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New tech aims to drive down costs of hydrogen fuel

Researchers at North Carolina State University have developed a new technique for extracting hydrogen gas from liquid carriers, making it faster, less expensive and more energy efficient. The new method uses sunlight and a reusable photocatalyst to release hydrogen molecules, reducing the need for rhodium and lowering production costs.

SourceNorth Carolina State University·JournalChemSusChem·TypeExperimental study·DateMay 23, 2022

Sparking sustainable new chemical catalysts

Researchers at the University of Pittsburgh have discovered a new catalyst, tungsten oxide, that can efficiently convert carbon dioxide into useful fuels and chemicals. This breakthrough could lead to a significant reduction in global warming by utilizing hydrogen produced from renewable energy sources.

SourceUniversity of Pittsburgh·JournalJournal of the American Chemical Society·DateMay 18, 2022

Lights, catalyst, reaction! Converting CO2 to formic acid using an alumina-supported, iron-based compound

Researchers from Tokyo Tech developed an alumina-supported iron-based catalyst that efficiently converts CO2 into formic acid with up to 90% selectivity. The new catalyst's excellent recyclability and low-cost nature make it a promising candidate for reducing atmospheric CO2 levels and providing energy via combustion.

SourceTokyo Institute of Technology·JournalAngewandte Chemie·TypeExperimental study·DateMay 16, 2022

Microbial juggling

Researchers discovered a soil microbe's enzyme that converts CO2 into carbon compounds 20 times faster than plant enzymes during photosynthesis. The enzyme uses pairs of molecules working in sync like jugglers, with a spot of molecular glue and twisting motion facilitating the reaction.

SourceMax-Planck-Gesellschaft·JournalACS Central Science·TypeExperimental study·DateMay 12, 2022

Step toward a circular economy?

Researchers have discovered a zirconium-based metal–organic framework material that catalyzes the degradation of PET into its monomers. This process can be reused to make high-value PET products, enabling the development of a circular economy. The catalyst breaks down PET waste at 260°C with yields up to 98%

SourceWiley·JournalAngewandte Chemie International Edition·TypeExperimental study·DateMay 9, 2022

Crystal study may resolve DNA mystery

A study by Rice University bioscientists has revealed the presence of a central metal ion critical to DNA replication and implicated in misincorporation. The research found that three metal ions are involved in the process, with the first supporting nucleotide binding and the second stabilizing the binding of loose nucleotides. This di...

SourceRice University·JournalNature Communications·TypeExperimental study·DateMay 9, 2022

Energy researchers invent chameleon metal that acts like many others

Energy researchers have invented a device that electronically converts one metal into behaving like another to use as a catalyst for speeding chemical reactions. The invention opens the door for new catalytic technologies using non-precious metal catalysts, potentially improving efficiency and sustainability in various applications.

SourceUniversity of Minnesota·JournalJournal of the American Chemical Society·DateMay 9, 2022

Rice process aims to strip ammonia from wastewater

Researchers create high-performance catalyst to pull ammonia and solid fertilizer from low-level nitrates in industrial wastewater, reducing carbon dioxide emissions. The process works at room temperature and under ambient pressure, with potential for decentralized ammonia production.

SourceRice University·JournalNature Nanotechnology·TypeExperimental study·DateMay 2, 2022

Environmentally-friendly coatings

Researchers from Konstanz University have developed a new class of water-soluble catalysts that allow for the direct manufacturing of polyethylene dispersions in water. This breakthrough enables environmentally-friendly and emission-free production of plastic coatings, reducing energy consumption and pollution.

SourceUniversity of Konstanz·JournalAngewandte Chemie·DateApr 21, 2022

Haber-Bosch at the atomic scale

Researchers have directly observed N2 adsorption and tunneling electron-induced desorption processes at the atomic scale using scanning tunneling microscopy. The study reveals dominant pairwise electrostatic interactions between K and N2, weakening the molecule bond towards dissociation in the Haber-Bosch synthesis.

