A team of Chinese researchers has developed an electrocatalyst that efficiently converts CO2 into liquid fuels with multiple carbon atoms. The primary products are ethanol, acetone, and n-butanol, which have high energy density and are safe to store and transport.
SourceWiley·JournalAngewandte Chemie International Edition·TypeExperimental study·DateNov 15, 2021
Rice University researchers have developed a method to control the growth of tetrahedron-shaped nanoparticles, which can be used as building blocks for unique metamaterials. The team discovered that balancing thermodynamic and kinetic forces during crystallization allows for symmetry breaking, forming pyramid-shaped nanocrystals.
A new model by a SwRI-led team applies geologic evidence to understand how oxygen levels in the Earth's atmosphere evolved. The results indicate that large impacts may have contributed to the scarcity of oxygen, delaying its oxidation.
Researchers developed a new mechanism of adsorption called mechanisorption, which can store significant amounts of energy by recruiting molecules onto surfaces at high concentrations. This breakthrough has implications for energy storage, controlled release, and environmental remediation.
A new technique reveals the role of cations in surface chemistry, shedding light on environmental issues like rust and pollution. The study uses surface analysis to understand the initial stages of iron corrosion, which can help monitor carbon dioxide capture, water quality, and infrastructure management.
Using advanced microscopy techniques, researchers recorded the breaking of a single chemical bond between a carbon atom and an iron atom on different molecules. The team measured the mechanical forces applied at the moment of breakage, revealing insights into the nature of these bonds and their implications for catalysis.
A University of Queensland-led study reveals that hot spot volcanoes do not produce 'pristine' magma from the melting mantle but instead filter a different melt to the surface. This new information supports the notion that detection of magma at the crust-mantle boundary could indicate an upcoming eruption.
Researchers developed a method to scale up nanocages to trap noble gases like krypton and xenon. The team used commercial materials and found the optimal temperature range for trapping gas atoms inside the cages.
A UC Riverside materials scientist has received a $2 million grant to improve the scalability of quantum computers, allowing them to operate at room temperature. The project aims to create design guidelines and manufacturing strategies for hybrid organic-inorganic structures that can produce quantum computers on a larger scale.
Researchers from the University of Nottingham have developed a novel catalyst that combines homogeneous and heterogeneous features, defying traditional categorization. The discovery holds promise for increasing the active surface area available for catalysis, leading to more efficient and sustainable production of molecules.
The Dragonfly mission will investigate Titan's surface and atmosphere, searching for chemical biosignatures and exploring the moon's active methane cycle. By analyzing the prebiotic chemistry currently taking place in Titan's atmosphere and on its surface, scientists hope to gain insights into the potential for life on the moon.
The Center for Adapting Flaws into Features will explore chemical defects to optimize material properties, with a focus on creating better catalysts and electronics. The team aims to develop new approaches towards transformative technologies by leveraging advanced microscopy, spectroscopy, and data science.
A team of Lehigh University researchers is studying a promising alternative catalytic process based on solid acid catalysts for ethylene dimerization. Using in situ and operando molecular spectroscopy, they aim to understand the surface structures of the catalyst and design more active catalysts with reduced environmental impact.
Researchers at Simon Fraser University have developed a new coating solution that can transform regular materials into waterproof surfaces, with potential applications in various industries. The patented formula is up to 90 percent cheaper to produce and free of harmful fluorinated compounds.
Scientists have discovered that snake scales adapt to different environments by changing their surface chemistry. The study found that tree snakes have ordered lipid molecules on their bellies, while sand snakes have similar layers on both sides.
A team of researchers from the University of Münster has developed a highly efficient method to produce silicon polymers using surface chemistry. The breakthrough allows for the creation of long polymers with mild reaction conditions, paving the way for new material properties and potential applications as organic semi-conductors.
Researchers used advanced technique to study phenol reaction at air-water interface, revealing a 10,000-fold increase in reaction speed compared to bulk water. The findings could improve understanding of catalytic chemistry and its impact on the global environment.
A study of indoor ozone chemistry in an occupied house found overall low ozone concentrations but multiple VOCs indicating ozone reactions with skin lipids and other surface chemicals. Volatile oxidation products from skin oil persisted for up to 5 days, suggesting a significant contribution of skin lipids to indoor ozone chemistry
Scientists have discovered a novel electroactive bacterium, Desulfuromonas acetexigens, that preferentially grows on modified electrodes, producing higher current densities than existing species. This breakthrough could enable energy-neutral wastewater treatment using microbial electrolysis cells.
