Articles tagged with Catalysis
Researchers from Dalian Institute of Chemical Physics designed a chainmail catalysis system for CO oxidation, achieving near 100% conversion at room temperature. The graphene-isolated Pt catalyst overcomes the issue of deep oxidation and enables efficient CO conversion.
Researchers develop a multifunctional supramolecular catalysis protocol using open-cage solutions to achieve diverse cage-confined catalysis. The protocol enables selective mass transfer, C-H activation, and anionic intermediate stabilization, promoting acid/base-catalyzed cascade reactions.
Researchers review strategies to enhance Cu-based catalysts' performance in CO2 reduction, including surface structure tuning and local environment regulation. The study aims to overcome current challenges and outline future opportunities for efficient CO2 conversion.
Researchers linked microscopic and macroscopic approaches to describe a technologically important chemical reaction under realistic conditions. This allows understanding why catalyst particle size plays a crucial role in chemical processes.
University of Rochester researchers have developed a novel three-component cross-coupling reaction using iron catalysts, which could potentially bring iron to the front of the class. The reaction enables faster and less expensive synthesis of previously difficult-to-make drug-like compounds in a single step.
The researchers developed a catalyst that achieves high selectivity and stability in the reduction of CO2 to formic acid. The catalyst, containing indium sulfide and zinc, demonstrates excellent catalytic stability even at industrial current density for extended periods.
Researchers at IOCB Prague have created a glowing DNA enzyme called Supernova, which catalyzes a chemiluminescent reaction. This breakthrough uses artificial evolution to identify light-producing deoxyribozymes in a vast library of DNA molecules, opening up new possibilities for point-of-care assays and high-throughput screens.
Researchers at USTC have successfully synthesized small-sized Pt intermetallic nanoparticle catalysts with ultralow Pt loading and high mass activity. These catalysts exhibited excellent electrocatalytic performance for oxygen reduction reaction in proton-exchange membrane fuel cells, potentially decreasing the cost of fuel cells.
Researchers developed a new mechanism of adsorption called mechanisorption, which can store significant amounts of energy by recruiting molecules onto surfaces at high concentrations. This breakthrough has implications for energy storage, controlled release, and environmental remediation.
Researchers at Berkeley Lab have successfully engineered microbes to produce novel chemicals and developed a new technique for studying enzyme reactions in real-time. This breakthrough could lead to the production of sustainable fuels, pharmaceuticals, and renewable plastics.
Researchers developed an electrochemical strategy for hydrogenation of N-heterocycles over a bifunctional MoNi4 electrode, achieving high Faradaic efficiency and selectivity. The method uses water as a hydrogen source, avoiding flammable gases and toxic substances.
Researchers discovered that nickel can catalyze the cross-coupling of aryl ethers through a nickelate anion. This reaction pathway relies on the formation and stability of the catalyst, providing an alternative to traditional palladium-catalyzed cross-couplings.
Researchers developed a new catalyst with unique atomic-sized rafts that improve the cleaning of emissions from natural gas engines. The catalyst enhances energy efficiency and reduces unburnt methane emissions, making natural gas-powered technology cleaner and more viable.
Researchers have developed bimetallic catalysts that enhance oil upgrading, decreasing heavy hydrocarbons and increasing light hydrocarbons. The test results showed positive influence on petroleum quality, transportation efficiency, and environmental impact.
Researchers at Arizona State University explore alternative approaches to catalysis, a chemical process crucial for industrial applications. The study aims to develop synthetic catalysts that can improve on nature's designs, leading to the production of carbon-neutral fuels.
Researchers developed a predictive tool using %V bur (min) to categorize phosphine structures as active or inactive in many experimental datasets. This advancement will facilitate organometallic chemistry and catalysis, enabling easier computation and prediction of phosphine reactivity.
Rice chemist Julian West and graduate student Yen-Chu Lu discovered manganese as a more efficient catalyst for synthesizing fluoroketones, precursor molecules for drugs. The use of manganese reduces material costs and simplifies purification.
Using advanced microscopy techniques, researchers recorded the breaking of a single chemical bond between a carbon atom and an iron atom on different molecules. The team measured the mechanical forces applied at the moment of breakage, revealing insights into the nature of these bonds and their implications for catalysis.
Researchers at RMIT University have developed a clean and cost-effective way to upcycle used plastic into high-value products such as carbon nanotubes and clean liquid fuel. The two-step process converts organic waste into charcoal, which is then used as a catalyst to upcycle the plastic.
Dalian Institute of Chemical Physics researchers propose dual active site strategy to isolate dehydrogenation and oxidation in oxidative dehydrogenation of ethane, resulting in near 100% ethene selectivity. This approach could be extended to multiple oxidation reactions plagued by over-oxidation.
