Researchers led by Prof. WANG Bin at National Center for Nanoscience and Technology (NCNST) of the Chinese Academy of Sciences recently reported that strain generated at bubbles of 2D materials can benefit the catalytic activity of the hydrogen evolution reaction (HER). The study was published in Chem Catalysis .
Green hydrogen produced by electrochemical water splitting offers the potential to achieve carbon-neutral production processes. Catalysts play a crucial role in facilitating HER at the anode, making it a key component in the transition to a sustainable energy future. Transition metal dichalcogenides (TMDs), particularly MoS 2 , have drawn attention to replacing platinum-based materials. A series of strategies such as defect, doping, vacancy, and interface engineering have been implemented to improve the catalytic activity of the MoS 2 basal plane for HER.
However, the influence of out-of-plane microstructures (such as wrinkles or ripples, scrolls or folds, and bubbles) that commonly exist in 2D materials due to their flexibility, has often been overlooked. Therefore, the correlation between the active sites and the tested performance of catalysts is still questionable, especially considering the easy appearance of curved morphology in actual catalysts.
In this study, Prof. WANG’s team—inspired by bubbles fabricated via the top-down approach—successfully tailored bubbles with different “substrate-free” curvature at the interfaces between monolayer MoS 2 and hBN using a droplet-assisted transfer method.
Finite element modeling (FEM) calculations demonstrated a gradual increase in strain distribution, moving from the bubble’s periphery towards its center. Large bubbles can reach strain levels as high as 1.74%. Density functional theory (DFT) showed that these bubbles induce strain formation on MoS 2 , which enhances the adsorption of protons and HER kinetics. Consequently, there was a substantial boost in HER activity, with values reaching 129.65 mA cm -2 compared to 48.11 mA cm -2 at -0.4 V vs. reversible hydrogen electrode (RHE).
"Our team has discovered an innovative method for fabricating bubbles, enabling precise customization and providing insights into the profound influence of bubbles on strain distribution. Experimental results showed that the strain level associated with larger bubbles surpasses the typical lattice distortion-induced strains. We believe that this finding has important implications for understanding the intricate relationship between out-of-plane structures and the intrinsic material properties,” said Prof. WANG.
In addition, theoretical studies showed that the strain appearing in such out-of-plane structures could tune the electronic structure and thus adjust the proton adsorption performance of catalysts. This process not only provides a more efficient and stable catalyst for hydrogen energy production but may also drive technological advances in other related fields.
Chem Catalysis
Strain derived from bubbles at monolayer MoS2/hBN interfaces for enhanced hydrogen evolution reaction activity
12-Mar-2024