Articles tagged with Catalysis
A research team has discovered that protein misfolding is a major cause of efficiency problems when using split inteins to produce proteins. By introducing specific mutations to the intein fragment, they were able to suppress aggregation and increase productivity.
Researchers engineered conjugation of donor and acceptor units in covalent organic frameworks to enhance photocatalytic H2O2 production. USTB-46 achieved a high yield of 8274 mmol g−1 h−1, attributed to optimized light absorption, thermodynamic catalytic activity, and compatible D-A units.
RMIT University's PYROCO technology converts treated sewage into a carbon-rich product called biochar, which acts as a catalyst to produce phenol-rich bio-oil. The technology has been applied to several circular economy applications and offers a sustainable way to reduce carbon dioxide emissions.
A new probing technique allows researchers to observe the surface of iron reacting with oxygen in real time, revealing key factors that influence catalyst performance. This breakthrough could lead to more efficient development of new materials and systems.
Researchers have developed a method to prepare copper single atoms using a nano-constrained environment, resulting in improved catalytic performance. The new catalyst exhibits high activity and selectivity in CO2 cycloaddition reactions.
A team of researchers from Oregon State University and China has improved the chemical reaction that underpins a range of commercial and industrial goods. They created single-atom catalysts that demonstrate excellent catalytic activities, leading to record high activities and excellent stabilities in hydrogenation reactions.
Scientists have developed a method to produce propylene through nonoxidative propane dehydrogenation (PDH) using light-driven nanoparticles. This process could reduce energy demands and emissions in the chemical industry, paving the way for a more sustainable future.
Researchers developed a new viscoelastic model of enzymes, elucidating the intertwined effects of elastic forces and friction forces on enzyme function. This breakthrough allows proteins to be perceived as soft robots or programmable active matter, revolutionizing our understanding of enzymatic catalysis.
Researchers develop a novel 'zeolite blending' method to synthesize CON-type zeolites with unprecedentedly high aluminum content. This approach enables precise control over Al content, opening possibilities for catalyst development in various industrial applications.
Researchers at University of Nottingham use transmission electron microscopy to observe real-time growth and contraction of Palladium nanoparticles. The study reveals a unique cyclic process where nanoparticles grow, dissolve, and re-grow, potentially leading to the development of new efficient catalysts.
Scientists have developed a novel synthesis method for trivalent phosphorus compounds, leveraging an adduct-catalyzed tandem electro-thermal approach to produce high-yielding organophosphorus compounds with improved efficiency and selectivity. The approach also enables the in-situ consumption of renewable energy sources.
Researchers developed a strategy to regulate hydrogen bond networks at electrolyte-electrode interfaces, accelerating proton transfer in CO2 reduction reactions. The approach involves introducing extra catalytic centers, such as cubic phase molybdenum carbide, to enhance water dissociation and facilitate proton generation.
Researchers developed a dual bio-/photo-catalytic system for achieving enantioselective hydroamination of enamides, producing diverse enantioenriched vicinal diamines. The system utilizes green light to initiate nitrogen-centered radical reactions, achieving high yields and enantiomeric excess.
Researchers from PolyU have discovered the precise location of aluminium atoms in zeolite frameworks, enabling the design of more efficient and stable catalysts. This breakthrough has wide-reaching implications for industries such as renewable energy and pollution control.
Researchers discovered that tetrahedral Co²⁺ is preferentially incorporated into the lattice in early stages of Co(OH)₂ formation. The retention of tetrahedral Co²⁺ is linked to effective OH⁻ concentration, paving the way for optimized synthesis methods and enhanced material properties.
Researchers have developed cost-effective and efficient water-splitting catalysts using cobalt and tungsten, which surprisingly increase in performance over time. The unique self-optimization process involves changes in the chemical nature of the catalyzing oxide, leading to improved activity and reduced overpotentials.
Researchers at Northwestern University have developed a solvent-free process to break down polyethylene terephthalate (PET) plastics using a molybdenum catalyst and ambient air moisture. The process converts PET into monomers, the building blocks for plastics, paving the way for more sustainable plastic recycling.
Researchers at Yale University have discovered a new method to convert carbon dioxide (CO2) into formate, a chemical compound used in preservatives and pesticides. The breakthrough could lead to the development of alternative fuels and sustainable products, addressing environmental concerns.
Researchers at Tohoku University found that incorporating gadolinium into iron-doped nickel oxide markedly enhances oxygen evolution reaction activity. Gd-doping reduces theoretical overpotentials and demonstrates favorable kinematics, leading to remarkable long-term stability and robust performance in water electrolysis.
A POSTECH research team has developed a new catalyst using aluminum, improving the performance of hydrogen production in alkaline water electrolysis by approximately 50%. The aluminum catalyst maintained high current density and excellent stability, making it suitable for large-scale hydrogen production.
