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Tethered chem combos could revolutionize artificial photosynthesis

Scientists at Brookhaven National Laboratory have developed a new approach to artificial photosynthesis that improves the efficiency of capturing light and splitting water molecules to produce hydrogen fuel. The system uses molecular tethers to attach chromophores to catalysts, allowing for stable and efficient electron transfer and ge...

SourceDOE/Brookhaven National Laboratory·JournalThe Journal of Physical Chemistry C·DateNov 4, 2019

Nanoceramics from the ball mill

Researchers have found a way to produce corundum nanoparticles using simple mechanochemistry in a ball mill, which could lead to more robust and easier-to-manufacture automotive catalysts and ceramics. The production method involves grinding lumps of boehmite in a ball mill for 3 hours and then heating them briefly.

SourceMax-Planck-Gesellschaft·JournalScience·DateOct 30, 2019

Tungsten suboxide improves the efficiency of platinum in hydrogen production

Researchers have developed a new strategy to enhance catalytic activity using tungsten suboxide as a single-atom catalyst, significantly improving hydrogen evolution reaction performance. The study found that the support effect of tungsten suboxide enhances platinum's mass activity for hydrogen evolution by up to 16.3 times.

SourceThe Korea Advanced Institute of Science and Technology (KAIST)·JournalAngewandte Chemie International Edition·DateOct 28, 2019

Turning plastic trash into treasure

Researchers at Northwestern University have developed a new catalytic method to upcycle single-use plastics into high-quality liquid products, such as motor oils, lubricants, and cosmetics. This breakthrough improves current recycling methods, producing fewer greenhouse gases and toxic byproducts, while contributing to a circular economy.

SourceNorthwestern University·JournalACS Central Science·DateOct 23, 2019

Study shows a much cheaper catalyst can generate hydrogen in a commercial device

Researchers have developed a cheap catalyst that can generate hydrogen gas for hours in a commercial device, offering a potential solution to reduce the cost of producing this important industrial chemical. The catalyst, based on cobalt phosphide nanoparticles, was tested in a commercial electrolyzer and operated well over 1,700 hours.

SourceDOE/SLAC National Accelerator Laboratory·JournalNature Nanotechnology·DateOct 14, 2019

How to make biocatalysts immortal

A research team from Bochum and Marseille has developed a self-defence mechanism in biocatalysts that shields them from oxygen, extending their service life up to 22,000 years. The new design uses tiny molecular spheres to create an extremely thin protective film that maintains efficiency.

SourceRuhr-University Bochum·JournalJournal of the American Chemical Society·DateOct 9, 2019

Shocking heat waves stabilize single atoms

Researchers at Argonne National Laboratory successfully stabilized single atoms using record-high temperatures of up to 2000 K. The method enables the creation of stable single atom catalysts, which can remain in their place for unprecedented periods of time, maximizing atom-use efficiency and improving catalytic performance.

SourceDOE/Argonne National Laboratory·JournalNature Nanotechnology·DateSep 26, 2019

Nanocatalyst makes heavy work of formic acid

Researchers at Osaka University have developed a palladium-based alloy nanocatalyst that promotes the selective production of deuterium isotope compounds from formic acid. The catalyst enables a cost-effective and scalable process for producing these gases, which are useful in fine chemical production and research applications.

SourceOsaka University·JournalNature Communications·DateSep 25, 2019

Big game hunting for a more versatile catalyst

Researchers at Harvard University have discovered the architecture of a copper-nitrenoid complex that can transform carbon-hydrogen bonds into valuable building blocks for chemical synthesis. This breakthrough could lead to more efficient and sustainable production methods for pharmaceuticals, household products, and other chemicals.

SourceHarvard University·JournalScience·DateSep 12, 2019

Extracting clean fuel from sunlight

Researchers at Arizona State University have developed new technologies that combine light-gathering semiconductors and catalytic materials to produce clean fuel. The technologies use solar energy to drive chemical reactions capable of producing fuels, which store the sun's energy in chemical bonds.

SourceArizona State University·JournalJournal of the American Chemical Society·DateSep 3, 2019

Single atoms as catalysts

Researchers at Vienna University of Technology have successfully incorporated individual metal atoms into a surface, enabling precise control over their chemical behavior. This breakthrough enables the creation of more efficient catalysts for environmentally friendly processes.

SourceVienna University of Technology·JournalAngewandte Chemie·DateSep 2, 2019

A new way to make valuable chemicals

Researchers developed a new process to form high-value chemicals called amides by coupling carbon and nitrogen bonds in an electrochemical reaction. This breakthrough enables the production of useful substances in various industries, including pharmaceuticals.

SourceUniversity of Delaware·JournalNature Chemistry·DateAug 26, 2019

Oddball edge wins nanotube faceoff

The Rice team found that the Janus configuration, with a half-circle of zigzags opposite six armchairs, allows for tight contact with solid catalysts and preserves continuous nanotube growth. This discovery advances understanding of growth mechanisms and has implications for designing efficient catalysts.

SourceRice University·JournalACS Nano·DateJul 29, 2019

A catalyst for sustainable methanol

Scientists at ETH Zurich developed a new catalyst technology converting CO2 and hydrogen directly into methanol, enabling the production of fuels and chemicals from renewable resources. The approach has significant potential to close the carbon cycle and produce sustainable methanol on an industrial scale.

SourceETH Zurich·JournalNature Communications·DateJul 29, 2019

How nature builds hydrogen-producing enzymes

Researchers from Ruhr-Universität Bochum and University of Oxford reveal the mechanism behind activating hydrogenases, complex enzymes that produce hydrogen efficiently. The discovery sheds light on the process of introducing a chemical cofactor into the enzyme's active center.

SourceRuhr-University Bochum·JournalProceedings of the National Academy of Sciences·DateJul 24, 2019

Improving the odds of synthetic chemistry success

University of Utah chemists developed an algorithm that analyzes previous chemical reaction data to predict hypothetical reactions, narrowing the range of conditions needed for successful synthesis. The model successfully predicted outcomes for various reactions, offering a time-saving solution for pharmaceutical and materials research.

SourceUniversity of Utah·JournalNature·DateJul 17, 2019

Activity of fuel cell catalysts doubled

Researchers at TUM have developed platinum nanoparticles that double the performance of current fuel cells. The particles are about one nanometer big and contain approximately 40 platinum atoms, resulting in high mass activity. This breakthrough could lead to widespread adoption of fuel cells in electric cars.

SourceTechnical University of Munich (TUM)·JournalAngewandte Chemie International Edition·DateJul 3, 2019