Articles tagged with Metal Organic Frameworks
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Researchers created a two-dimensional MOF-based nano-impeller that achieved efficient photoisomerization and on-demand cargo delivery. The study found that mechanical activation and dimensionality synergistically regulate the photo-switching dynamics, enabling 99% cargo release within 50 minutes.
Researchers at Tohoku University have demonstrated a water-resistant and recyclable redox-active metal-organic framework (RAMOF) that can store electrons in acidic aqueous solutions. The breakthrough material shows high durability in an aqueous RAMOF-based rechargeable battery.
A new open-access tool, MOF-ChemUnity, offers a systematic way to organize and synthesize knowledge about metal–organic frameworks (MOFs), enabling the discovery of their potential uses in drug delivery, catalysis, carbon capture, and more. The system creates a unified foundation that both researchers and AI systems can build on, reduc...
A Chinese research team developed an innovative device that skips CO₂ purification, cuts costs, and produces commercial-grade HCOOH directly from dilute emissions. The membrane-integrated electrolyzer concentrates CO2 to high levels for efficient conversion, producing a valuable liquid fuel and industrial chemical.
Researchers at OSU have designed a novel manganese-based MOF, BVR-19, which is less toxic to patients and more environmentally friendly than current contrast agents. The new material has shown promising results in medical imaging, with higher r1 relaxivity and biocompatibility.
A glassy metal-organic framework coating accelerates ion desolvation, stripping solvent molecules from lithium ions, while a second layer enables rapid transport into the graphite bulk. This synergistic design results in unprecedented fast-charging performance, with batteries maintaining high capacity and stability.
Researchers develop new electrochromic MOF platform by mixing two materials at the molecular level, allowing multidirectional control of color change. This innovation enables future smart electronics with quick, reversible and energy-efficient color responses.
Researchers have made significant advancements in soft porous crystals (SPCs) with promising applications in gas storage, separation, catalysis, and devices. The 'dose sensitivity' of SPCs directly affects their economic viability, with high performance and batch consistency crucial for trace or low-dose applications.
A team developed a metal-organic framework (MOF) neuron that perceives dopamine, a key neurotransmitter in the brain. The device demonstrated synaptic plasticity, integrate-and-fire dynamics, and spike tuning, mirroring biological neurons' behavior.
Researchers developed a triggered air-water interfacial coordination assembly method to synthesize ultrathin large-sized continuous 2D MOF membranes within just 30 minutes. The method enables highly accurate permeable and stable H2/CO2 separation, revolutionizing industrial separation processes.
Researchers at UNIST developed a platform to engineer moiré systems with customizable length scales, enabling precise control over electronic properties. The study introduces quasiperiodic patterns with potential to subtly influence electron behavior.
A new strategy enables the rapid fabrication of high-performance 2D MOF membranes with customizable pores, achieving efficient gas separation. The approach accelerates membrane development time from hours to minutes while reducing organic ligand consumption.
Researchers developed a new class of 2.5D MOFs using triptycene-based molecules, enabling high-quality single crystals for detailed structural and functional studies. The materials exhibit strong electronic and magnetic correlations in the interlayer direction, paving the way for next-generation MOF-based technologies.
A new AI system developed by U of T researchers can predict the potential real-world use for a new material, using early-stage data. The tool focuses on porous materials like metal-organic frameworks (MOFs), which have tunable properties leading to various applications.
Researchers from Northwestern University developed a novel approach to integrate metal-sulfur active sites into metal-organic frameworks, which significantly outperformed their non-sulfur counterparts in hydrogenation catalysis. The study provides a powerful new strategy to design and study metal-sulfur catalysts for various applications.
A study reveals that metal-organic frameworks (MOFs) can be toxic to mice, causing disruptions in blood cell formation and immune balance. The researchers found that the MOFs suppressed production of certain cells but also triggered a rebound effect, leading to increased inflammation.
Advanced electron crystallography techniques have revealed the unexpected structure of carmine, a natural red colouring agent. The substance has a well-defined, three-dimensional porous structure composed of two calcium ions, two aluminium ions, and four organic ligand molecules.
A team of scientists at UNIST developed a data-driven structure prediction algorithm that led to the synthesis of three novel porous materials with exceptional selectivity in gas separation. The newly developed materials have significant potential for greenhouse gas separation and purification applications.
A research team developed a novel strategy to balance high catalytic activity and durability under industrial-level conditions. They constructed a MOF@POM superstructure that undergoes an in-situ transformation into a single-layer CoFe hydroxide catalyst, exhibiting exceptional performance in alkaline electrolytes.
