Tsukuba, Japan – It is well-established that the accumulation of greenhouse gases, like carbon dioxide (CO 2 ), in the atmosphere contributes to climate change. Therefore, CO 2 capture and recycling are vital for mitigating detrimental environmental effects and addressing the climate crisis. Recently, researchers from Japan designed a polymer-coated metal catalyst that accelerates CO 2 conversion and offers green energy insights.
In a study published in ACS Catalysis , researchers from the University of Tsukuba describe porous tin (Sn) catalysts coated with polyethylene glycol (PEG) and show how this polymer facilitates CO 2 transformation into a useful carbon-based fuel.
Various polymers can capture CO 2 molecules, and Sn catalysts are known to reduce CO 2 to other molecules, like formate (HCOO – ), which can be reused to power fuel cells.
“We were interested in combining these capabilities into a single catalytic system that could scrub CO 2 from its surroundings and recycle it into formate,” says research group leader, Professor Yoshikazu Ito. “However, it’s difficult to obtain only the desired product, formate, at a high production rate and in high yield, so we had to fine-tune the catalyst design.”
The formate production rate of PEG-coated Sn was 24 times higher than that of a conventional Sn plate electrode, and no byproducts were detected (>99% yield of formate). To understand this enhanced CO 2 -reduction reaction, the researchers fabricated an Sn catalyst coated with another CO 2 -capturing polymer (polyethyleneimine; PEI) whose structure interacts differently with incoming CO 2 . The PEG-coated Sn still outperformed the PEI-coated Sn, and considering the chemical characteristics of these polymers, the authors proposed that PEI held the CO 2 molecules too tightly, whereas PEG struck a key balance in capturing and then releasing CO 2 to the catalytic Sn core.
“Modeling this reaction using theoretical computations confirmed the favorability of PEG shuttling CO 2 to the Sn center and explained the accelerated formate production,” explains PhD student, Samuel Jeong. “However, we wanted to further clarify the PEG-CO 2 interactions.”
More detailed computations revealed that while the absence of polymer limits the Sn catalyst’s CO 2 -capture ability, an excessively dense layer of PEG inhibits CO 2 transfer to the metal surface, thereby decreasing formate production. Therefore, a complete but relatively sparse layer of PEG is optimal for funneling CO 2 to Sn, while maintaining a CO 2 -rich environment and preventing byproduct release.
The mantra “reduce, reuse, recycle” no longer only refers to single-use plastics. The simple catalyst-coating technique reported by Ito and co-workers can be used to develop systems that efficiently recycle CO 2 into useful compounds, like formate, which can power fuel cell devices that provide green electricity.
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The article, “Polyethylene Glycol Covered Sn Catalysts Accelerate the Formation Rate of Formate by Carbon Dioxide Reduction,” was published in ACS Catalysis at DOI: 10.1021/acscatal.1c02646
Funding Statement:
This work was sponsored by a JSPS Grant-in-Aid for Scientific Research on Innovative Areas “Discrete Geometric Analysis for Materials Design” (Grant Nos. JP20H04628 and JP20H04639), the JSPS KAKENHI (Grant Nos. JP21H02037 and JP19K15505), the Futaba Research Grant Program of the Futaba Foundation, KONDO-ZAIDAN, and a cooperative program (Proposal No. 202011-CRKEQ-0001) of the CRDAM-IMR, Tohoku University, the Open Facility, Research Facility Center for Science and Technology, University of Tsukuba.
ACS Catalysis
Polyethylene Glycol Covered Sn Catalysts Accelerate the Formation Rate of Formate by Carbon Dioxide Reduction
26-Jul-2021