As the global energy crisis and greenhouse effect intensify, utilizing renewable electricity to convert carbon dioxide (CO 2 ) into high-value-added fuels has become one of the key pathways to achieving the "Dual Carbon" goals. Recently, the team led by Professor Lei Ge from the State Key Laboratory of Heavy Oil Processing at China University of Petroleum (Beijing) has made significant progress in this field. They successfully developed a copper-zinc (Cu-Zn) bimetallic tandem catalyst that significantly enhances the efficiency and selectivity of the carbon dioxide electroreduction reaction (eCO 2 RR) to produce methane (CH 4 ).
The related research, titled "*Synergistic promotion of proton relay and CO hydrogenation in Cu-Zn tandem catalysts for highly efficient electrocatalytic CO 2 -to-CH 4 conversion," has been published in the prestigious nanoscience journal Nano Research on June 8, 2026.
Methane, the primary component of natural gas, possesses a high gravimetric energy density and is directly compatible with existing energy infrastructure. However, converting CO 2 to methane is a complex kinetic process involving an eight-electron transfer, characterized by high reaction energy barriers and susceptibility to interference from side reactions such as the hydrogen evolution reaction (HER), making product selectivity difficult to control. Traditional single-metal copper-based catalysts, while capable of producing methane, often face challenges including low Faradaic efficiency, narrow potential windows, and poor stability.
To address these challenges, Professor Ge's team innovatively utilized the volatility of zinc at high temperatures, employing a solvothermal method combined with a high-temperature calcination strategy to prepare a series of carbon-coated Cu-Zn bimetallic catalysts (CuZn@C). By precisely controlling the calcination temperature (700℃, 800℃, 900℃), the researchers achieved accurate modulation of the zinc content on the catalyst surface.
Experimental results show that the CuZn800@C sample calcined at 800°C performed the best. At a potential of -1.7 V (vs. the reversible hydrogen electrode), its methane Faradaic efficiency (FE) reached as high as 64.5%, with a partial current density for methane hitting -429.1 mA/cm². Meanwhile, the catalyst demonstrated excellent stability, with only a slight decay in catalytic performance during a continuous 24-hour test.
"The core of this study lies in revealing the 'tandem catalysis system' mechanism constructed by copper and zinc," explained Zhixin Dai, the first author of the paper. "Through in situ infrared spectroscopy and density functional theory (DFT) calculations, we found that zinc and copper play distinct roles in the reaction. Zinc sites are primarily responsible for promoting water dissociation, acting as a 'proton relay station' to supply protons, while copper sites are responsible for lowering the energy barrier for the hydrogenation of the key intermediate *CO to form *CHO."
The research team further discovered that the Cu-Zn dual sites enhance the adsorption capacity of CO 2 , altering its linear molecular structure to make it more susceptible to activation. This "division of labor" tandem effect effectively suppresses the competitive hydrogen evolution reaction and significantly accelerates the conversion pathway from CO 2 to CH 4 .
This work not only provides a new strategy for designing high-performance copper-based methanation catalysts but also offers new insights into understanding bimetallic synergistic catalysis mechanisms, holding significant importance for advancing the development of electrocatalytic CO 2 resource utilization technologies.
Other contributors include Ruichao Bian, Yanping Qiu, Linping Li and Ning Li from the State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of a Petroleum Beijing in Beijing, China.
This work was financially supported by National Natural Science Foundation of China (Grant No. 52473327, 51572295 and 21273285) and National Key R&D Program of China (Grant No. 2021YFA1501300, 2019YFC1907602).
DOI Link:
https://doi.org/10.26599/NR.2026.94908916
About Nano Research
Nano Research is a peer-reviewed, open access, international and interdisciplinary research journal, sponsored by Tsinghua University and the Chinese Chemical Society, published by Tsinghua University Press on the platform SciOpen. It publishes original high-quality research and significant review articles on all aspects of nanoscience and nanotechnology, ranging from basic aspects of the science of nanoscale materials to practical applications of such materials. After 18 years of development, it has become one of the most influential academic journals in the nano field. Nano Research has published more than 1,000 papers every year from 2022, with its cumulative count surpassing 8,000 articles. In 2025 InCites Journal Citation Reports, its 2025 IF is 9.4 (8.3, 5 years), and it continues to be the Q1 area among the four subject classifications. Nano Research Award, established by Nano Research together with TUP and Springer Nature in 2013, and Nano Research Young Innovators (NR45) Awards, established by Nano Research in 2018, have become international academic awards with global influence.
Nano Research
Synergistic promotion of proton relay and *CO hydrogenation in Cu-Zn tandem catalysts for highly efficient electrocatalytic CO2-to-CH4 conversion
8-Jun-2026