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After desalination, brine gets a second life in solar-driven methane conversion

08.20.26 | Science China Press
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As offshore exploration moves into increasingly remote waters, a new challenge is emerging: how to make marine platforms more self-sufficient. Beyond extracting resources, future offshore facilities will need to secure freshwater supplies, utilize local resources efficiently, and reduce dependence on external logistics. Addressing this challenge requires new strategies that connect resource production and chemical manufacturing within a single integrated process.

China’s Deep Sea One energy station in the South China Sea represents the expanding frontier of offshore development. However, sustaining long-term operation in remote marine environments remains challenging. Offshore platforms have access to abundant seawater and methane resources, yet these resources are rarely integrated. Seawater desalination can provide essential freshwater but also generates concentrated brine that requires further management, while methane remains difficult to convert into higher-value chemicals because of its strong carbon-hydrogen bonds.

Researchers from the University of Science and Technology of China, Anhui Normal University, and the University of Trieste have developed a solar-driven offshore continuous-flow platform that connects these previously separate processes. The system gives concentrated desalination brine a second life by transforming it from a byproduct into a chemical resource for methane conversion while simultaneously producing freshwater.

The process begins with sunlight-driven photothermal evaporation, which produces freshwater while concentrating chloride ions in the remaining brine. Instead of being discarded, the concentrated brine is directly reused as the chlorine source for photocatalytic methane conversion into chloromethane. By linking desalination and chemical synthesis, the platform creates a resource loop in which the output of one process becomes the input for another.

A key feature of the technology is a floating gas-liquid-solid catalytic interface, where methane, chloride-containing water, and the photocatalyst are brought into close contact. This interfacial architecture enables selective methane activation and chloromethane formation under mild conditions, providing an alternative to conventional chlorination processes that typically require high temperatures and external chlorine sources.

To improve methane conversion, the researchers developed a platinum-modified titanium dioxide photocatalyst. Platinum promotes charge separation and facilitates methane activation, while aluminum ions regulate the local reaction environment by preventing excessive alkalization near the interface and maintaining conditions favorable for selective chloromethane formation. Spectroscopic studies revealed that the catalyst surface and surrounding chemical environment work together to guide methane transformation pathways.

Under ambient conditions, the photocatalytic system achieved 98.1 percent selectivity toward chloromethane with a production rate of 2.9 millimoles per gram per hour. The researchers further demonstrated the technology in a solar-driven continuous-flow setup. Under one-sun illumination, the system produced freshwater at a rate of 1.25 kilograms per square meter per hour. Using concentrated desalination brine, the platform achieved a chloromethane production rate of 79.5 millimoles per square meter per hour and maintained stable operation for 15 days. A nanofiltration process enabled efficient recovery and recycling of the aluminum additive, with more than 98 percent retention.

Instead of treating desalination brine as a waste stream, this study shows that it can become part of a circular resource pathway for offshore chemical manufacturing. By coupling freshwater generation with methane valorization, the solar-driven approach improves resource efficiency while reducing waste in offshore environments.

More broadly, the work presents a new vision for offshore chemical manufacturing, where marine platforms could evolve beyond resource extraction sites into integrated hubs that produce freshwater and value-added chemicals using local resources and sunlight. This approach offers a promising pathway toward more sustainable and self-sufficient offshore operations.

National Science Review

10.1093/nsr/nwag440

Experimental study

Keywords

Article Information

Contact Information

Bei Yan
Science China Press
yanbei@scichina.com

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This article is based on a news release from Science China Press. BrightSurf curates and republishes science news from research institutions worldwide; the original release is linked below.

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APA:
Science China Press. (2026, August 20). After desalination, brine gets a second life in solar-driven methane conversion. Brightsurf News. https://www.brightsurf.com/news/LPEZ3GN8/after-desalination-brine-gets-a-second-life-in-solar-driven-methane-conversion.html
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"After desalination, brine gets a second life in solar-driven methane conversion." Brightsurf News, Aug. 20 2026, https://www.brightsurf.com/news/LPEZ3GN8/after-desalination-brine-gets-a-second-life-in-solar-driven-methane-conversion.html.