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Supernova: A glowing DNA enzyme

Researchers at IOCB Prague have created a glowing DNA enzyme called Supernova, which catalyzes a chemiluminescent reaction. This breakthrough uses artificial evolution to identify light-producing deoxyribozymes in a vast library of DNA molecules, opening up new possibilities for point-of-care assays and high-throughput screens.

Anionic Nickel

Researchers discovered that nickel can catalyze the cross-coupling of aryl ethers through a nickelate anion. This reaction pathway relies on the formation and stability of the catalyst, providing an alternative to traditional palladium-catalyzed cross-couplings.

SourceWiley·JournalAngewandte Chemie International Edition·TypeExperimental study·DateOct 20, 2021

Bimetallic catalysts for oil extraction

Researchers have developed bimetallic catalysts that enhance oil upgrading, decreasing heavy hydrocarbons and increasing light hydrocarbons. The test results showed positive influence on petroleum quality, transportation efficiency, and environmental impact.

SourceKazan Federal University·JournalJournal of Petroleum Exploration and Production Technology·TypeExperimental study·DateOct 15, 2021

Predict phosphine reactivity with one simple metric

Researchers developed a predictive tool using %V bur (min) to categorize phosphine structures as active or inactive in many experimental datasets. This advancement will facilitate organometallic chemistry and catalysis, enabling easier computation and prediction of phosphine reactivity.

SourceUniversity of Utah·JournalScience·TypeComputational simulation/modeling·DateOct 14, 2021

Manganese makes its mark in drug synthesis

Rice chemist Julian West and graduate student Yen-Chu Lu discovered manganese as a more efficient catalyst for synthesizing fluoroketones, precursor molecules for drugs. The use of manganese reduces material costs and simplifies purification.

SourceRice University·JournalACS Catalysis·TypeExperimental study·DateOct 5, 2021

Researchers measure the breakup of a single chemical bond

Using advanced microscopy techniques, researchers recorded the breaking of a single chemical bond between a carbon atom and an iron atom on different molecules. The team measured the mechanical forces applied at the moment of breakage, revealing insights into the nature of these bonds and their implications for catalysis.

SourcePrinceton University, Engineering School·JournalNature Communications·TypeExperimental study·DateOct 4, 2021

Researchers propose strategy to inhibit over-oxidation for oxidative dehydrogenation of ethane

Dalian Institute of Chemical Physics researchers propose dual active site strategy to isolate dehydrogenation and oxidation in oxidative dehydrogenation of ethane, resulting in near 100% ethene selectivity. This approach could be extended to multiple oxidation reactions plagued by over-oxidation.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalNature Communications·TypeCommentary/editorial·DateSep 27, 2021

Identifying activity origin of single-atom catalyst through atom-by-atom counting

A new methodology, EMARS, was developed to directly identify the activity origin of Pt/Al2O3 industrial reforming catalyst by analyzing over 18,000 Pt atoms. The study found that density of supported Pt1 single atoms and Pt-Pt distance larger than 0.38 nm are correlated with aromatic production activity.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalJournal of the American Chemical Society·TypeCommentary/editorial·DateSep 10, 2021

Using electricity to give chemistry a boost

Researchers have successfully produced iron-based Metal Organic Framework (MOF) materials directly using renewable electricity at room temperature, overcoming challenges in scalability and environmental friendliness. The new method is 96% efficient and enables the creation of advanced MOF sensors.

SourceUniversity of Delaware·JournalACS Central Science·DateSep 8, 2021

Mining waste could be used as an ingredient for cheaper hydrogen fuel production

Researchers have discovered a way to use mining waste as part of a potential cheaper catalyst for hydrogen fuel production. The new catalyst triggers water splitting reactions using aluminosilicate minerals found in mining waste, which could lead to lower production costs and increased efficiency.

SourceQueensland University of Technology·JournalAdvanced Energy and Sustainability Research·TypeExperimental study·DateSep 7, 2021

New research advances clean energy solutions

Researchers at Arizona State University have developed a synthetic diiron-containing porphyrin that can efficiently catalyze the conversion of radiant energy from the sun into chemical energy. This breakthrough has potential applications in creating non-fossil-based fuels and electrochemical cells for renewable energy storage.

SourceArizona State University·JournalChemElectroChem·TypeExperimental study·DateSep 2, 2021

Scientists discover zeolite-tailored active site proximity for efficient production of pentanoic biofuels

Researchers design a new strategy for producing pentanoic biofuels by synthesizing Ru metal nanoclusters confined within zeolite Y. This approach boosts chemoselectivity and promotes catalytic activity. The findings extend the notion of 'the closer, the better' into biomass catalysis.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalAngewandte Chemie International Edition·TypeCommentary/editorial·DateSep 1, 2021

Best of both worlds: Updating the chemical process to remove organic pollutants from water

Researchers from India and Saudi Arabia have combined oxidation and photocatalysis to create a heterogeneous photo-Fenton system that degrades phenols at higher rates than individual approaches. The system is highly photostable and reusable, making it promising for practical applications in wastewater purification.

SourceShoolini University·JournalJournal of Industrial and Engineering Chemistry·TypeExperimental study·DateSep 1, 2021

A new approach creates an exceptional single-atom catalyst for water splitting

Scientists created a new approach to anchoring individual iridium atoms on the surface of a catalytic particle, increasing its efficiency in splitting water molecules to record levels. This breakthrough could ease the bottleneck for sustainable energy production by enabling more efficient electrolysis.

SourceDOE/SLAC National Accelerator Laboratory·JournalProceedings of the National Academy of Sciences·TypeExperimental study·DateAug 31, 2021

Anchoring single atoms

Researchers from Vienna University of Technology have developed a new method to anchor single atoms on surfaces, paving the way for single-atom catalysis. The technique uses silicon atoms as anchors for single metal atoms, which can be used to accelerate chemical reactions.