Researchers at the University of Illinois discovered that tiny porous crystals called zeolites can speed up chemical reactions by changing the shape of water molecules. This approach could lead to more sustainable and environmentally friendly industrial processes.
A research group synthesized a Pb-alloyed Cu catalyst, showing high activity for electrochemical CO2 reduction with selectivity to formate. The study reveals a multi-path mechanism for CO2 reduction through COOH* and HCOO* intermediates.
Researchers have discovered a three-part catalyst configuration that transforms CO2 into ethanol through a well-tuned interplay between cesium, copper, and zinc oxide sites. The study provides a fundamental understanding of the reaction mechanism and will drive further research towards developing practical industrial catalysts.
A new methodology, EMARS, was developed to directly identify the activity origin of Pt/Al2O3 industrial reforming catalyst by analyzing over 18,000 Pt atoms. The study found that density of supported Pt1 single atoms and Pt-Pt distance larger than 0.38 nm are correlated with aromatic production activity.
Researchers develop a novel method to convert nitrate in wastewater into ammonia with nearly 100% efficiency and zero greenhouse gas emissions. The system utilizes cobalt catalysts and solar power to achieve unprecedented solar-to-fuel efficiency, outperforming existing technologies.
Researchers synthesized a uniform Cu-N-C single-atom catalyst that exhibits comparable alkaline ORR activity to Pt/C. The active site structure undergoes dynamic changes during the reaction, transforming into HO-Cu-N2 under reaction conditions.
Researchers have successfully produced iron-based Metal Organic Framework (MOF) materials directly using renewable electricity at room temperature, overcoming challenges in scalability and environmental friendliness. The new method is 96% efficient and enables the creation of advanced MOF sensors.
Researchers have discovered a way to use mining waste as part of a potential cheaper catalyst for hydrogen fuel production. The new catalyst triggers water splitting reactions using aluminosilicate minerals found in mining waste, which could lead to lower production costs and increased efficiency.
Researchers at RMIT University developed highly versatile, cost-effective 3D printed catalysts that could tackle the challenge of overheating in hypersonic aircraft. The new catalysts show promise for fuelling the future of hypersonic flight by simultaneously cooling the system.
Researchers developed an earth-abundant Zr-H catalyst for selective hydroboration of primary, secondary, and tertiary amides. The reaction pathway involves unusual C-N bond cleavage-reforming followed by C-O bond cleavage, enabling efficient amine synthesis.
Researchers at Arizona State University have developed a synthetic diiron-containing porphyrin that can efficiently catalyze the conversion of radiant energy from the sun into chemical energy. This breakthrough has potential applications in creating non-fossil-based fuels and electrochemical cells for renewable energy storage.
Researchers from India and Saudi Arabia have combined oxidation and photocatalysis to create a heterogeneous photo-Fenton system that degrades phenols at higher rates than individual approaches. The system is highly photostable and reusable, making it promising for practical applications in wastewater purification.
Researchers develop efficient Ni-Co alloy nanoparticle catalysts for HDO reactions, achieving 100% selectivity and conversion efficiency. The synergistic effect of alloyed nanoparticles enhances deoxygenation activity and selectivity.
Researchers design a new strategy for producing pentanoic biofuels by synthesizing Ru metal nanoclusters confined within zeolite Y. This approach boosts chemoselectivity and promotes catalytic activity. The findings extend the notion of 'the closer, the better' into biomass catalysis.
Researchers from Vienna University of Technology have developed a new method to anchor single atoms on surfaces, paving the way for single-atom catalysis. The technique uses silicon atoms as anchors for single metal atoms, which can be used to accelerate chemical reactions.
Scientists created a new approach to anchoring individual iridium atoms on the surface of a catalytic particle, increasing its efficiency in splitting water molecules to record levels. This breakthrough could ease the bottleneck for sustainable energy production by enabling more efficient electrolysis.
A new catalyst developed by Tokyo Tech researchers can generate hydrogen gas from ammonia at lower operating temperatures than existing methods. The calcium imide-supported Ni-catalyst produces good ammonia conversion and offers a promising solution for the production of clean hydrogen fuel.
Researchers at Pusan National University have developed a novel electrocatalyst that can effectively produce hydrogen and oxygen from water at low cost. The catalyst, composed of transition metal phosphates, achieves high surface area and fast charge transfer, making it suitable for commercial on-site production of hydrogen.
A study reveals the biological process used by Xanthomonas to weaken plants' defense systems and discovers a novel class of enzymes called CE20 that can assist infection. This discovery contributes to developing strategies to combat citrus canker and obtaining advanced sugars from agroindustrial waste.
Researchers developed highly-efficient chainmail catalysts for decoupled water electrolysis, producing hydrogen with low energy consumption. The device reduced the potential of hydrogen production by 1.24V, saving 60.2% energy compared to direct electrolysis.