SourceUniversity of Pittsburgh·JournalCell Reports Physical Science·TypeImaging analysis·DateApr 21, 2022

Extract from a common kitchen spice could be key to greener, more efficient fuel cells

Researchers at Clemson University and SSSIHL discovered a novel way to combine curcumin and gold nanoparticles to create an electrode that efficiently converts ethanol into electricity. The discovery brings replacing hydrogen as a fuel cell feedstock one step closer, with potential applications in sensors and supercapacitors.

SourceClemson University·JournalNano Energy·TypeExperimental study·DateApr 18, 2022

A sustainable photocatalytic method to introduce the pyridine and valuable functional groups into alkenes

A novel visible light-promoted transition-metal-free acetalation-pyridylation of alkenes has been developed, providing a sustainable way to introduce pyridine and valuable functional groups. The methodology enables diverse modifications of drugs with excellent functional group tolerance.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalChinese Journal of Catalysis·DateApr 7, 2022

Research team from Goethe University discovers Achilles’ heel of dangerous hospital pathogen

A team from Goethe University has identified the spatial structure of the mannitol-synthesizing enzyme MtlD in Acinetobacter baumannii, which is crucial for its survival. This discovery could lead to the development of customized substances to inhibit the enzyme and combat this hospital pathogen.

SourceGoethe University Frankfurt·JournalProceedings of the National Academy of Sciences·TypeExperimental study·DateApr 6, 2022

The platinum riddle

Researchers have solved a long-standing puzzle in surface physics, explaining how individual atoms of a catalyst capture molecules to transform them. The breakthrough reveals that both the catalyst and its anchor material assume energetically unfavorable states for a short time to facilitate the reaction.

SourceVienna University of Technology·JournalScience Advances·TypeExperimental study·DateApr 4, 2022

New strategy enables successive cleavage and functionalization of C–C bonds in alcohols

Researchers developed a novel protocol for the direct synthesis of amides via heterogeneous manganese oxide catalyzed successive cleavage and amidation of C-C bonds in alcohols. The method features good functional-group tolerance, cost-effective and recyclable catalyst, and broad substrate scope.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalChem·TypeCommentary/editorial·DateApr 1, 2022

Cheap, eco-friendly catalyst opens new possibilities for organic molecules built from pyruvate

Researchers develop an eco-friendly organic catalyst system that improves the production of organic molecules from pyruvate, a key biomolecule in metabolic pathways. The catalyst promotes reactions where pyruvate donates electrons to produce molecules like amino acids.

SourceOkinawa Institute of Science and Technology (OIST) Graduate University·JournalOrganic Letters·TypeExperimental study·DateMar 24, 2022

Thomas Senftle wins NSF CAREER Award

Engineer Thomas Senftle at Rice University has won a prestigious NSF CAREER Award to improve catalysts through machine learning. He will develop open-source models to speed up the development of catalysts with optimized particle/support combinations, aiming to reduce unwanted molecules in water.

How a particular protein regulates up to two-thirds of the world’s methane emission: key mechanism for methane emission in anaerobic environments is now understood, potentially helping the fight against climate change.

Researchers have deciphered the activity of B12-dependent radical SAM enzymes, which regulate methane production by archaea. The study's findings have implications for biotechnologies that control key enzymatic events and could help reduce global warming.

SourceNagoya University·JournalNature·TypeImaging analysis·DateMar 17, 2022

A fresh perspective on Picket-Spengler reaction with α-ketoesters as a new carbonyl source

Researchers from Nagoya Institute of Technology have successfully demonstrated the first enantioselective Pictet-Spengler reaction of acyclic α-ketoesters with tryptamines, achieving high yields and enantioselectivity. The study expands the scope of the process, which could accelerate drug development.

SourceNagoya Institute of Technology·JournalOrganic Letters·TypeExperimental study·DateMar 16, 2022

KANPHOS: Newly developed database for kinase-associated protein phosphorylation eases neural signaling research

The newly developed KANPHOS database provides comprehensive information on kinase-associated protein phosphorylation, facilitating research into neural signaling pathways. The database contains information on phosphoproteins, phosphorylation sites, and participant kinases, allowing for searches based on various parameters.

