Articles tagged with Chemical Reactivity
Scientists have discovered a new method to enable oxidative addition of aryl halides at group 13 elements using visible light. This breakthrough could lead to sustainable catalytic processes reducing the need for rare and expensive transition metals.
Researchers at Texas A&M University develop a laser technique called TRIP to directly measure quantum forces shaping proteins, enabling accurate prediction of how pharmaceutical drugs interact with them. This breakthrough could lead to the design of medicines tailored to specific diseases, revolutionizing precision medicine.
Researchers at the University of Missouri have created a more efficient method for manufacturing computer chips using ultraviolet-enabled atomic layer deposition (UV-ALD). This approach reduces the number of manufacturing steps, saving time and materials, while also minimizing the use of harmful chemicals.
Researchers at TU Wien have developed a new electrochemical synthesis method for MXene, overcoming the difficulties of producing this 'miracle material'. The new process uses electricity instead of toxic hydrofluoric acid, allowing for safer and more sustainable production.
Research shows that highly reactive components in particulate matter disappear within hours, leading to inaccurate estimates of their presence and potential health risks. This discovery highlights the need for more accurate measurements and better protective measures.
A team of researchers has developed a molecular system that enables the controlled release of iron, using a carbon nanohoop and ferrocene as the iron carrier. The system allows for the release of Fe2+ ions upon activation with green light.
Researchers used X-ray light to analyze the structure of 2-thiouracil, a substance with medically relevant properties. The study found that UV radiation causes the molecule to bend, resulting in the protrusion of the sulfur atom and making it reactive.
Researchers at University of Wúrzburg have synthesized a molecule with a boron-carbon triple bond, a long-sought achievement in chemistry. The new molecule, called a boryne, exists as an orange solid at room temperature and has sparked interest in its reactivity.
Researchers utilized muon spin rotation spectroscopy to investigate the regioselective muoniation of peri-trifluoromethylated 12-phosphatetraphene 1, revealing a highly reactive muoniated radical at the phosphorus site. The study provided detailed insights into the structure and dynamics of the radical.
Researchers synthesized optically active conducting polymers through physical methods using liquid crystals as solvents, achieving asymmetric (chiral) living polymerization. The resulting polyisocyanides exhibited optical activity and properties of twisted-bend nematic liquid crystal.
Researchers developed a novel coating material that captures the brilliance of structural colors using melanin particles, producing non-iridescent color even when viewed from different angles. The coatings displayed a contact angle of over 160 degrees, monochromatic hues, and a self-cleaning surface.
Researchers developed a sodium-doped amorphous silicon-boron-nitride catalyst that enhances reactivity and stability under harsh conditions. The material enables reversible hydrogen adsorption and desorption, making it a promising catalyst for sustainable industrial reactions.
Researchers from the University of Pennsylvania School of Engineering and Applied Science have discovered a previously unreported enzyme that catalyzes the creation of cyclopentachromone-containing compounds. This breakthrough could potentially lead to the development of new pharmaceuticals for treating cancer and inflammation.
Chemists at Emory University and Caltech have developed a revolutionary strategy for functionalizing carbon-hydrogen bonds, transforming low-cost materials into complex building blocks of organic chemistry. The breakthrough enables the synthesis of complex natural molecules with antimicrobial properties.
A University of Virginia-led research team has developed new protective coatings that allow turbine engines to run at higher temperatures before components begin to fail. The coatings were created using rare earth oxides and have shown improved performance without complex multi-layer coatings.
The Rice-led MURI project aims to develop innovative single-atom reactor systems and analyze various chemical processes of strategic importance to the DOD. The researchers, led by Naomi Halas, seek to improve energy efficiency and reduce protocol intensity in chemical reactions.
A Montana State University researcher has developed nano-scale materials that can convert carbon dioxide into chemical building blocks, marking a potential step forward in reducing atmospheric CO2. The materials mimic enzymes and have the ability to selectively capture CO2 from the air.
A team of researchers from the University of Maryland has developed a novel way to produce and observe carbenes, a class of highly reactive molecules necessary for life. They successfully formed a carbene called hydroxymethylene (HCOH) by breaking down methanol with pulses of ultraviolet radiation.
Researchers at The University of Manchester have developed a new ruthenium catalyst, proven to be long-term stable in air while maintaining high reactivity. This breakthrough enables the user to run simultaneous reactions, streamlining optimisation procedures and reducing waste accumulation.
Researchers developed mesoporous metal oxides on flexible materials using synergetic effect of heat and plasma at lower temperatures. The devices can withstand bending thousands of times without losing energy storage performance.