Researchers developed fluorescent polyionic nanoclays that can be customized for medical imaging, sensor technology, and environmental protection. These tiny clay-based materials exhibit high brightness and versatility, enabling precise tuning of optical properties.
Researchers at Graz University of Technology developed a new understanding of how complex materials like organic semiconductors and MOFs transport thermal energy. They discovered that phonon tunneling plays a crucial role in heat conduction, enabling targeted design of materials with specific thermal properties.
A new material has been developed for efficient separation of deuterium (D2) from hydrogen (H2) at elevated temperatures. The material's performance exceeds that of traditional methods, which operate at extremely low temperatures.
A novel copper-based zeolite imidazolate framework (Cu-ZIF-gis) has been developed to separate deuterium (D2) from hydrogen (H2) at 120 K (-153°C), exceeding the liquefaction point of natural gas. This material exhibits improved separation efficiency and lower energy consumption compared to traditional methods.
A novel mixed-ligand strategy creates ultrahigh surface area, chemically stable chiral MOFs ideal for practical applications in asymmetric catalysis. The frameworks demonstrate record-breaking surface areas and exceptional structural features, making them suitable as heterogeneous catalysts.
Researchers at TU Wien developed COK-47, a powdery solid substance with remarkable capabilities, by combining organic and inorganic chemistry. In humid environments, the material forms a tribofilm that ensures extremely low friction, making it highly interesting for industry applications.
A research team led by Paolo Falcaro has developed a microporous crystal compound that detects toxic chemical compounds produced when protein-rich foods spoil. The ERC Proof of Concept Grant will explore practical applications for the composite ink, which changes color depending on the concentration of toxic compounds.
Researchers developed a bioinspired MOF membrane with a scale-like structure to separate propylene from propane. The membrane achieved excellent separation performance, exceeding 220, and retained its stability for over 1,000 hours.
Researchers developed a new cathode material using MOF-mediated synthesis, achieving over 1000 stable battery cycles with exceptional capacity retention. The material's unique structure boosts electronic conductivity, inhibits Mn dissolution, and improves long-term cycling stability.
Researchers at Nagoya University developed a novel porous metal-organic framework (MOF) that combines adsorption and dissolution to separate oxygen from argon. The 'adsorptive-dissolution' mechanism enhances gas separation efficiency and selectivity, with potential applications in industries requiring high-purity oxygen.
Researchers at TUM have identified a new, highly effective filter material that can remove hazardous PFAS chemicals from drinking water. The bespoke metal-organic framework compounds are adaptable and electrostatically charged, significantly improving filter capacity compared to existing materials.
Researchers at Oregon State University have discovered a way to increase the effectiveness of a chemical structure for scrubbing carbon dioxide from factory flues. The new method uses metal-organic frameworks (MOFs) and achieves more than double the capture ability compared to traditional sorbents.
Researchers at UC Berkeley have developed a metal-organic framework that can capture CO2 at extreme temperatures, relevant to cement and steel manufacturing plants. The discovery has the potential to change how scientists think about carbon capture and reduces the need for costly infrastructure.
A research team developed a metal-organic framework (MOF) that suppresses charge recombination, enabling efficient overall water splitting. The MOF's dynamic structural twist prolongs the lifetime of excited-state electrons.
A new covalent organic framework (COF) material developed by UC Berkeley researchers can capture CO2 from ambient air without degradation, making it a promising solution for reducing atmospheric greenhouse gases. The material's high carbon dioxide capacity and selectivity make it an attractive alternative to existing carbon capture tec...
A new MOF has been developed using a 'Merged-Net Strategy' inspired by skyscraper architecture, resulting in enhanced porosity and structural stability. The material exhibits superior water adsorption capacity and reusability compared to conventional MOFs.
Researchers developed a novel strategy for designing MOFs, merging bottom-up and top-down approaches to explore structures based on metal clusters. The Up-Down Approach enables the creation of novel materials with tailored properties, including high chemical stability and diverse chemical properties.
A team of researchers has developed a new membrane material that can detect and remove pharmaceutical chemicals from water at trace levels. The new approach uses a polymer membrane with an interconnected network of pores, which are designed to capture larger molecules, allowing for more effective filtration.
Early porous coordination polymers (PCPs) exhibit a flexible 'soft' nature, allowing them to adjust their shape and hold more gas. This finding offers new insights into the evolution of PCPs and paves the way for future research and applications.
Researchers at Sandia National Laboratories have created a cleaner way to separate rare-earth elements from complex mixtures. They designed sponges that selectively absorb one metal while excluding others, with the potential to improve purification processes globally.
