Tsukuba, Japan – As well as making it one of the most widely recognized molecules, the distinctive soccer ball shape of C 60 gives it some useful properties. One of which is thought to be electrical conductivity when multiple molecules are close together. Efforts have therefore been made to optimize C 60 so that it can be applied to electronic devices. Now, researchers at the University of Tsukuba have devised a way of depositing films based on C 60 to provide a robust model to study. Their findings are published in The Journal of Physical Chemistry Letters .
Organic electronics—based on carbon atoms—offer advantages such as being cheaper, lighter, and more flexible than traditional metal alternatives. They are therefore expected to play a big part in the future of electronics.
C 60 is a promising organic electronic material that has been further optimized by including a lithium ion inside the cage to give Li@C 60 . If a layer of lithium filled cages can be arranged close together on a surface, the molecular orbitals of these structures—known as superatom molecular orbitals (SAMOs)—are thought to be sufficiently diffuse and overlapping to allow them to transport electrons.
Attempts have been made to prepare Li@C 60 films to study by depositing them from salts. However, the heat required caused the lithium ions to be dislodged, leaving many of the C 60 cages empty. The researchers used a salt with a larger, less strongly bound anion, which meant lower temperatures could be used and a monolayer of intact Li@C 60 could be formed.
“Although our previous efforts to deposit Li@C 60 films gave us the opportunity to study single superatoms, we didn’t get the complete picture we were looking for,” explains study corresponding author Professor Yoichi Yamada. “Using the [Li@C 60 ] NTf 2 − salt produced a stable monolayer and provided us with an excellent opportunity to study the SAMOs.”
The researchers used scanning tunneling microscopy and density functional theory calculations to study the Li@C 60 film. They found that although the s-SAMO was localized on the individual Li@C 60 molecules, the p z -SAMO was much more diffuse, allowing the transport of electrons.
“We have demonstrated a successful model that will be useful for future Li@C 60 monolayer experiments,” says Professor Yamada. “And although we are not quite at the stage of making electronic devices based on Li@C 60 a reality, our findings provide a significant step in the right direction.”
The article, “Direct Visualization of Nearly-Free-Electron States Formed by Superatom Molecular Orbitals in Li@C 60 Monolayer”, was published in The Journal of Physical Chemistry Letters at DOI: 10.1021/acs.jpclett.1c02246.
The Journal of Physical Chemistry Letters
Direct Visualization of Nearly-Free-Electron States Formed by Superatom Molecular Orbitals in Li@C60 Monolayer
10-Aug-2021