Researchers at TU Wien have developed a process to recover nickel from spent batteries and convert it into a nanocatalyst that reduces CO2 into valuable methane. This innovation has the potential to reduce waste and provide a sustainable fuel source.
Researchers at IISc have developed an onsite production strategy for hydrogen peroxide using a zinc-air battery. The process generates H2O2 while degrading toxic dyes, making it a low-cost and highly energy-efficient method. This approach has the potential to be scalable and can be used in various applications.
Scientists have uncovered the molecular structure of Mycoplasma mobile's twin motors that power its gliding ability, using cryo-electron microscopy. The complex structure reveals a new mechanism by which energy from ATP hydrolysis is converted into motility.
A study by the Advanced Institute for Materials Research found that tin monoxide (SnO) electrocatalysts can produce both formic acid and carbon monoxide in significant amounts. The research team identified key structural changes that influence product distribution, providing insights into optimizing electrocatalyst performance.
Researchers from NUS have pioneered a new catalytic transformation that converts epoxides into fluorinated oxetanes, a coveted class of drug molecules. The discovery potentially opens the door to new medicines and offers a reliable route to incorporate these motifs into the design of novel small-molecule therapeutics.
The newly synthesized monolayer Ti3C2Tx transforms photocatalytic bioaerosol disinfection at the catalyst-cell interface. The material achieves a sterilization efficiency of 3.3 log in just 12.8 seconds, far exceeding traditional TiO2.
Researchers at HZB and HU Berlin have discovered a high-spin manganese centre, crucial for molecular oxygen formation in natural photosynthesis. The discovery, made possible by BESSY II's unique experimental capabilities, sheds light on the complex process of photosynthesis.
Research reveals oxygen vacancies in ZrO2 catalysts increase catalytic performance in propane dehydrogenation. The vacancies create a localized electronic state that promotes the activation of C-H bonds in propane.
Researchers have made progress in understanding the dynamics of Cu-based catalysts in electrochemical CO2 reduction. The study highlights the importance of structural factors and cation effects on catalytic performance.
Researchers at Tohoku University developed a novel method to accelerate the development of single-atom catalysts (SACs) for robust and efficient water purification. Using data-driven predictions, they identified an optimized Fe-SAC with high decontamination performance, breaking down pollutants in water.
Researchers at the University of Minnesota discovered a new method to selectively burn one molecule in a mixture of hydrocarbons using a bismuth oxide catalyst. This process, called chemical looping combustion, could help remove pollutants and improve industrial processes with high energy efficiency.
Researchers uncover a novel reaction pathway in weak-binding metal-nitrogen-carbon single-atom catalysts, contradicting the traditional Sabatier principle. This discovery offers new insights into their exceptional catalytic behavior.
Researchers from DGIST develop a catalytic technology that effectively removes additives hindering plastic recycling, using sugar-derived cyclodextrin. This breakthrough provides an alternative to complex processes and suggests expandability into environmental remediation.
A new nanomedicine, ZnDHT NM, selectively targets cancer stem-like cells (CSCs) and tumor cells, promoting CSC differentiation while inhibiting EMT. This approach also leads to the release of toxic compounds in tumor cells, inducing apoptosis/ferroptosis pathways.
Researchers at Texas A&M University have developed a new catalytic graphitization technology to convert petroleum coke into graphite, reducing emissions and cost associated with conventional synthetic graphite production. The process uses lower temperatures and shorter times, making it more sustainable and efficient.
Researchers at Stanford University have illuminated how enzymes speed up life-sustaining biochemical reactions so dramatically. By understanding the chemical and physical interactions responsible for enzyme's enormous reaction rates, scientists may be able to design new enzymes that rival those found in nature.
Dr. Denzil Moodley, a leading expert in Fischer-Tropsch technology, joins HZB to accelerate the development of sustainable aviation fuels. The appointment strengthens the partnership between HZB and Sasol, combining cutting-edge research with practical industrial insights.
Researchers have developed a novel solid catalyst to efficiently reclaim materials from epoxy products, including carbon fibers and glass fibers. The process uses lower temperatures than traditional methods, reducing energy requirements and making the recovery of materials more environmentally friendly.
Researchers developed AshPhos, a ligand that facilitates the formation of carbon-nitrogen bonds using inexpensive materials. The tool has potential applications in pharmaceuticals, nanomaterials, and degrading PFAS pollutants.
Researchers have designed an innovative iron-based catalyst that can produce ammonia at a rate three times higher than the current industry standard. The new catalyst, made from earth-abundant materials, enables efficient industrial production of ammonia, a crucial chemical for fertilizers and sustainable agriculture.