Researchers at Michigan Tech and University of Edinburgh highlight the importance of understanding virus surface stability and interaction in various environmental conditions. They propose new techniques for studying surface chemistry, which could help design effective vaccines and treatments for SARS-CoV-2 and future pandemics.
Researchers at University of Göttingen use femtochemistry to film and control chemical reactions on solid surfaces. They successfully transfer principle from molecules to a solid, controlling its crystal structure with high efficiency.
New research from Washington University in St. Louis finds that electrostatic discharge during Martian dust storms generates highly reactive chlorine compounds, driving the surface-to-atmosphere cycle of chlorine. The ongoing chlorine cycle may impact the detection of biomarkers on Mars.
Researchers used X-ray technology to analyze chainmail links from the Mary Rose, revealing their composition and extent of corrosion since recovery. The findings confirm the effectiveness of conservation techniques and hint at further history yet to be uncovered.
The technique successfully removes even the tiniest contaminants down to the atomic scale, achieving an unprecedented level of cleanliness. The research also explored the origins and mechanisms of recontamination at the nanoscale, revealing surface diffusion and airborne contamination.
Researchers at INRS and McGill University developed a method to draw molecular patterns on the surface of quantum materials using macrocycles, changing their optical, magnetic, and electrical properties. This technique has potential applications for electronic devices and biosensing.
Researchers have discovered a new class of 2D materials called MXenes that can store enormous amounts of charge, similar to batteries. These materials can be charged or discharged within tens of seconds, making them ideal for rapid energy storage.
Researchers from CSU's HOMEChem experiment found sharp spikes in hypochlorous acid and chlorine when mopping floors with bleach, revealing a new world of indoor chemistry. The team also observed interactions between nitrogen and ammonia emissions from cooking with cleaning products.
Researchers at Imperial College London and the University of Toronto have developed a sponge that captures and removes oil microdroplets from wastewater, improving upon previous concepts. The new sponge works faster and over a wider pH range than its predecessor, making it suitable for industrial wastewater applications.
Researchers at McMaster University developed a self-cleaning surface that can repel all forms of bacteria, preventing the transfer of antibiotic-resistant superbugs in medical settings. The treated material is also suitable for food packaging to prevent bacterial contamination, such as E. coli and Salmonella.
Growing nanoscale polymer brushes on materials' surfaces enables the creation of diverse array of materials with tailored chemical properties. The approach allows for precise control over surface density, length and chemistry, enabling various catalysis and antibacterial applications.
A new sensor developed by scientists uses black silicon to detect trace amounts of nitroaromatic compounds, a common component of explosives and toxic pollutants. The sensor's high sensitivity and dynamic measurement range make it a potentially game-changing tool for medical and forensic evaluations.
Researchers at the University of Copenhagen are establishing a new center to study catalysis on high-entropy alloys, aiming to develop sustainable chemistry alternatives. The project aims to identify materials capable of combining carbon and oxygen-containing molecules to produce valuable chemicals.
A University of Hawaii team has provided answers to key questions about Titan's surface, including the existence of vast longitudinal dunes and dark organics. The researchers used remote sensing data from NASA's Cassini-Huygens mission to study the chemical makeup of these organic dunes.
Scientists warn of ocean acidification's impact on marine life, habitat degradation and biodiversity loss due to rising CO2 levels, threatening ecosystem services and human livelihoods.
Scientists have found that local fluctuations on a solid-state catalyst's surface create opportunities for reactant molecules to diffuse and undergo desired reactions. The findings, published in Science, reveal that even with densely packed adsorbed particles, molecular mobility is possible due to periodic changes in particle density.
Researchers found significant gaps in understanding microplastic effects, with concentrations detected being orders of magnitude lower than those affecting organisms in lab tests. The study highlights a need for more environmentally realistic studies and better monitoring of specific environmental regions.
Researchers found a way to change the spatial arrangement of bipyridine molecules on surfaces using metals, which can improve dye-sensitized solar cells. The cis configuration is formed through the addition of iron atoms and increased temperature, altering the chemical conformation.
Researchers at TU Dresden developed DUT-60, a crystalline framework with the highest specific surface area and pore volume among known materials. The highly porous material can store large quantities of gases or filter toxic gases from the air.
Scientists at the University of Waterloo have created a new class of semiconductors by controlling the orientation and size of single-walled carbon nanotubes. This breakthrough could lead to more powerful devices with improved battery life, as they consume less power.
