Articles tagged with Oxidants
Researchers have developed metal-free organic semiconductor photocatalytic H2O2 production, providing a robust material platform for green and efficient synthesis. Novel surface reactions can fundamentally increase the utility of photogenerated excitons by exploiting unexpected chemical processes.
Researchers from Institute of Science Tokyo developed a novel catalyst that efficiently produces sulfones at low temperatures, achieving high selectivity and reducing precious metal consumption. The new SrMn₁₋xRu_xO₃ catalyst offers significant advantages over conventional systems, making it suitable for various industries.
Researchers at Tohoku University developed a new synthesis method for highly pure porous organic polymers (POPs), eliminating residual impurities and achieving high porosity. The obtained POPs exhibited improved CO2 adsorption capacity, proton conductivity, and unique gas adsorption behavior.
Researchers from Institute of Science Tokyo successfully developed a multi-element perovskite catalyst that selectively oxidizes light alkanes to alcohols with high yield and selectivity. The breakthrough catalyst operates under mild conditions and exhibits excellent stability and reusability.
Researchers validate increase of specific t-Cys sites associated with aging in human proteome, suggesting potential role in age-related diseases. The study expands beyond classical proteinopathic paradigms, highlighting trioxidized cysteine as a key molecular mechanism underlying aging.
Scientists at Yokohama National University developed innovative catalysts using noble metals Rhodium and Ruthenium to facilitate cross-dehydrogenative coupling reactions. These reactions utilize oxygen as the sole oxidant, producing aryl esters with minimal waste.
A team of scientists has developed a new treatment for chronic wounds that uses ionized gas plasma to decontaminate and heal wounds. The technology shows promise in treating diabetic foot ulcers, internal wounds, and potentially cancerous tumours.
A new study found that even a mild chronic sleep deficit can lead to inflamed and dysfunctional vascular cells, increasing the risk of cardiovascular disease. Shortened sleep duration for six weeks caused oxidative stress in these cells.
Scientists at the University of California - Riverside have developed a fire-safe fuel that cannot ignite without an external electrical current. This breakthrough could significantly reduce the risk of wildfires and improve energy efficiency.
Researchers at City University of Hong Kong have developed a new class of near-infrared-activated photo-oxidants that can effectively kill cancer cells without requiring oxygen. The discovery offers a promising direction for developing anti-cancer drugs and could overcome existing limitations of photodynamic therapies.
A ferrocene-based capsule with unusual charge-transfer interactions has been synthesized, allowing for reversible encapsulation and release of guest molecules. The capsule can bind to a variety of organic and inorganic dyes and electron-accepting molecules, demonstrating its potential applications in medicine, biotechnology, and chemic...
A new study by researchers at Florida Atlantic University explored the effects of resistance training on older adults' cellular level. The study found that resistance training did not significantly affect inflammatory proteins or redox balance markers, but showed a significant reduction in a specific protein ratio. This may support the...
Scientists at Washington University in St. Louis found that manganese oxides can be formed without atmospheric oxygen under Mars-like conditions. The study, published in Nature Geoscience, used kinetic modeling to show that halogens like chlorate and bromate can convert manganese into minerals thousands of times faster than by oxygen.
A new study suggests that comet impacts can transport oxidants from Europa's surface to its ocean, increasing the probability of finding life. The research model shows that if an impact reaches halfway through the moon's icy shell, meltwater sinks to the ocean, bringing critical chemicals.
Researchers have found a way to perform hydrogen atom transfer reactions with fewer chemicals and less cost, making it more efficient for industrial and academic settings. The new method uses electrochemistry to create cobalt hydride catalysts, reducing the need for expensive oxidants and reductants.
A recent airborne study reveals extreme amounts of hydroxyl and hydroperoxyl radicals generated by lightning, suggesting a substantial proportion of global atmospheric oxidation. The results could indicate that lightning-generated oxidants are responsible for between 2-16% of the Earth's atmosphere oxidizing capacity.
Scientists at Southwest Research Institute modeled chemical processes in Enceladus' subsurface ocean, indicating the possibility of a diverse microbial community. The study found that oxidant production and oxidation chemistry could contribute to supporting possible life on Enceladus.
Researchers at University of Freiburg developed a novel, stable oxidizing agent that overcomes common disadvantages of existing oxidants. The new reagent allows for the synthesis of reactive species in standard laboratory solvents and has broad applicability in inorganic, organic chemistry, electrochemical research.
Scientists create a novel, metal-free method to selectively introduce Fluor into aliphatic C-H bonds, enabling the efficient synthesis of complex fluorinated compounds. The approach combines iodine catalysis and photochemistry, offering a greener alternative to existing electrophilic fluorination methods.
Researchers developed a smart polymer that senses high oxidant levels and administers just the right amount of antioxidant to restore balance. The polymers successfully recovered water fleas' heart rates when exposed to sublethal concentrations of hydrogen peroxide.
A research team led by Professor Jaeheung Cho has found a new active intermediate synthesized in the oxidation process using biomimetic catalysts and artificial oxidants. This discovery clarifies the oxidation mechanism and clears the long-standing debate on the role of metal-iodosylbenzene intermediates.
