The international study focuses on the differences of complex acid-base equilibria (i.e., the ratio between basic and acidic components) inside the bulk of a solution on one hand, and at the very interface between the solution and the surrounding vapor on the other. While it is straightforward to measure acid-base equilibria in the bulk of a solution using state-of-the art methods, determining these equilibria at the boundary between a solution and the surrounding gas phase is challenging. Even though this boundary layer is about one hundred thousand times narrower than a human hair, it plays a very important role in processes that influence air pollution and climate change. Examining the chemistry of the solution-vapor boundary on a molecular scale thus helps to develop improved models for our understanding of the fate of aerosols in the atmosphere and their influence on the global climate.
1. Complex acid-base equilibria determined: The researchers used complementary spectroscopic methods to unravel the complex acid-base equilibria that result when the pollutant sulfur dioxide (SO 2 ) is dissolved in water.
2. Unique behavior at the liquid-vapor interface: Under acidic conditions, the tautomeric equilibrium between bisulfite and sulfonate is strongly shifted towards the sulfonate species.
3. Stabilization at the interface: Molecular dynamic simulations revealed that the sulfonate ion and its acid (sulfonic acid) are stabilized at the interface due to ion pairing and higher dehydration barriers, respectively. This explains why the tautomeric equilibria are shifted at the interface.
The findings highlight the contrasting behaviors of chemicals at the interface versus the bulk environment. This difference significantly impacts how sulfur dioxide is absorbed and reacts with other pollutants like nitrogen oxides (NO x ) and hydrogen peroxide (H 2 O 2 ) in the atmosphere. Understanding these processes is crucial for developing strategies to reduce air pollution and its harmful effects on health and the environment.
Nature
Direct observation of the complex S(IV) equilibria at the liquid-vapor interface
18-Oct-2024