Scientists have discovered a new process to layer metals under graphite, leading to unique mesas with potential applications in quantum computing and sensing. The formation of these structures could enable controlled magnetic and electronic properties.
A two-year project, called HOMEChem, aims to comprehensively understand the chemistry of indoor environments by studying various aspects of air, surfaces and microbes in a recreated home setting. Researchers will analyze data collected using new mass spectrometry-based instrumentation.
Researchers found that a baking soda solution was the most effective at removing pesticide residues from organic Gala apples. After 12 and 15 minutes of washing, 80% of thiabendazole and 96% of phosmet were removed. The study suggests that this simple method could be an effective strategy for cleaning pesticides off produce.
Researchers discovered that water-repellent surfaces force ice to grow upward, making it easier to remove. The team's findings suggest applying water-repellent coatings or engineering surfaces with built-in repelling properties could enable breeze-assisted ice removal.
Researchers aim to develop a framework to inform design of carbon nanomaterials, minimizing potential unintended consequences. They will manipulate surface chemistry and test biological and electrochemical activity to optimize CNM properties.
Researchers from TU Dresden and CiQUS successfully synthesized decacene, the longest acene molecule ever produced. The breakthrough achievement demonstrates the power of collaboration between synthetic chemists and surface scientists to overcome long-standing chemical challenges.
A new nanocoating technique developed by KAIST researchers uses plant-derived polyphenol to extend the shelf life of produce. The sprayable nanocoating process has been shown to significantly prolong postharvest shelf life, preserving freshness beyond 28 days and 58 hours for certain fruits.
Researchers at EPFL's Laboratory for Fundamental BioPhotonics have developed a microscope that can track three-dimensional spatial changes in molecular structure and chemistry of confined systems. The study reveals a remarkable spread in surface reactivity, even on small portions of a capillary, shedding light on the chemical reactivit...
Experts at Rutgers University-New Brunswick and Michigan State University have designed a way to reduce enzyme use in biofuels production. The new approach enables the recycling of enzymes, lowering production costs and making biofuels more affordable.
Scientists have found that magma reservoirs are less liquid and more crystalline than previously thought, with most crystals retaining their structure for tens of thousands of years before being exposed to molten magma. This discovery could help predict when volcanoes pose the greatest risk by identifying those with mobile magma.
Research by Tufts University chemist Mary Jane Shultz sheds new light on snowflake formation. The study reveals that flat sides of a snowflake consist of a bilayer structure, contradicting previous theories.
Researchers developed microbes to aid methane recovery, while also improving chemistry students' test scores through personalized feedback. Urban streams were found to exhibit unique nutrient patterns driven by wastewater treatment plants.
A team of researchers at Berkeley Lab used a unique infrared probe to pinpoint areas on single metallic particles where chemical reactivity occurs. This technique reveals the detailed chemistry occurring on the surface of particles, enabling customization of structural properties for more effective catalysis.
Researchers at Colorado State University have developed a simple and inexpensive device that can sort droplets of liquid based solely on their varying surface tensions. The device uses a tunable surface chemistry to manipulate its repellency to different liquids, enabling the sorting of droplets by surface tension.
A team of researchers has successfully imaged all steps in a complex organic reaction, revealing the mechanisms behind it. The study used atomic force microscopy to visualize the bond configuration of reactants, intermediates, and products, providing new insights into the stabilization of intermediates.
Scientists at University of Copenhagen discover heart urchin shell has a structure that nears theoretical ideal for foam structure strength. The shell's unique porosity and strut arrangement make it up to six times stronger than chalk, despite being lighter.
Researchers develop new algorithm to simulate water evaporation at molecular scale, matching theoretical and real-world observations. The tool enables the study of various heat transfer problems, including rapid cooling of computer chips and energy conversion devices.
University of Cincinnati quantum chemistry researcher Thomas Beck develops new methods to calculate the thermodynamics of ion hydration, leading to more efficient renewable energy devices. His findings have garnered international respect and recognition from top physicists.
Researchers at KU Leuven have developed a method to produce bioplastics, such as polylactic acid (PLA), more efficiently and with less waste. This breakthrough could lead to cheaper and more sustainable production of biodegradable plastics.
A new paint developed by researchers at UCL creates self-cleaning surfaces that resist everyday wear and tear. The paint's unique properties allow it to withstand damage and maintain its self-cleaning abilities, making it suitable for a wide range of applications.
Theoretical chemists generate maximally random, jammed states using a computer algorithm, revealing new insights into the nature of randomness. These findings have implications for materials science and photonics, where randomly dispersed patterns can create unique properties.