They published their work in Energy Material Advances .
“Sodium-ion batteries (SIBs) have shown to be promising candidate to replace lithium-ion batteries (LIBs), because Na is considered ubiquitous on earth,” said paper author Jun Song Chen, with School of Materials and Energy, University of Electronic Science and Technology of China. “However, the larger atomic size of sodium than lithium results in retarded charge diffusion and severe volume change during sodium storage, thus deteriorating the cycling stability and rate performance of SIBs.”
It is crucial to design unique electrode materials with enhanced electrochemical properties to address these drawbacks. Chen explained that transition metal sulfides are attractive for sodium storage among various anode materials. Besides, constructing heterostructures is also effective to enhance the electrochemical properties of active materials, which induces a strong internal electric field at the interface between two components, offering extra driving force for the ions and electrons transport at the boundary.
“Inspired by these ideas, we constructed a unique NiS 2 /FeS heterostructure by a multi-step method,” Chen said. “The as-synthesized NiS 2 /FeS exhibited good sodium storage properties with enhanced high-rate performance of 156 mAh g -1 at 50 A g -1 , and high stable long cyclic retention of 606 mAh g -1 at 5 A g -1 after 1000 cycles, much better than other metal sulfide electrodes.”
The mechanism of the enhanced performance due to heterostructure need to be confirmed. According to Chen, the density functional theory (DFT) calculations were adopted to uncover the reason for the superior battery performance of the NiS 2 /FeS heterostructure.
“The NiS 2 /FeS heterostructure displayed the lowest Na migration energy barrier than pure NiS 2 and FeS, confirming the fastest Na diffusion at the interface. In addition, NiS 2 /FeS demonstrated the highest adsorption energy, implying that the heterostructure provided the most stable adsorption of Na, thus offered improved structure stability upon repeated charge/discharge. Furthermore, the calculated total DOS (TDOS) showed that the NiS 2 /FeS heterostructure possessed the maximum charge density near the Fermi level, indicating that the NiS 2 /FeS possessed enhanced electrical conductivity,” Chen said. “As the DFT calculations showed, the NiS 2 /FeS heterostructure significantly enhanced the electrical conductivity, kinetic diffusion of Na + and structure stability, leading to high reversible capacities and superior cycling stability, which matched well with the experimental results.”
The researchers also explored the potential for commercial applications of as-synthesized NiS 2 /FeS. “We investigated the full-cell performance by assembling devices using Na 3 V 2 (PO 4 ) 3 (NVP) as the cathode and NiS 2 /FeS as the anode,” Chen said. “As-assembled NVP||NiS 2 /FeS full cell exhibited good electrochemical performance, with good commercial potential.”
This work provides an effective approach to design composite functional materials with heterostructures for different applications with improved properties.
Chen is also affiliated with the institute for Advanced Study, Chengdu University, and Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China.
Other contributors include Dong Yan, Shuhao Xiao, Xinyan Li, Hanchao Li, Rui Wu, Xiaobin Niu, all with School of Materials and Energy, University of Electronic Science and Technology of China; Jinxia Jiang, Chongqing Medical and Pharmaceutical College; Qiyuan He, Department of Materials Science and Engineering, City University of Hong Kong. Jiaqian Qin, Center of Excellence on Advanced Materials for Energy Storage, Metallurgy and Materials Science Research Institute, Chulalongkorn University. Dong Yan is also affiliated with Institute for Advanced Study, Chengdu University.
The authors appreciated the funding support from the National Key R&D Program of China (No. 2021YFB2401900).
###
Reference
Authors: DONG YAN, SHUHAO XIAO, XINYAN LI, JINXIA JIANG , QIYUAN HE, HANCHAO LI, JIAQIAN QIN, RUI WU, XIAOBIN NIU, AND JUN SONG CHEN
Title of original paper: NiS 2 /FeS Heterostructured Nanoflowers for High-Performance Sodium Storage
Journal: Energy Material Advances
DOI: 10.34133/energymatadv.0012
Affiliations:
1 Institute for Advanced Study, Chengdu University, Chengdu 610106, P. R. China.
2 School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, P. R. China.
3 Chongqing Medical and Pharmaceutical College, Chongqing 401331, P. R. China.
4 Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong, China.
5 Center of Excellence on Advanced Materials for Energy Storage, Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330, Thailand.
6 Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China, Shenzhen, P. R. China.
About the author:
Professor Chen is dedicated to the synthesis of metal oxides/sulfides/selenides-based functional materials with specific nanostructures, and to explore the application of these materials in energy storage devices, such as sodium-ion batteries. He has published more than 90 academic papers in international journals of materials and chemistry with more than 10000 SCI citations, and many of them were selected as ESI highly cited papers, with an H-index of 47.
Energy Material Advances
Experimental study
Not applicable
NiS2/FeS Heterostructured Nanoflowers for High-Performance Sodium Storage
31-Jan-2023
The authors declare that they have no competing interests.