Researchers at the University of Adelaide have developed a new nanocomposite electrocatalyst that enables lithium-sulphur batteries to achieve full charge/discharge in less than five minutes. This breakthrough has significant implications for high-performance battery systems and energy storage technologies.
Researchers have developed a copper(II)-alkylperoxo complex that can selectively oxidize unactivated alkanes, showcasing exceptional reactivity and paving the way for sustainable technology. By manipulating the solvent environment, the team uncovered the unique properties of their catalyst.
Researchers at Carnegie Mellon University have created a new machine learning model that can simulate reactive processes in diverse organic materials and conditions. The model, called ANI-1xnr, performs simulations with significantly less computing power and time than traditional quantum mechanics models.
Researchers at Politecnico di Milano have designed a hydrogel with specific characteristics using supramolecular chemistry and crystallography. The study showed that the interactions between an amino acid and bioactive molecules can be identical in both solid and aqueous states.
Researchers at Kyoto University developed a new reactant demonstrating efficacy on proteins with drug-resistant mutations. The new inhibitor, ArNASA, reacts with lysine residues and is highly stable in physiological environments.
Researchers at Xi'an Jiaotong-Liverpool University have developed a sensitive and robust pH sensor that can detect pH variation in just a few microliters of samples. The new sensor uses novel materials and methods to overcome the current method's limitations, which are not sensitive enough or fragile for commercial-scale use.
Formaldehyde is a toxic chemical known to cause cancer but also plays an important role in human biology. New compounds developed by University of Leicester researchers allow for controlled release of formaldehyde in cells, enabling precise measurement of its effects.
Researchers used X-ray photocrystallography to study the transition metal-nitrenoid intermediate in catalytic amination reactions. The team successfully captured the structure and properties of the rhodium-acylnitrenoid intermediate, providing crucial insights into its reactivity.
Scientists at Chalmers University of Technology have created a new method for removing mercury from concentrated sulphuric acid, reducing levels by more than 90%. This innovation could lead to reduced mercury emissions and the production of high-purity, non-toxic products in industries such as mining and metal refining.
A team of researchers has developed a promising synthesis method for producing 6-(difluoromethyl)phenanthridines, which hold tremendous potential for drug development. The study uses aryl-substituted difluoromethylborates and radical isonitrile insertion to form phenanthridine.
Researchers have successfully controlled chemical reactions by manipulating electromagnetic fields in an infrared cavity, improving understanding of reactivity and products formation. The discovery offers a new path for quantum physics to regulate chemical reactions.
Researchers have developed a mononuclear iron complex that selectively and efficiently converts methane to methanol under mild conditions. The catalyst achieves high efficiency and selectivity due to a hydrophobic environment near the active iron center, trapping methane and releasing methanol.
Scientists have discovered a new method for producing pure hydrogen from renewable energy, a significant step towards a greener future. The breakthrough uses specialized techniques to understand how a catalyst works, enabling the creation of clean fuels like hydrogen.
Researchers at Brookhaven Lab used pulse radiolysis to study a key class of water-splitting catalysts, revealing the direct involvement of ligands in the reaction mechanism. The team discovered that a hydride group jumped onto the Cp* ligand, proving its active role in the process.
Chemists have developed a high-performance catalyst specifically designed for solid-state mechanochemical synthesis, achieving efficient reactivity at near room temperature. The approach uses a metal catalyst attached to a long polymer molecule, which traps the catalyst in a fluid-phase, enabling fast and energy-efficient reactions.
Scientists at Paderborn University have developed a new catalyst, known as Lewis superacid, to break strong chemical bonds and speed up reactions. This breakthrough enables the conversion of non-biodegradable greenhouse gases into sustainable chemicals.
Researchers at Hokkaido University have developed a new method using cooperating catalysts to perform challenging dearomative carboxylation reactions. This process enables the production of α-amino acids, which are potentially useful for drug development, and offers greater freedom in designing and synthesizing molecules with carboxyl ...
Researchers have developed a novel catalytic approach to synthesize monocyclic 3-(pyrrol-1-yl)-azetidin-2-ones, which show potential as therapeutic agents. The method yields all four diastereomers with high selectivity and has been published in Current Organocatalysis.
Researchers at Boston College have developed a new catalytic approach that enables concurrent control of multiple convergences and selectivities in intermolecular amination of allylic carbon-hydrogen bonds in alkenes. The cobalt-based system exploits unique features of homolytic radical reaction to form desired amine products in a high...
A team of researchers identified a rare lead compound, lead(II) formate, in various areas of Rembrandt's The Night Watch using micro and macro X-ray analysis. This discovery provides clues about the artist's pictorial practices and the reactivity of lead driers in historical paintings.
