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More ancestral enzyme

The study reports the crystal structures of aconitase X enzymes from bacteria and archaea, providing novel insights into their catalytic mechanisms. The findings suggest that ancestral active sites in aconitase superfamily are conserved across different species.

SourceEhime University·JournalCommunications Biology·DateJul 8, 2021

Scientists home in on recipe for entirely renewable energy

Researchers from Trinity College Dublin have made significant progress in developing a recipe for entirely renewable energy by splitting water to produce green hydrogen. The team has identified nine earth-abundant metal combinations as highly promising leads for experimental investigation, with chromium, manganese, and iron standing ou...

SourceTrinity College Dublin·JournalCell Reports Physical Science·DateJul 7, 2021

Buttoned up biomolecules

Researchers have introduced a novel click reaction suitable for living cells and organisms, enabling the labeling of biomolecules without affecting physiological processes. The reaction uses linear, terminal alkynes and N,N-dialkylhydroxylamines to form biocompatible enamine-N-oxides.

SourceWiley·JournalAngewandte Chemie International Edition·DateJun 30, 2021

Quantum dots keep atoms spaced to boost catalysis

Rice University engineers developed a strategy to increase the number of transition-metal single atoms that can be loaded onto a carbon carrier using graphene quantum dots. The new technique showed significant improvement in electrochemical reduction of carbon dioxide compared to lower metal loading catalysts.

SourceRice University·JournalNature Chemistry·DateJun 24, 2021

Light-harvesting nanoparticle catalysts show promise in quest for renewable carbon-based fuels

A study by University of Illinois researchers has shown that small quantities of hydrocarbons can be produced when CO2 and water react in the presence of light and a silver nanoparticle catalyst. The findings demonstrate a viable technology for renewable energy generation and chemical manufacturing.

From milk protein, a plastic foam that gets better in a tough environment

Researchers at KTH Royal Institute of Technology developed a high-performance plastic foam from whey proteins that can withstand extreme temperatures. The material, which improves its mechanical performance after days of exposure to high temperatures, has potential applications in filtration, thermal insulation, and fluid absorption.

SourceKTH, Royal Institute of Technology·JournalAdvanced Sustainable Systems·DateJun 11, 2021

Active platinum species

Researchers investigated individual platinum atoms and small clusters on special zeolite supports, finding they are significantly more active than larger clusters in splitting oxygen. Platinum clusters also dominate CO oxidation, while individual atoms enable efficient methane combustion.

SourceWiley·JournalAngewandte Chemie International Edition·DateJun 10, 2021

How catalysts age

Scientists at the Paul Scherrer Institute have developed a new experimental method to investigate the ageing process of vanadium phosphorus oxides (VPO) catalysts. The method allows for precise measurement of chemical properties in three dimensions, revealing changes in the material's structure and chemistry over time.

SourcePaul Scherrer Institute·JournalScience Advances·DateJun 9, 2021

Passing the acid test: New low-pH system recycles more carbon into valuable products

Researchers at the University of Toronto have developed a new electrochemical system that converts more than 50% of CO2 into valuable products. The system runs under acidic conditions, which reduces undesired side reactions and enhances efficiency, making it an economically viable solution for carbon capture and utilization.

Nanomaterials with laser printing

Researchers develop a laser-driven method to synthesize nanoparticles, enabling efficient conversion of solar energy into electricity. The technology also promotes the production of green hydrogen by employing photoelectrodes that use sunlight directly.

SourceMax-Planck-Gesellschaft·JournalNature Communications·DateJun 2, 2021

Scientists demonstrate a better, more eco-friendly method to produce hydrogen peroxide

Researchers have developed a more efficient and environmentally friendly method to produce hydrogen peroxide by using palladium-gold nanoparticles as a catalyst. The new process produces almost 100% hydrogen peroxide with minimal water formation, making it a promising alternative to traditional methods.

SourceUniversity of Illinois College of Liberal Arts & Sciences·JournalJournal of the American Chemical Society·DateJun 1, 2021

Solar energy-driven sustainable process for synthesis of ethylene glycol from methanol

Researchers developed a novel solar energy-driven method to produce ethylene glycol (EG) from methanol, offering a sustainable and clean alternative. The catalyst, nitrogen-doped tantalum oxide, demonstrated high activity and stability for EG production, making it an environmentally friendly candidate for industrial applications.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalChinese Journal of Catalysis·DateJun 1, 2021

Graphene-based nanozyme helps to detect L-cysteine in serum

A novel graphene-based nanozyme was developed using Ganoderma lucidum extract polysaccharides, enabling high sensitivity and selectivity detection of L-cysteine in serum. The study published in Analytical and Bioanalytical Chemistry demonstrated improved stability and dispersion of the nanozyme in water.

SourceHefei Institutes of Physical Science, Chinese Academy of Sciences·JournalAnalytical and Bioanalytical Chemistry·DateMay 31, 2021

Tuning the intermediate reaction barriers by a CuPd catalyst for CO2 electroreduction to C2 products

Researchers designed a Cu-Pd bimetallic electrocatalyst that lowers the energy barrier of C2 product generation, resulting in a 50.3% C2 Faradaic efficiency. The catalyst exploits the benefits of both Cu (low energy barrier) and Pd (ultrafast kinetics), addressing CO2 conversion limitations.

AI-aided search for single-atom-alloy catalysts yields more than 200 promising candidates

Researchers at Skoltech developed a new algorithm to identify over 200 previously unknown single-atom-alloy catalysts with improved stability and performance. The AI-powered approach uses machine learning models to extract key parameters from computational data, providing a recipe for finding the best SAACs for specific applications.

Toward overcoming solubility issues in organic chemistry

A team of four scientists from Hokkaido University developed a rapid and efficient protocol for cross-coupling reactions using ball milling, expanding the pool of chemicals usable in organic synthesis. They successfully applied this method to mostly-insoluble aryl halides, yielding desired products.

SourceHokkaido University·JournalJournal of the American Chemical Society·DateMay 18, 2021