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CO2 catalysis made more accessible

Researchers have discovered a new aerogel electrocatalyst formed from inexpensive metal alloys, enabling highly efficient electrochemical conversion of carbon dioxide. The process achieves an efficiency of 93% with minimal byproducts.

SourceWiley·JournalAngewandte Chemie International Edition·DateApr 30, 2021

How acidic are atoms?

Researchers at Vienna University of Technology have developed a new microscopy technique that allows for the measurement of atomic acidity on surfaces. This breakthrough enables analysis of catalysts on an atomic scale, which is crucial for improving chemical reactions.

Sustainable chemical synthesis with platinum

Researchers have created a new catalyst that allows for more efficient and sustainable production of aromatic hydrocarbons using renewable sources like woody biomass. The catalyst reduces the need for high temperatures and pressures, minimizing energy costs and emissions.

SourceUniversity of Tokyo·JournalNature Catalysis·DateApr 19, 2021

New study reveals charge transfer at interface of spinel oxide and ceria during CO oxidation

A recent study has unveiled a new principle that active charge transfer at the interface between non-noble metals can enhance the catalytic performance of complex oxide catalysts. The researchers found that CeO2-deposited spinel oxide nanocubes exhibited a 12-times higher CO oxidation rate than pristine Co3O4 NCs.

The fastest one wins

A team at the Indian Institute of Science developed a catalytic version of the Fischer indole synthesis that primarily produces one enantiomer. The reaction involves a dynamic kinetic resolution mechanism with a chiral catalyst, resulting in moderate yields and good to excellent enantiomeric selectivity.

SourceWiley·JournalAngewandte Chemie International Edition·DateApr 8, 2021

High index surfaces-exposed PtCu3@Pt3Cu@Pt nanodendrites as ORR electrocatalyst

Researchers designed a nanodendrite Pt-Cu alloy electrocatalyst with high-index surfaces and graded composition, achieving excellent mass and area activities for oxygen reduction reaction. The catalyst's unique morphology and composition provide a high specific surface area to improve Pt utilization and enhance ORR activity.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalChinese Journal of Catalysis·DateApr 7, 2021

Story tips: Mighty Mo material, fueling retooling, goods on the move, doubling concrete and more

Researchers at Oak Ridge National Laboratory have developed a refractory metal alloy that can withstand extreme temperatures and is viable for additive manufacturing. The team also created an electrocatalyst that enables the conversion of water and carbon dioxide into higher weight hydrocarbons, set to reduce fuel costs.

SourceDOE/Oak Ridge National Laboratory·JournalConstruction and Building Materials·DateApr 5, 2021

Dual-bed catalyst enables high conversion of syngas to gasoline-range liquid hydrocarbons

Researchers at Dalian Institute of Chemical Physics developed a dual-bed catalyst that achieves highly efficient and selective conversion of syngas to gasoline-range liquid hydrocarbons. The catalyst showed excellent stability, with selectivities of C5-11 and C3-11 in the hydrocarbon products reaching 80.6% and 98.2%, respectively.

Synthetic mucus can mimic the real thing

Researchers at MIT have created synthetic mucins with a polymer backbone that mimic the structure and function of naturally occurring mucins, effectively neutralizing the bacterial toxin that causes cholera. This breakthrough could lead to new treatments for infectious diseases and potentially less resistance to antibiotics.

SourceMassachusetts Institute of Technology·JournalACS Central Science·DateMar 30, 2021

Making plastics production more energy efficient

Researchers at Northwestern University have developed a new method for producing propylene, a key component of plastics, that uses less energy. The technique, which involves the use of two catalysts, produces yields up to 30% higher than traditional methods, making it a promising solution for more energy-efficient plastics production.

SourceNorthwestern University·JournalScience·DateMar 22, 2021

Cu-based small-pore zeolites for deNOx

Cu-based small-pore zeolites have been demonstrated to be promising candidates for NH3-SCR catalysts due to their unique structural features and physicochemical properties. The latest advances in Cu-SSZ-13 applied to the NH3-SCR reaction highlight the significant opportunity presented by zeolite-based catalysts.

SourceScience China Press·JournalNational Science Review·DateMar 17, 2021

Simple iodine will speed up drug discovery

Researchers from Osaka University have developed a sustainable method for synthesizing vicinal diamines, crucial in medications for influenza and colorectal cancer. The process uses molecular iodine as a catalyst, reducing the need for rare and toxic metals.

SourceOsaka University·JournalJournal of the American Chemical Society·DateMar 15, 2021

Chemistry goes under cover

Scientists have discovered that covering metal catalyst surfaces with thin two-dimensional oxide materials can significantly enhance chemical reactions. The new method uses partially covered palladium surfaces with silica films to boost carbon dioxide production by 20%. This approach allows for more efficient and effective catalytic co...

SourceDOE/Brookhaven National Laboratory·JournalAngewandte Chemie International Edition·DateMar 2, 2021

Modeling a better catalyst for PIBSAs

Researchers have developed a computational model to improve the production of polyisobutenyl succinic anhydrides (PIBSAs) for auto industry formulations. The study reveals the detailed mechanism of Lewis acid-catalyzed reactions, enabling faster and more efficient synthesis with reduced energy input.

SourceUniversity of Pittsburgh·JournalIndustrial & Engineering Chemistry·DateFeb 17, 2021