SourceFujita Health University·JournalCells·TypeExperimental study·DateMar 16, 2022

Catalyst for a greener future

Researchers at the University of Delaware have developed a novel catalytic technology that converts non-edible plants into renewable fuels, chemicals and plastics. By pulsing hydrogen gas on and off, they increase the population of active sites on catalysts, allowing reactions to occur up to 10 times faster.

SourceUniversity of Delaware·JournalNature Catalysis·TypeExperimental study·DateMar 16, 2022

Chemical reaction design goes virtual

A new virtual ligand-assisted screening method enables efficient searching of ligands for optimal catalysis, accelerating reaction design. By simplifying ligand description with two metrics, researchers identify promising ligands and focus on real testing.

SourceHokkaido University·JournalACS Catalysis·TypeComputational simulation/modeling·DateMar 13, 2022

Study led by Wu Kai and Zhou Xiong published in Science to visualize on-surface ethylene polymerization

Researchers visualize ethylene polymerization on ordered iron carbide surface using in situ technology, revealing molecular insertion mechanism and chain initiation process. The study clarifies the scientific debate regarding chain initiation over Phillips catalysts and provides a method for controlling product chain length distribution.

SourcePeking University·JournalScience·DateMar 10, 2022

New research from Pusan National University sheds light on nature of friction in multi-layered graphene

A study by researchers at Pusan National University has investigated the relationship between surface structures and nanoscale friction in multi-layered CVD graphene. They found that only the top-most layer of graphene was twisted with respect to the rest, affecting layer-dependent nanoscale friction.

SourcePusan National University·JournalApplied Surface Science·TypeExperimental study·DateMar 9, 2022

Upcycling biomass waste into Fe single atom catalysts for pollutant control

Researchers have developed a sustainable methodology to utilize biomass waste for efficient remediation of antibiotic pollution. Fe-contaminated biomass waste ferns are used to synthesize highly active single atom catalysts, demonstrating an appealing strategy for pollutant control and other applications.

Novel enzyme catalyzing the formation of glycosidic bonds in complex sugar moieties characterized

Researchers have identified a novel enzyme that catalyzes the formation of glycosidic bonds in complex sugar moieties. The discovery provides fresh insights into carbohydrate metabolism and offers a breakthrough for the synthesis of sugar chains, which play key roles in various biological processes.

SourceTokyo University of Science·JournalJournal of Biological Chemistry·TypeExperimental study·DateMar 7, 2022

Breaking down how “single-atom” catalysts help remove organic pollutants

Researchers at Tokyo Metropolitan University developed a simple synthesis method for iron-based single-atom catalysts that activate peroxymonosulfate to break down difficult-to-degrade pollutants. The team discovered two distinct chemical pathways involving 'high-spin' state iron sites, which interact with peroxymonosulfate to create r...

SourceTokyo Metropolitan University·JournalEnvironmental Science & Technology·DateMar 5, 2022

Princeton Chemistry reports method for direct “uphill” isomerization of numerous olefin classes

Researchers at Princeton University have developed a method to generate less-stable olefins from internal olefins catalytically, utilizing photocatalysis and chromium co-catalysis. This innovation allows for the conversion of internal olefins into terminal olefins, which are useful starting points in various chemical processes.

SourcePrinceton University·JournalJournal of the American Chemical Society·TypeExperimental study·DateFeb 23, 2022

Metal mix and match: An unexpected discovery could improve the crystallinity of coordination nanosheets

Researchers at Tokyo University of Science have discovered a method to improve the crystallinity of coordination nanosheets by mixing two metal ion solutions. This approach results in higher crystallinity and improved performance in devices such as electronics and batteries. The findings open a new pathway for tuning the functional pro...

SourceTokyo University of Science·JournalAdvanced Materials·TypeExperimental study·DateFeb 21, 2022

Researchers realize photo-induced catalytic C-H heteroarylation of metallocenes

A team of scientists has successfully developed a photo-induced catalytic C-H heteroarylation method for ferrocenes and ruthenocenes, allowing for the creation of new pyridyl and pridonyl metallocenes. This protocol offers mild and concise conditions for functionalization, with significant implications for material science and catalysis.

SourceDalian Institute of Chemical Physics, Chinese Academy Sciences·JournalCell Reports Physical Science·DateFeb 16, 2022