Researchers developed MOF confined crown ether membranes with high monovalent ion permeation rates and selectivity. The membranes provided theoretical guidance for constructing precise separation membranes for ions in complex systems.
Researchers at the University of Utah have developed a compact rapid cycling fuel-fired atmospheric water harvesting device that can produce clean drinking water in arid places. The device uses hygroscopic materials to draw water molecules out of non-humid air and then applies heat to release those molecules into liquid form.
Researchers have developed a new electrochromic film based on metal-organic frameworks that can quickly switch between transparent and colored states to block or allow sunlight. The film demonstrated reliable performance for over 40 hours and 4,500 cycles of switching.
A new detector system uses a combination of metal-organic frameworks and conductive polymers to provide continuous monitoring of toxic gases. The material shows high sensitivity and reversibility, enabling detection at low concentrations, making it suitable for industrial or home settings.
A new atomically-thin material has been discovered that can switch between an insulating and conducting state by controlling the number of electrons. This property makes it a promising candidate for use in electronic devices such as transistors.
Researchers at KAIST have developed a hybrid sodium-ion battery with high energy and power density, enabling rapid charging in under a few seconds. The new battery technology has the potential to revolutionize energy storage for electric vehicles and other applications.
Scientists achieve room-temperature quantum coherence by embedding a chromophore in a metal-organic framework, enabling the creation of quintet state qubits with four electron spins. This breakthrough could lead to the development of multiple qubit systems at room temperature, revolutionizing quantum computing and sensing.
Researchers unveiled a two-dimensional Metal Organic Framework (MOF) that showcases negative thermal expansion and unique origami tessellation patterns. The MOF's deformable net topology enables origami-like movement in response to temperature changes.
Researchers at CSU and the University of St. Andrews created an effective antimicrobial material that slowly releases nitric oxide, killing bacteria and fungus over time.
Researchers propose a novel approach to customize metal-organic frameworks (MOFs) for efficient membrane separations. The strategy involves modularizing custom defect-free MOF separation membranes, allowing for rapid production of high-performance membranes.
Researchers developed and characterized nitric oxide-storing MOFs embedded in polymers with novel antibacterial potential. The nickel and copper MOFs combined to create a composite material that achieved an optimal, two-stage NO delivery system.
A team of scientists constructed micro-mesoporous metal-organic framework and carbon nanotube-based composite catalysts showing excellent oxygen reduction reaction electrocatalytic activity. The presence of MNx sites was found responsible for the enhanced electrocatalytic activity.
Researchers developed a method to form tailored nanoscale windows in porous materials called MOFs using an architectural arch-forming template. This approach enables precise control over structure formation, leading to the creation of new materials with potential gas separation, medical applications and energy security benefits.
A team of researchers elucidated how hydrogen peroxide affects the degradation of a carbon-based catalyst named N-G/MOF. The study examined changes in the catalyst's elemental composition, major chemical bonds, crystal structure, and morphology under varying concentrations of hydrogen peroxide.
The team created a proof-of-concept nanocapsule capable of delivering specific payloads to targeted locations, with potential applications in drug delivery, nutrient transport, and other fields. By using calcium metal ions as building blocks, they can generate identical reservoirs for different substances.
Researchers at EPFL have developed a record-thin MOF film that performs exceptional hydrogen-nitrogen separation. The breakthrough uses an innovative crystallization method to create uniform two-dimensional films with unprecedented thickness.
A team of researchers at UNIST has developed solid electrolyte materials utilizing metal-organic frameworks (MOFs) to improve the efficiency of hydrogen fuel cells. The new materials demonstrate high hydrogen ion conductivity and durability, holding promise for advancing sustainable energy solutions.
Metal organic framework nanosheets were found to optimize the morphology and texture of zinc anodes, reducing dendrite formation and side reactions. This enables efficient ion flux decoupling and improves cycling performance at both low and high rates.
Researchers developed a stable, porous molecular crystal using triptycene as a building block, leveraging noncovalent interactions to create a flexible material with high solubility and self-healing capabilities. The synthesized PMC exhibits excellent thermal and chemical resistance, making it suitable for various applications.
A Clemson team created a novel metal-organic framework with combined conduction pathways, outperforming traditional MOFs. This breakthrough could advance modern electronics and energy technologies.
Researchers have discovered ultra-thin metal-organic layers that prevent ice crystal formation in red blood cells during freezing and thawing. These nanolayers, made from metal-organic frameworks based on hafnium, show excellent cryoprotection at minimal concentrations, potentially leading to new and efficient cryoprotectants.