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Delight for diastereomer production: A novel strategy for organic chemistry

A team of researchers at The University of Osaka has found a novel method for creating diastereomers, which are structurally identical molecules with different biological activities. Their approach uses a group-14 allylatrane to control the reaction, resulting in the high-yield synthesis of complex molecules.

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Core electron bonding may not always require extreme pressure, study finds

A study by University at Buffalo researchers reveals that some elements' semicore electrons can participate in bonding under just a few gigapascals of pressure, far lower than previously thought. This finding challenges traditional notions of core electron behavior and may have implications for our understanding of planetary evolution.

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Scientists discover a single-electron bond in a carbon-based compound

Researchers from Hokkaido University have discovered a stable single-electron covalent bond between two carbon atoms, validating a century-old theory and paving the way for further exploration of this type of bonding. The discovery was made using X-ray diffraction analysis and Raman spectroscopy.

Simultaneous synthesis and fixing of covalent organic frameworks

Researchers from Tokyo Institute of Technology have developed a novel synthesis method for imine-based COFs, eliminating the need for long reaction times, high temperatures, and Lewis acid catalysts. The method uses an electrogenerated acid as a catalyst, enabling direct fixation of COF films onto electrodes.

Making rubbery materials that can take a beating without losing their bounce

Researchers at Duke University have discovered a way to make rubbery materials up to nine times more durable without compromising their elasticity. This breakthrough could help reduce microplastic pollution from car tires, with estimates suggesting that tire wear alone releases millions of metric tons of debris into the environment eac...

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Customizing T cell-based immunotherapies in a ‘SNAP’

University of Pittsburgh researchers created a universal receptor system allowing T cells to recognize any cell surface target. This enables highly customizable CAR T cell and other immunotherapies for treating cancer and diseases, with potential applications in solid tumors.

What if ceramics were ductile?

Researchers have discovered a way to create ductile ceramics that can exhibit ultimate strength of up to 11 GPa, potentially leading to improved energy efficiency and reduced material usage. However, further studies are needed to scale up the process and apply it to larger materials.

Carbon-carbon covalent bonds far more flexible than presumed

Researchers at Hokkaido University discovered that carbon-carbon covalent bonds can expand and contract flexibly, a new phenomenon that could confer unique properties on organic compounds. The study found that these flexible bonds exhibit reversible expansion and contraction in response to external stimuli.

Living components

Scientists at the University of Freiburg have developed a system to control the dynamics of energy-consuming DNA structures using an artificial chemical approach. The researchers successfully programmed these dynamic systems, enabling them to adapt to different situations and respond to stimuli faster.

Angling for gold

A new model provides an alternative description of atomic-level gold bonding, taking into account bond directionality. The Tersoff potential model allows for reliable covalent bonds between gold atoms and other materials.

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UCLA scientists design new super-hard material

Researchers at UCLA have designed a new super-hard material called rhenium diboride, which is as incompressible as diamond but can be made without high-pressure conditions. This material has the potential to replace some industrial applications of diamond and cubic boron nitride.

Seeing quantum mechanics: Image of orbitals confirms bonding hypothesis

Researchers at Arizona State University have achieved clear images of electron orbitals in Cu2O, verifying the hypothesis that both ionic and covalent bonding occurs in the material. The images show complex formations resembling a dumbbell shape, indicating the presence of metal-to-metal bonds.

The Secret Nature Of Hydrogen Bonds

A US-France-Canada physics collaboration has confirmed that hydrogen bonds in water partially get their identity from covalent bonds within the H2O molecule. This property is a manifestation of quantum mechanics' effects, enabling researchers to improve predictions and advance areas like nanotechnology and superconductors.