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In a hurry to develop drugs? Here's your cHAT

Rice University scientists have developed a novel 'green' method for producing pharmaceutical intermediates using the cooperative hydrogen atom transfer (cHAT) technique. This approach employs earth-abundant iron and sulfur as catalysts, reducing costs and environmental impact compared to traditional methods.

SourceRice University·JournalJournal of the American Chemical Society·DateOct 30, 2020

Solar hydrogen: let's consider the stability of photoelectrodes

Researchers have conducted the first operando stability study of high-purity BiVO4 photoanodes during photoelectrochemical oxygen evolution reaction (OER). Using in-situ plasma mass spectrometry, they determined a useful parameter called the stability number (S), which can be used to compare and assess the stability of photoelectrodes.

SourceHelmholtz-Zentrum Berlin für Materialien und Energie·JournalACS Applied Energy Materials·DateOct 26, 2020

Smarter models, smarter choices

Researchers developed a new mathematical framework that leverages uncertainty and expert knowledge to create more accurate and efficient computer models. This method provides guarantees on model performance and can lead to breakthroughs in renewable energy, battery technology, and other fields.

SourceUniversity of Delaware·JournalScience Advances·DateOct 19, 2020

How consumers responded to COVID-19

The study identifies four threats that affect consumer behavior, including health, economic, social, and misinformation threats. Consumers have shown adaptive responses to these challenges, such as switching to online streaming services or making their own hand sanitizer.

SourceUniversity of Maryland·JournalJournal of Consumer Research·DateOct 12, 2020

Palladium catalysts can do it

Researchers have found a way to directly couple aryl halides and alkyllithium compounds using palladium catalysts containing YPhos-type ligands. This breakthrough enables the efficient synthesis of complex chemical structures with minimal side products, reducing costs and environmental impact.

SourceWiley·JournalAngewandte Chemie International Edition·DateOct 9, 2020

Spinach: good for popeye and the planet

Researchers at American University have developed a new method to create highly active and stable oxygen reduction reaction catalysts from spinach, which outperforms commercial platinum catalysts. The spin-based catalysts have potential applications in hydrogen fuel cells and metal-air batteries.

SourceAmerican University·JournalACS Omega·DateOct 5, 2020

Noble metal clusters can enhance performance of catalysts and save resources

Researchers at Karlsruhe Institute of Technology (KIT) have discovered that noble metal clusters are more reactive than individual atoms, allowing for improved removal of exhaust gases. The clusters exhibit optimal structure for high activity, enabling the development of catalysts with enhanced stability and long-term performance.

SourceKarlsruher Institut für Technologie (KIT)·JournalNature Catalysis·DateOct 1, 2020

Better catalysts for a sustainable bioeconomy

The researchers recommend returning to classic zeolites, which are efficient catalysts that can be modified and adapted for specific purposes. The team found inconsistencies in the literature on how aluminium atoms catalyse reactions, highlighting the need for further understanding of these active centres.

SourcePaul Scherrer Institute·JournalNature Materials·DateSep 21, 2020

Shape matters for light-activated nanocatalysts

A study by Rice University's Laboratory for Nanophotonics found that aluminum nanocatalysts with sharply pointed corners, dubbed 'octopods,' have a higher reaction rate and lower activation energy than similar shapes. The research builds on previous efforts to develop commercially viable light-activated nanocatalysts.

SourceRice University·JournalACS Nano·DateSep 18, 2020

Cascades with carbon dioxide

Researchers develop a conceptually new process to produce cyclic carbonates from CO2 and basic building blocks, offering potential for biodegradable plastics and pharmaceutical intermediates. The process yields six-membered rings with great potential for creating new CO2-based polycarbonates.

SourceWiley·JournalAngewandte Chemie International Edition·DateSep 8, 2020

New Nitrogen Assembly Carbon catalyst has potential to transform chemical manufacturing

Scientists have discovered a metal-free carbon-based catalyst with potential to transform chemical manufacturing, enabling more efficient reactions without expensive transition metals. The catalysts are robust and deliver unexpected catalytic reactions for various processes including hydrogenolysis, dehydrogenation, and hydrogenation.

SourceDOE/Ames National Laboratory·JournalNature Communications·DateAug 26, 2020

Hydrogen vehicles might soon become the global norm

Researchers at the University of Copenhagen have developed a new catalyst that can produce cheaper and more sustainable hydrogen-powered vehicles, reducing reliance on precious materials like platinum. The breakthrough could make hydrogen vehicles more durable and scalable, leading to a potential shift towards sustainable transportation.

SourceUniversity of Copenhagen·JournalNature Materials·DateAug 24, 2020