Researchers create self-healing, electrically conductive, and frost-resistant silicones by oxidizing organic compounds with molecular oxygen. The new method offers improved selectivity and mild conditions, enabling the production of functional organosilicon substrates.
A study published in Scientific Reports reveals that the Na/K-ATPase oxidant amplification loop plays a key role in aging and may be targeted for anti-aging interventions. Researchers successfully demonstrated the therapeutic potential of pNaKtide, a synthetic peptide, in improving impaired physiological functions.
The presence of reactive oxygen species (ROS) drives the digestion process of dead cells through efferocytosis. This mechanism helps limit host inflammation and regulates the immune response. Producing optimal levels of ROS is essential to prevent autoimmune disease and chronic conditions.
Scientists used a novel gene editing technique to uncover the genetic basis of paraquat-induced Parkinson's disease. The study identified three genes - POR, ATP7A and SLC45A4 - that confer resistance to paraquat, suggesting these genes may be responsible for the toxicity.
Researchers have discovered that young roots take chemical snapshots to detect obstructions and coordinate their paths, outsmarting seemingly random root patterns. This process relies on compounds similar to those used in traditional photography, improving understanding of plant immunity and potential crop yield boosts.
A University of Washington study reveals that during large climate swings, oxidants shift in a different direction than expected, leading to changes in ozone and greenhouse gas levels. Researchers propose two possible explanations: a change in atmospheric circulation patterns and chemical reactions with halogens.
The study demonstrates that pNaKtide attenuates the development of experimental nonalcoholic fatty liver disease (NAFLD) and atherosclerosis in mice fed a Western diet. The researchers found improvements in insulin sensitivity, dyslipidemia, and cholesterol levels.
Scientists have developed new methods to monitor endogenous oxidants, which are essential chemical messengers that help maintain organism function. The methods involve genetically encoded probes that can detect specific oxidants in real-time and down to single-cell levels.
Researchers at Marshall University have identified a novel mechanism for blocking the signal by which the cellular sodium-potassium pump amplifies oxidants, leading to obesity and metabolic syndrome. The study, published in Science Advances, suggests that the Na/K-ATPase might be a therapeutic target for treating these conditions.
James Watson suggests that type 2 diabetes is linked to a lack of biological oxidants, not an excess. Exercise promotes oxidation, which can help remedy this deficiency and benefit individuals with high blood sugar.
High levels of molecular chlorine have been detected in the Arctic atmosphere, with concentrations peaking at 400 parts per trillion. The discovery highlights the potential for molecular chlorine to influence atmospheric chemistry and has implications for mercury cycling and ozone formation.
Researchers have discovered a light-independent source of superoxide in the depths of oceans and dark environments. Bacteria common in these areas produce superoxide, which has both toxic and beneficial effects on the environment.
Researchers observed oxidative changes in living organisms for the first time, revealing that many assumptions about oxidative stress and aging are incorrect. Antioxidants did not reduce oxidant levels, but rather increased production in energy plants.
Biologists at USC discovered major declines in the availability of an enzyme, known as the Lon protease, as human cells grow older. The finding may help explain why humans lose energy with age and could point medicine toward new diets or pharmaceuticals to slow the aging process.
Researchers identified a new mechanism for mouse lung protection against inhaled oxidants. Alveolar macrophages express MARCO and SR-AI/II, clearing lipids modified by oxidants that can trigger inflammation.
The researchers designed a microfluidic fuel cell that functions without a physical barrier to separate the fuel and oxidant, utilizing laminar flow instead. This design offers several advantages, including fewer parts and simpler design, as well as compatibility with alkaline chemistry.
In Volvox carteri, colonies become sexual when exposed to high temperatures, releasing pheromones to guarantee mating partners. This response is linked to the activation of the sex-inducer gene, which promotes the production of a pheromone in reaction to increased oxidants produced by free radicals.
Researchers at Scripps Research Institute have found that the human body produces ozone as part of a mechanism to protect itself from bacteria and fungi. The discovery suggests a new role for neutrophils and antibodies in the immune system, potentially leading to new treatments for inflammatory diseases.
Research reveals bilirubin's role in protecting cells from oxidative damage, potentially improving outcomes for conditions like stroke and heart attack. The study also sheds light on the paradox of bilirubin's production, suggesting it may be an evolutionary development to combat cellular stress.
Researchers found sulforaphane's phase 2 enzymes protect cells against oxidants for up to three days, preventing damage from cancer, retinal degeneration, and other conditions. Eating large quantities of vegetables, especially cruciferous ones, helps fight disease by increasing antioxidant defenses.
Researchers have developed a battery-powered disinfecting pen that can inactivate waterborne parasites, viruses, and bacteria within minutes. The device generates mixed oxidants from a salt solution, delivering safe drinking water even better than plain chlorine.
Researchers developed a battery-operated pen that can disinfect drinking water using a salt solution, inactivating parasites, viruses, and bacteria with dramatic results.
Researchers found that oxidants are necessary for endothelial cell migration and wound healing after vascular injury. Oxidants stimulate the production of actin fibers, allowing cells to move towards injured sites.