the C-H bond breakage in alkanes using X-ray light, revealing the role of metal catalysts. The study solves a 40-year-old mystery and provides new insights into catalyst performance. Scientists hope to direct electron flow to develop better catalysts for the chemical industry.
The new method enables the synthesis of BCBs with unprecedented ease through a formal [2+2] cycloaddition, achieving regioselectivity and expanding chemists' access to diverse BCB scaffolds. This breakthrough addresses the challenges of BCB synthesis and offers a promising route for pharmaceutical applications.
Researchers propose a new bonding theory that illustrates how each boron atom satisfies the octet rule and how alternating σ bonds further stabilize the 2D sheet. The theory introduces a new form of resonance, allowing delocalization of σ electrons within the plane.
A team of FSU chemists has developed a new test for detecting biological markers related to several types of cancer. The sensing platform uses gold nanoparticles and peptides labeled with a dye, emitting light when the enzyme MMP-14 is present, allowing researchers to generate data on cancer marker levels
Researchers at UW-Madison developed a model of how catalytic reactions work at the atomic scale, potentially allowing for more efficient catalysts and enormous energy savings. The new framework challenges established assumptions about catalysis, its relevance to non-metal catalysts, corrosion, and tribology.
Researchers at Hokkaido University and Kyushu University have developed a technique to synthesize potential molecular switches from anthraquinodimethanes (AQDs), a group of overcrowded organic molecules. The synthesized derivatives can stably form twisted and folded isomers, as well as other isomeric forms, in different solvents.
Researchers from Japan have synthesized two di-superatomic molecules composed of Ag and evaluated the factors involved in their formation. The study found that a twist between the two icosahedral structures stabilizes the nanocluster by shortening the distance between them. Additionally, the presence of Pd and Pt central atoms was foun...
A team of scientists has designed a molecule that targets the PLpro enzyme in SARS-CoV-2, limiting its replication and hampering the host's immune response. The covalent inhibitor shows promise as a new treatment for COVID-19 and other viral diseases.
Researchers at UChicago develop a more efficient and less toxic method to create MXene material, enabling new applications in electronics and energy storage. The breakthrough allows for the production of large amounts of materials with minimal waste, paving the way for innovative technologies.
Researchers have pushed single-atom vibrational spectroscopy to the level of chemical bonds, enabling precise measurements of point defects in graphene. The study found unique vibrational modes for two types of silicon point defects, with stronger signals for one defect configuration.
Researchers from Tokyo Institute of Technology discovered that amide-to-ester substitutions can significantly improve cyclic peptides' membrane permeability, making them suitable for clinical and therapeutic applications. The study used enhanced sampling molecular dynamics simulations to unravel the mechanism behind this effect.
Researchers developed a chemical scissor to split and stitch nanoscopic layers of two-dimensional materials, opening pathways to sustainable energy technologies. This new process allows for structurally splitting, editing, and reconstituting layered materials with exceptional properties.
New study by Curtin University researchers finds that silicon, gold, and copper can trap and destroy the spike proteins of SARS-CoV-2, likely killing the virus. The materials can be used in air filters, coatings, or fabric to capture coronaviruses and prevent infection.
Researchers from Durham University and University of York successfully twisted molecules to their breaking point, exploring how far the chemical bonding in an aromatic ring can be twisted before its aromatic bonding breaks. The study reveals a balance point where the ring jumps between aromatic structure and two smaller rings.
Scientists at Paderborn University have developed a new catalyst, known as Lewis superacid, to break strong chemical bonds and speed up reactions. This breakthrough enables the conversion of non-biodegradable greenhouse gases into sustainable chemicals.
Researchers at Boston College have developed a new catalytic approach that enables concurrent control of multiple convergences and selectivities in intermolecular amination of allylic carbon-hydrogen bonds in alkenes. The cobalt-based system exploits unique features of homolytic radical reaction to form desired amine products in a high...
Researchers at Rice University have developed a photochemical process that simplifies the manufacture of essential precursors for drugs and agricultural chemicals. By illuminating reagents with visible light, they can form diazides in conditions far gentler than current industrial processes.
Researchers at the University of California, Riverside, have created a novel method to break down per- and polyfluoroalkyl substances (PFAS), also known as 'forever chemicals', in contaminated water. The hydrogen-infusion and UV light-based process achieves high molecular destruction rates without generating unwanted byproducts.
Researchers at UCSF's Cell Design Institute engineered cells with customized adhesion molecules to form complex multicellular ensembles in predictable ways. The discovery represents a major step toward building tissues and organs through regenerative medicine.
Researchers demonstrate the expanded use of a computational method called AFIR, predicting pericyclic reactions with accurate stereoselectivity based on target product molecule information. The technique successfully handles molecules up to 52 atoms and predicts stereochemistry for reactions that break Woodward-Hoffman rules.