The electrochemical oxidation of 5-hydroxymethylfurfural (HMFOR) in alkaline electrolyte is a promising strategy for producing high-value chemicals from biomass derivatives. However, the disproportionation of aldehyde groups under strong alkaline conditions and the polymerization of HMF to form humic substances can impact the purity of 2,5-furandicarboxylic acid (FDCA) products. The use of neutral electrolytes offers an alternative environment for electrolysis, but the lack of OH − ions in the electrolyte often leads to low current density and low yields of FDCA.
In this study, a sandwich-structured catalyst, consisting of Ru clusters confined between unilamellar MnO 2 nanosheets (S-Ru/MnO 2 ), was used in conjunction with an electrochemical pulse method to realize the electrochemical conversion of 5-hydroxymethylfurfural into FDCA in neutral electrolytes. Pulse electrolysis and the strong electron transfer between Ru clusters and MnO 2 nanosheets help maintain Ru in a low oxidation state, ensuring high activity. The increased *OH generation led to a groundbreaking current density of 47 mA/cm 2 at 1.55 V vs. reversible hydrogen electrode (RHE) and an outstanding yield rate of 98.7% for FDCA in a neutral electrolyte. This work provides a strategy that combines electrocatalyst design with an electrolysis technique to achieve remarkable performance in neutral HMFOR.
https://www.sciencedirect.com/science/article/pii/S2095927324006479#f0025
Science Bulletin