A cross-sectional study found that detained immigrants experience high rates of poor health, mental illness, and posttraumatic stress disorder (PTSD). Longer detention periods are associated with higher health harms, emphasizing the need for improved immigration detention conditions.
Researchers have developed a Zn-decorated GaN nanowire catalyst that efficiently converts CO2 and H2O into methane and hydrogen peroxide under light irradiation. The catalyst achieves high conversion rates with 93.6% selectivity and maintains activity for over 80 hours, providing a practical solution for sustainable fuel production.
Researchers from Dalian Institute of Chemical Physics summarize the catalytic performance of various metal-based catalysts in CO2-assisted oxidative dehydrogenation of light alkanes. The review identifies catalyst systems with great potential for further development and elucidates the mechanisms of CO2 activation and transformation.
Researchers have discovered a new strategy to efficiently create structural motifs with two carbonyl groups along a carbon chain. The use of hydrazones as key functional groups enables the targeted reversal of polarity, solving a major challenge in chemistry.
Researchers developed a nano-heterostructure catalyst featuring MoS2-confined Rh-Zn atomic pairs, achieving high selectivity and productivity in photo-driven methane carbonylation. The catalyst enables efficient conversion of methane to acetic acid under mild conditions.
Researchers developed a method to extract CO2 from flue gases with as little as 5% concentration using a superactive nickel-copper catalyst. The process involves adjusting electrical potentials and electrolyte, allowing access to previously unusable CO2 sources.
Researchers developed a robust, thermally stable, and impurity-tolerant aluminum-based catalyst system for polylactide production. The new system exhibits high activity at low catalyst concentrations and can produce colorless semicrystalline poly(lactic acid) under industrially relevant conditions.
The SNU-Hyundai joint research developed an innovative analysis technique, e-LCTEM, to rapidly evaluate fuel cell catalyst durability and identify degradation mechanisms. This technology accelerates durability testing, reducing evaluation costs and paving the way for more efficient catalyst verification.
A novel chemoenzymatic cascade strategy enables the sustainable production of high-value chiral aspartic acids from furfural and waste. The process combines photoelectrocatalytic oxidation with biocatalysis, yielding a significant yield of maleic acid and fumaric acid.
Researchers explore interface engineering strategies to optimize alkaline electrolysis HER process, including bifunctional catalysts, built-in electric fields, and hydrogen spillover effects. The review highlights the need for precise methods to tailor hetero-interfaces and characterize water molecules at the catalyst/solution interface.
Researchers developed an automated analytical method to analyze single atom catalysts, which could lead to more efficient fuel production and sustainable energy. The new tool, called MS-QuantEXAFS, automates the analysis process, reducing time from days to months.
Scientists developed a method to densely populate and precisely position isolated Pt atoms on α-Fe nanoparticles, enhancing the intrinsic activity of hydrogenation reactions. This achievement resolves the activity-selectivity trade-off in hydrogenation reactions by fine-tuning the coordination environment of the active site.
A new study has developed a platinum-based catalyst that can efficiently convert CO2 into valuable chemicals, with improved stability in acidic media. The catalyst, PtNPs@Th, was created by encapsulating thionine molecules within platinum nanocrystals, resulting in enhanced catalytic activity and corrosion resistance.
Researchers develop coprecipitation method to create free-standing porous carbon fibers with Zn single atom sites and molybdenum carbide clusters, enhancing iodine adsorption and electrocatalytic activity. The resulting zinc-iodine batteries demonstrate high specific capacity and good capacity retention.
Researchers developed a heterogeneous catalytic system to depolymerize polyurethane waste into diamines, diols, and lactones. The resulting intermediates were then converted into functional polymers, including energy-storage-capable polyimide and chemically recyclable polylactone.
Researchers used time-delayed laser pulses to capture electric and magnetic field vectors of surface plasmon polaritons, revealing a meron pair's spin texture. The study demonstrates stable spin structures despite fast field rotations.
Researchers at University at Buffalo have developed a plasma-electrochemical reactor that produces ammonia from nitrogen in the air and water, with no carbon footprint. The process uses renewable electricity and can be scaled up to meet industrial demands.
Scientists have engineered a 'super-powered' bacterium, E. coli, with a polymer coating to increase its industrial productivity and sustainability. The new strain enhances catalysis capabilities, reducing energy use and making production more environmentally friendly.
Researchers have developed a new X-ray technique called XL-DOT that visualizes crystal grains, grain boundaries, and defects in materials, enabling previously inaccessible insights into functional materials. The technique uses polarized X-rays to probe the orientation of structural domains in three dimensions.
Researchers at HZB developed a new P2X catalyst requiring less iridium than commercial materials, showing remarkable stability and different mechanisms for oxygen evolution. The study provides valuable information about catalyst performance and stability.