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Scientist uses form to explain function of key building blocks of life

Researchers studied iron-sulfur proteins called rubredoxin, which play a crucial role in processes like photosynthesis and respiration. By analyzing the strength of hydrogen bonds in different variants of the protein, they were able to explain changes in protein function and predict its behavior.

SourceUniversity of Wisconsin-Madison·JournalProceedings of the National Academy of Sciences·DateSep 30, 2005

Water makes a splash

Researchers at Berkeley Lab found that most liquid water molecules interact with only two other water molecules, contrary to the traditional picture of four hydrogen bonds per molecule. The study used a unique experimental technique and measured the energy required to distort hydrogen bonds in solid and liquid water.

SourceDOE/Lawrence Berkeley National Laboratory·JournalScience·DateNov 11, 2004
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Water molecules clump more loosely than previously thought

A team led by scientists at Stanford Synchrotron Radiation Laboratory found that water molecules form only two hydrogen bonds instead of the previously believed three or four. This discovery reopens the hunt for the structure of liquid water and could lead to a better understanding of the chemistry of cells.

SourceStanford University·JournalScience·DateApr 2, 2004

Favorite liquid revisited

A team of scientists has found that water molecules in liquid form clump much more loosely than previously believed, challenging 20 years of research. This discovery reopens the hunt for a better understanding of water's unique properties and potential applications in fields like biology.

SourceDOE/SLAC National Accelerator Laboratory·JournalScience·DateApr 2, 2004

Plastic is forever -- or not

Virginia Tech researchers have made a breakthrough in creating polymers that can be reversed using heat, opening up new possibilities for thermoplastic elastomers (TPE) and novel adhesives. The team synthesized nano-phase separated polystyrene and polyisoprene based materials containing reversible linkages.

SourceVirginia Tech·DateAug 29, 2001

Chemists report using infrared lasers to probe key molecular interactions

Researchers have developed a new technique called Doubly Vibrationally Enhanced (DOVE) Four Wave Mixing, which uses two infrared lasers to study molecular connections and vibrations. This method allows chemists to gain insights into complex scientific problems, such as bacterial resistance to antibiotics and soil weathering.

SourceUniversity of Wisconsin-Madison·JournalPhysical Review Letters·DateFeb 7, 2000

Protein component apparently plays key role in muscle elasticity

A pair of hydrogen bonds in titin allows muscle to stretch and return to normal by regulating unfolding of protein sections. This finding is a significant step forward in understanding muscle elasticity and its role in cardiac muscular diseases.

SourceUniversity of Illinois at Urbana-Champaign, News Bureau·JournalNature·DateNov 3, 1999
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Walking Without Moving: Proton Diffusion In Water

Researchers use fully quantum-mechanical simulations to study proton diffusion in acids, finding that the proton migrates by interconverting hydrogen bonds into strong covalent bonds. Quantum tunneling is not involved, and the defect's delocalization is induced by zero-point motion of excess protons.

SourceMax-Planck-Gesellschaft·JournalNature·DateJan 15, 1999

The Secret Nature Of Hydrogen Bonds

A US-France-Canada physics collaboration has confirmed that hydrogen bonds in water partially get their identity from covalent bonds within the H2O molecule. This property is a manifestation of quantum mechanics' effects, enabling researchers to improve predictions and advance areas like nanotechnology and superconductors.

SourceAmerican Institute of Physics·JournalPhysical Review Letters·DateJan 12, 1999

'Tumbling' Atoms May Help Explain Hydrogen Re-Forming Reactions

Researchers at the University of Illinois have discovered that tumbling atoms play a crucial role in hydrogen re-forming reactions. The study reveals that hydrogens exchange sites with each other, leading to the formation of new bonds between carbon and metal centers.

SourceUniversity of Illinois at Urbana-Champaign, News Bureau·JournalJournal of the American Chemical Society·DateOct 1, 1998

Computational Physics Unravels The Mysteries Of Ice

A team of scientists uncovered how protons move and share in hydrogen bonds under extreme pressure, shedding light on biological processes like enzyme catalysis. This discovery could lead to advancements in materials science and chemistry.

SourceMax-Planck-Gesellschaft·JournalNature·DateMar 30, 1998
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UNC-CH Scientists Observe For First Time How Bonds Behave At High Temperatures

Chemists directly observed how hydrogen atoms behave and bond to surfaces at high temperatures using a scanning tunneling microscope. They found that dangling bonds on the surface unpaired, re-paired multiple times depending on temperature, showing favorable conditions for growing more silicon.

SourceUniversity of North Carolina at Chapel Hill·JournalScience·DateJan 23, 1998

Study: Hydrogen Bonds Aren't Key To DNA Pairing After All

Researchers found that growing strands of DNA can accurately incorporate a nucleotide that closely resembles thymine but lacks hydrogen bonding ability. This finding suggests that the distinctive shapes and sizes of DNA bases may underpin the impressive 99.99-percent accuracy of DNA replication.

SourceUniversity of Rochester·JournalProceedings of the National Academy of Sciences·DateSep 29, 1997

Molecular "Ice Cubes" Reveal Secrets Of Water's Properties

Researchers have discovered that tiny clusters of eight water molecules naturally arrange themselves into small cubic structures, revealing unique properties of water. The study found that even in very small water clusters, water has the capacity to arrange its hydrogen bonds in several distinct orientations.

SourcePurdue University·JournalScience·DateJun 12, 1997