Researchers utilized the James Webb Space Telescope to observe dense interstellar clouds, revealing a treasure trove of pristine ices from the early universe. The study provides new insights into chemical processes in one of the coldest places in the universe, offering clues on molecular origins and sulfur storage.
Researchers at UCLA have created the first synthetic version of lissodendoric acid A, a sea sponge-derived molecule with potential therapeutic benefits for Parkinson’s disease and similar disorders. The team developed a method that employs cyclic allenes to produce only the desired enantiomer of the molecule.
Chemists at the University of Groningen have developed a simple one-pot reaction to produce chiral Z-alkenes, previously inaccessible molecules. This method uses a phosphine molecule as a starting point, reducing the need for purification and allowing for the creation of complex functionalised alkenes.
Researchers at Washington University in St. Louis found that nanoplastics from polystyrene can produce reactive oxygen species when exposed to light, which can harm wildlife and the aquatic ecosystem. The study suggests that smaller particle sizes of nanoplastics may be more reactive and decompose faster under light.
Researchers have developed a new method for recycling high-density polyethylene (HDPE) into fully recyclable and biodegradable material. The approach uses catalysts to cleave polymer chains, reducing carbon emissions and pollution associated with HDPE.
Researchers at Baylor University have synthesized a new, one-step Lewis superacid called tris(ortho-carboranyl)borane (BoCb3), which has applications in the production of common plastics. The compound is more efficient to produce, safer for the environment, and could potentially save billions of dollars in manufacturing costs.
Researchers at the University of California, Riverside, have created a novel method to break down per- and polyfluoroalkyl substances (PFAS), also known as 'forever chemicals', in contaminated water. The hydrogen-infusion and UV light-based process achieves high molecular destruction rates without generating unwanted byproducts.
Researchers use pulse radiolysis experiments to measure how unpaired electrons can drive chemical reactivity on a molecule's opposite side, enabling the creation of novel synthetic methodologies. The study demonstrates the potential for free radicals to influence reactivity beyond their site of origin.
Researchers at Hokkaido University have developed a simple radical-based reaction to create unsymmetric variants of molecular compounds used in transition metal catalysts. This method opens up new avenues for designing catalysts and utilizes abundant ethylene feedstock.
Researchers develop a new way to manufacture high-efficiency diffraction gratings using reactive ion-plasma etching, achieving near-theoretical unpolarized diffraction efficiency of 94.3%. The process enables robust and durable gratings suitable for harsh environments.
Scientists have created a new method to stabilize precious metals as catalysts, enabling efficient use of expensive materials in various applications. The approach involves dispersing metal atoms within nanometer-sized islands of cerium oxide, which provides high surface area and stability.
Researchers have developed a reusable, low-cost Mn catalyst that facilitates the alkylation of ketones with alcohols via the 'borrowing hydrogen' method. The catalyst achieves high yields and can alkylate ketone-containing substrates without byproducts.
A new study reveals that wood releases low levels of formaldehyde at room temperature due to a lignin-mediated Fenton reaction. Researchers have developed an effective, low-cost method to mitigate this release by mixing antioxidants and chelators with wood or spraying them on surfaces.
Researchers at Kobe University have developed a new method to synthesize fluoroalkyl carbonates, which are environmentally friendly alternatives to toxic precursors. These carbonates exhibit high reactivity and can be used to create pharmaceutical intermediates and other substances.
High levels of OH radicals can be generated indoors due to human presence and ozone, transforming chemicals in the process. This 'oxidation field' has significant implications for indoor air quality and occupant health.
Researchers at Kyoto University have developed a new protocol for synthesizing dialkyl ethers using three catalysts that hydroxylate alkenes quickly and cheaply. This method enables the precise control of electrons and protons to convert unactivated alkenes into reactive carbocation equivalents under mild reaction conditions.
Researchers at Ohio State University have developed a new method to synthesize medicines using carbenes, reducing the need for explosive intermediates. This breakthrough could enable faster production of cyclopropanes, a key ingredient in COVID-19 treatments and other medications.
Researchers at Rice University have developed a chemical process that can add two distinct functional groups to single alkenes, a breakthrough in drug design and materials science. The process uses manganese catalysts and photocalysts to enable radical ligand transfer, allowing for the creation of unique molecules.
A University of Central Florida researcher has been awarded $800,000 by the US Department of Energy to investigate elusive chemical compounds known as Criegee intermediates. The research aims to develop more efficient low emission fuel architectures and engine technologies to reduce combustion's impact on the environment.
Researchers at NIST developed a new, faster, and more accessible method for screening skin allergens without animal testing. The electrophilic allergen screening assay (EASA) achieved similar results to existing methods with 77% agreement rate, paving the way for potential standardization and increased international trade.