Researchers from University of Science and Technology of China have quantified the critical particle distance to inhibit metal sintering in catalysts. The study found that adjusting particle spacing can significantly impact sintering, with PMC dominant at short distances and OR dominant at long distances.
A team of researchers has developed a method to produce nylon 6-6 without using the environmentally endangered element zinc. They achieved this by using alternative metals such as iron and cobalt, and harnessing the power of solar energy. The new process reduces energy consumption, saves water, and minimizes hazardous chemicals.
A novel method for imaging vibrations and movements of atoms in catalysts has been developed by a collaboration of internationally leading researchers. The new analytical method reveals a dynamic behavior of the atoms, contrary to the long-held expectation that atoms in nanoparticles are static during observations.
Researchers at Nanyang Technological University (NTU) Singapore have devised a new method for producing urea, a key compound in fertilisers, through electrocatalysis. This approach produces urea five times more efficiently than previous methods and has the potential to contribute to sustainable agricultural practices.
Researchers at the University of Bristol used molecular computer simulations to understand how laboratory evolution transforms inefficient designer biocatalysts into highly active enzymes. They found that evolution 'tunes' the flexibility of the whole protein, allowing it to accelerate chemical reactions.
Researchers from the University of Nottingham have developed a novel catalyst that combines homogeneous and heterogeneous features, defying traditional categorization. The discovery holds promise for increasing the active surface area available for catalysis, leading to more efficient and sustainable production of molecules.
A research team at POSTECH has developed a biocompatible nanomotor that mimics life's autonomous motility using glucose as fuel. The nanomotors exhibit directional propulsion, overcoming Brownian motion, and show potential for intracellular targeted drug delivery and precise cell manipulation.
Scientists have developed a method to synthesize uniform atomically precise Ni2 sites, a crucial step in designing effective dinuclear-site catalysts. Theoretical calculations suggest that these active intermediates play a key role in facilitating CO2 reduction reactions.
Researchers highlight the potential of covalent organic frameworks (COFs) in solar-to-fuel production, converting sunlight into hydrogen and other fuels. COF-based photocatalysts have shown promising properties, including improved catalysis and electron delocalization, making them a viable solution for future energy needs.
Researchers at Tokyo Institute of Technology have developed a high-yield synthesis pathway through reduction of rhodium complexes, enabling the addition of electron-deficient boron groups to arenes. This new strategy uses a cyclopentadienyl-rhodium-based catalyst and produces arylboronates with high yields and cleaner conditions.
Researchers developed direct cellulose fuel cells that directly use cellulose as fuel without reforming processes. The study found that gold is highly active in the cleavage reaction at negative potential and nickel and palladium are active in decomposition reactions at positive potential.
A team of researchers at Tokyo University of Science has developed a stable and highly active photocatalyst from gold nanoclusters. By removing the protective molecules around the nanoclusters, they were able to increase their catalytic activity and stability, opening up new possibilities for hydrogen generation and other applications.
Researchers discovered that certain catalyst materials, such as erythrite, improve in performance over time due to restructuring. This process increases the surface area of the material, allowing for more reactions to occur, resulting in higher oxygen yields and doubled electrical current generation.
Researchers from University of Tsukuba and Osaka University developed a polymer-coated metal catalyst that accelerates CO2 conversion into formate, a useful carbon-based fuel. The PEG-coated Sn catalyst showed a 24 times higher formate production rate than conventional Sn plate electrodes.
The Center for Adapting Flaws into Features will explore chemical defects to optimize material properties, with a focus on creating better catalysts and electronics. The team aims to develop new approaches towards transformative technologies by leveraging advanced microscopy, spectroscopy, and data science.
Researchers at the University of Rochester have developed a new method using pulsed lasers in liquids to create nanoparticles that can be easily tested for use as catalysts. This technique accelerates the process of discovering effective catalysts, which is crucial for producing essential materials and clean fuels.
Researchers at Oak Ridge National Laboratory are advancing various technologies to minimize oil leaks, enable 3D printing in space, and increase fuel efficiency from ethanol. They have developed a quantum sensing system to detect pipeline leaks more quickly, built a thermal protection shield for a capsule launched into space, and creat...
Researchers at the University of Basel have developed new luminescent manganese complexes with promising properties, including improved efficiency and stability. These findings offer a potential solution for more sustainable energy production and could lead to the creation of water-soluble variants for medical applications.
A team of Lehigh University researchers is studying a promising alternative catalytic process based on solid acid catalysts for ethylene dimerization. Using in situ and operando molecular spectroscopy, they aim to understand the surface structures of the catalyst and design more active catalysts with reduced environmental impact.
A team of researchers has successfully synthesized polycarbonate diols from carbon dioxide and diol at atmospheric pressure using a CeO2 catalyst. This process eliminates the need for dehydrating agents, producing only water as a by-product, making it an attractive alternative to existing methods.