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Anions matter

Researchers found that sulfate anions significantly improve the performance of zinc-ion hybrid capacitors, enabling them to operate for over nine months and showing excellent flexibility. The study highlights the importance of electrolyte anions in enhancing the power and energy density of capacitors.

SourceWiley·JournalAngewandte Chemie International Edition·DateNov 13, 2020

Smart fluorescent molecular switches based on boron-based compounds

Scientists have created extremely stable fluorescent molecular switches that can be controlled electrochemically, using a particular redox active anion. These systems show large reversible fluorescence modulation and are soluble in many organic solvents, making them suitable for applications in biosensing, imaging, and drug delivery.

SourceUniversitat Autonoma de Barcelona·JournalChemistry - A European Journal·DateOct 28, 2020

Solvation rearrangement brings stable zinc/graphite batteries closer to commercial grid storage

A research team at Chinese Academy of Sciences has developed a new solvation strategy to enhance the oxidation stability of carbonate-based electrolytes in Zinc/Graphite batteries. This breakthrough could lead to high-voltage cells with low self-discharge and long shelf life, making them suitable for large-scale grid storage.

SourceChinese Academy of Sciences Headquarters·JournalAngewandte Chemie International Edition·DateSep 10, 2020

Electron-gun simulations explain the mechanisms of high-energy cosmic rays

Chinese physicists develop mathematical equations and computer simulations to model photodetachment of negative ions via photons, simulating cosmic rays' collisions with planets. The speed of a moving surface significantly affects the chances of photodetachment, with Chloride (Cl-) ions being less prone than hydrogen (H-) ions.

SourceSpringer·JournalThe European Physical Journal D·DateFeb 6, 2019

A closed cage-like molecule that can be opened

Researchers at Kanazawa University designed a metallomolecular cage that can be opened through disulfide exchange reactions with thiolate anions. The cage's 'hatch' opens to allow cesium ions to enter, demonstrating its potential as a molecular container with on-demand guest uptake/release systems.

SourceKanazawa University·JournalChemistry - A European Journal·DateJan 30, 2019

Doubly-excited electrons reach new energy states

Physicists have characterised higher energy levels reached by electrons in resonance with positronium ions, a complex three-particle system. The new model provides guidance for experimentalists to observe these resonant structures, potentially leading to breakthroughs in atomic and nuclear physics.

SourceSpringer·JournalThe European Physical Journal D·DateNov 13, 2018

How ions gather water molecules around them

Researchers from Ruhr-Universität Bochum used terahertz spectroscopy to gain new insights into the hydration shell of charged particles. They found that hydration shells with a size between two and 21 water molecules were determined for more than 37 salts, depending on the ion's size and valency.

SourceRuhr-University Bochum·JournalAngewandte Chemie International Edition·DateAug 9, 2018

Brewing up Earth's earliest life

A team of planetary scientists from MIT has identified large concentrations of sulfidic anions in shallow lakes on early Earth, which may have sped up the chemical reactions required to convert simple prebiotic molecules into RNA. This finding fundamentally changes our knowledge of early Earth and its potential role in the origin of life.

SourceMassachusetts Institute of Technology·JournalAstrobiology·DateApr 9, 2018

A new way to find better battery materials

Researchers at MIT have developed a new approach to designing battery materials that could lead to improved ion mobility and reduced reactivity. By analyzing the lattice properties of solid materials, they found a correlation between vibrational frequency and conductivity, allowing for accurate predictions of material properties.

SourceMassachusetts Institute of Technology·JournalEnergy & Environmental Science·DateMar 26, 2018

Siberian scientists suggested a new method for synthesizing a promising magnetic material

Scientists from Siberian Federal University have developed a new method for synthesizing iron-dysprosium garnet, a promising magnetic material. This method uses anion resin exchange precipitation, allowing for the production of materials with controlled properties and no high temperatures or aggressive substances.

SourceSiberian Federal University·JournalMaterials Science and Engineering A·DateJan 23, 2018

'Ion billiards' cue novel material synthesis method

Researchers at Hokkaido University have developed a novel material synthesis method that utilizes protons to introduce ions into host materials. This liquid-free process enables the homogenous introduction of various ions, such as lithium and sodium, into tantalum sulfide, maintaining its crystallinity.

SourceHokkaido University·JournalJournal of the American Chemical Society·DateNov 16, 2017

Super cement's secret

Scientists create a unique cement semiconductor by introducing electron anions, which transforms its properties from insulator to transparent conductor. The material's glass equivalent has a lower glass transition temperature, allowing for greater control over the formation process.

SourceDOE/Pacific Northwest National Laboratory·JournalProceedings of the National Academy of Sciences·DateAug 29, 2016

Electron scavenging to mimic radiation damage

A new study uses electron scavenging to mimic radiation damage in a material called trifluoroacetamide (TFAA), triggering selective reactions and creating specific negative ions. The findings provide insights into the effects of low-energy electrons on biological tissues, potentially leading to better protection methods.

SourceSpringer·JournalThe European Physical Journal D·DateJun 30, 2016

An elusive molecule -- finally revealed

Researchers at the University of Arizona have discovered ethylenedione, a diradical molecule that was previously thought to be elusive. The discovery has significant implications for understanding radical molecular species, industrial processes, and potentially even atmospheric chemistry and climate modeling.

SourceUniversity of Arizona·JournalAngewandte Chemie International Edition·DateJul 13, 2015

In water as in love, likes can attract

A team led by chemist Richard Saykally and theorist David Prendergast has observed contact pairing between guanidinium cations in aqueous solution, governed by water-binding energy. This phenomenon challenges the long-held assumption that like charges repel, suggesting a new understanding of ion interactions in water.

SourceDOE/Lawrence Berkeley National Laboratory·JournalThe Journal of Chemical Physics·DateSep 18, 2013

A new tool for molecular architects

A team of chemists at the University of Geneva has developed a rare halogen bond that can transport anions across phospholipid bilayer membranes, similar to cellular structures. This discovery has significant implications for medical applications, particularly in treating diseases linked to ion transport issues.

SourceUniversité de Genève·JournalNature Communications·DateJun 20, 2012

When ions get closer

Researchers discovered a previously unknown phenomenon in quantum plasmas, enabling positively charged particles to form atom-like structures. This discovery accelerates current conduction, potentially revolutionizing nanotechnology and applications such as micro-chips and semiconductors.

SourceRuhr-University Bochum·JournalPhysical Review Letters·DateMar 26, 2012

The interplay of dancing electrons

Researchers from the University of Gothenburg developed a new method to study electron interactions in negative ions, crucial for understanding phenomena like superconductors. This knowledge may also shed light on the origin of life and the chemical reactions that occurred in space.

SourceUniversity of Gothenburg·JournalReview of Scientific Instruments·DateNov 29, 2011