SourceVienna University of Technology·JournalACS Nano·TypeExperimental study·DateAug 31, 2021

Improved water splitting method: A green energy innovation by Pusan National University

Researchers at Pusan National University have developed a novel electrocatalyst that can effectively produce hydrogen and oxygen from water at low cost. The catalyst, composed of transition metal phosphates, achieves high surface area and fast charge transfer, making it suitable for commercial on-site production of hydrogen.

SourcePusan National University·JournalApplied Catalysis B Environment and Energy·TypeExperimental study·DateAug 30, 2021

NTU Singapore scientists develop ‘greener’ way to make fertiliser

Researchers at Nanyang Technological University (NTU) Singapore have devised a new method for producing urea, a key compound in fertilisers, through electrocatalysis. This approach produces urea five times more efficiently than previous methods and has the potential to contribute to sustainable agricultural practices.

SourceNanyang Technological University·JournalNature Sustainability·TypeExperimental study·DateAug 19, 2021

Nanocluster discovery will protect precious metals

Researchers from the University of Nottingham have developed a novel catalyst that combines homogeneous and heterogeneous features, defying traditional categorization. The discovery holds promise for increasing the active surface area available for catalysis, leading to more efficient and sustainable production of molecules.

SourceUniversity of Nottingham·JournalNature Communications·TypeExperimental study·DateAug 17, 2021

Harnessing sunlight to fuel the future through covalent organic frameworks

Researchers highlight the potential of covalent organic frameworks (COFs) in solar-to-fuel production, converting sunlight into hydrogen and other fuels. COF-based photocatalysts have shown promising properties, including improved catalysis and electron delocalization, making them a viable solution for future energy needs.

SourceShoolini University·JournalCoordination Chemistry Reviews·TypeLiterature review·DateAug 12, 2021

Less is more: 'Reduction' allows for cleaner and more efficient catalytic reactions

Researchers at Tokyo Institute of Technology have developed a high-yield synthesis pathway through reduction of rhodium complexes, enabling the addition of electron-deficient boron groups to arenes. This new strategy uses a cyclopentadienyl-rhodium-based catalyst and produces arylboronates with high yields and cleaner conditions.

SourceTokyo Institute of Technology·JournalJournal of the American Chemical Society·TypeExperimental study·DateAug 11, 2021

Striking gold: A pathway to stable, high-activity catalysts from gold nanoclusters

A team of researchers at Tokyo University of Science has developed a stable and highly active photocatalyst from gold nanoclusters. By removing the protective molecules around the nanoclusters, they were able to increase their catalytic activity and stability, opening up new possibilities for hydrogen generation and other applications.

SourceTokyo University of Science·JournalAngewandte Chemie·TypeExperimental study·DateAug 10, 2021

Polymer coating accelerates fuel production

Researchers from University of Tsukuba and Osaka University developed a polymer-coated metal catalyst that accelerates CO2 conversion into formate, a useful carbon-based fuel. The PEG-coated Sn catalyst showed a 24 times higher formate production rate than conventional Sn plate electrodes.

SourceUniversity of Tsukuba·JournalACS Catalysis·DateAug 5, 2021

Story tips: Sensing oil leaks, 3D prints in space, more fuel from ethanol, Arctic modeling boost, making isotopes faster and nano-enabled microscopy

Researchers at Oak Ridge National Laboratory are advancing various technologies to minimize oil leaks, enable 3D printing in space, and increase fuel efficiency from ethanol. They have developed a quantum sensing system to detect pipeline leaks more quickly, built a thermal protection shield for a capsule launched into space, and creat...

SourceDOE/Oak Ridge National Laboratory·JournalNature·TypeImaging analysis·DateAug 2, 2021

Manganese could make luminescent materials and the conversion of sunlight more sustainable

Researchers at the University of Basel have developed new luminescent manganese complexes with promising properties, including improved efficiency and stability. These findings offer a potential solution for more sustainable energy production and could lead to the creation of water-soluble variants for medical applications.

SourceUniversity of Basel·JournalNature Chemistry·TypeExperimental study·DateAug 2, 2021

Breathing new life into fuel cells

Researchers at the University of Texas at Austin have discovered a new method to improve oxygen reduction in fuel cells using iron-based single-atom catalysts. This breakthrough could unlock a level of efficiency never before realized, enabling large-scale deployment of fuel cells and their nearly limitless potential applications.

SourceUniversity of Texas at Austin·JournalNature Catalysis·DateJul 28, 2021

‘Double decoration’ enhances industrial catalyst

Researchers at Hokkaido University have designed a highly stable platinum-gallium catalyst that can support propylene production at very high temperatures, making it suitable for a month. The 'doubly decorated' catalyst is alloyed with lead and calcium, which blocks side reactions and improves stability.

SourceHokkaido University·JournalAngewandte Chemie International Edition·TypeExperimental study·DateJul 27, 2021

New strategy for drug design: Keeping copper atoms closer to keep bacteria away

Scientists at Tokyo University of Science developed a copper-containing polymer that greatly enhances the antibacterial activity of hydrogen peroxide. The use of these tailored polymers resulted in higher catalytic activity and more effective killing of bacteria, opening up new design avenues for antimicrobial drugs.

SourceTokyo University of Science·JournalMacromolecular Rapid Communications·TypeExperimental study·DateJul 27, 2021

Controlling asymmetry for drug synthesis

A team of scientists has developed an iridium-catalyzed hydrogen addition method to control asymmetry in drug synthesis. This approach reduces wasteful by-products and enables targeted synthesis with high precision.

SourceWiley·JournalAngewandte Chemie International Edition·TypeExperimental study·DateJul 27, 2021