Articles tagged with Catalysis
Researchers at Osaka University have elucidated the activation mechanism of nanoporous gold catalysts, making poisonous CO gas harmless. The study used atomic-scale resolution environmental transmission electron microscopy and computer simulations to reveal the role of residual impurities in catalyzing chemical reactions.
A new study shows that combining machine learning and quantum chemistry can help chemical engineers at Rice University and Penn State find fundamental correlations in large amounts of data. This allows them to narrow down their search and design more efficient catalysts, which can translate into millions of dollars for companies.
A new hybrid catalyst made of iron and dinickel phosphides on commercially available nickel foam can produce both hydrogen and oxygen from water, reducing energy requirements and costs. This breakthrough could lead to a significant increase in the production of clean energy from hydrogen.
Researchers have developed a new catalyst that increases the rate of methanol formation by three times over palladium alone and four times over copper alone. The catalyst combines palladium and copper in a precise atomic ratio, creating an ideal surface structure for efficient CO2-to-methanol conversion.
University of Tsukuba researchers developed a method to balance catalyst activity and stability in acidic liquids using graphene coatings. The approach resulted in nanoparticles with high durability and similar catalytic activity to expensive platinum-based catalysts.
Researchers have developed a catalyst that converts CO2 into liquid alcohols like ethanol and propanol, offering a potential solution for renewable transportation fuels. The new catalyst design enhances CO2 reduction by incorporating sulfur atoms and copper vacancies, inspiring more efficient catalysts.
Researchers at ETH Zurich have developed a solid catalyst for a major chemical reaction, reducing waste and increasing efficiency by 20 times compared to traditional soluble catalysts. The new palladium-carbon-nitrogen material is more stable and cost-effective, making it suitable for commercial-scale production.
A team from Osaka University invents a pseudo-rotaxane with unidirectional movement, enabling the observation of simultaneous motion and chemical reactivity. This innovation demonstrates 'face-selective translation,' where α-cyclodextrin interacts with the molecular machine to catalyze a reaction.
Researchers at Princeton University have found a way to make a naturally occurring enzyme take on a new role, enabling the catalysis of non-natural reactions. This breakthrough could lead to the development of new enzymatic reactions and potentially more cost-effective chemical catalysis.
Researchers at Princeton University have found a revolutionary approach using cobalt and methanol to produce an epilepsy drug, replacing toxic rhodium and dichloromethane. The new reaction is faster, cheaper, and more environmentally friendly, offering distinct advantages over traditional methods.
A new study from Duke University's Fuqua School of Business found that how inequity is presented can influence individuals' willingness to rectify it. Participants were more likely to give up part of a bonus when told a specific black colleague was unfairly disadvantaged, rather than being told they had an unfair advantage.
Osaka University researchers have developed a practical and environmentally innocuous method for functionalizing multiply substituted amines. Their reductive alkylation approach uses hydrogen directly, generating only water as a byproduct and efficiently synthesizing a wide variety of amines, including amino acids.
Recent study reveals supports in atomically dispersed catalysts play a significant role in catalysis, not just as ligands. The findings suggest that metal atoms on the support can directly participate in the activation of reactants.
Researchers at Virginia Tech have synthesized a biodegradable alternative to polyolefins using a new catalyst and polyester polymer. This breakthrough could lead to improved physical and chemical properties of the resulting material, making it suitable for various applications.
Scientists have developed a neural network that can recognize features in x-ray absorption spectra sensitive to atomic arrangement at fine scales. This method helps reveal details of atomic-scale rearrangements during iron's phase transition, and could be applied to study nanoparticles, catalytic materials, and other materials.
Researchers have designed a new material that uses self-assembly to create an efficient catalyst for hydrogen fuel cells. The catalyst is made from a combination of cobalt and ruthenium molecules that assemble themselves into the desired structure, allowing for large-scale production at a lower cost than current platinum-based catalysts.
Researchers have discovered a way to harness bismuth's unique property, called catalytic plasticity, to convert carbon dioxide into liquid fuels and industrial chemicals. This approach could potentially provide sustainable routes to making fuels and reduce greenhouse gas emissions.
Scientists create nanoparticles that can change their surface topography under light control, enabling precise control over chemical reactions. This breakthrough allows for more efficient and selective catalysis, with potential applications in multistage reactions and simplified post-reaction processing.
Researchers developed an artificial metalloenzyme that can penetrate a mammalian cell and accelerate hormone release, activating a gene switch to create a fluorescent protein. This breakthrough enables the modification of cell functions on a genetic level or the creation of drugs from harmless precursors.
A new technique doubles the conversion of carbon dioxide to an essential plastic component, ethylene. The approach uses copper coated with polyacrylamide to increase efficiency, offering a promising method for recycling CO2 and reducing greenhouse gas emissions.
Researchers have demonstrated the unique potential of carbon nitrides as hosts for isolated metal atoms, including palladium, in various crystalline forms. The study found that varying the lattice structure significantly impacts the strength of the metal-host interaction, leading to improved catalytic activity and selectivity.
University of Groningen biotechnologists successfully redesigned aspartase enzyme using computational method, producing kilograms of pure building blocks for pharmaceuticals and other bioactive compounds.
A University of Toronto engineering team has designed a most efficient and stable process to convert climate-warming carbon dioxide into ethylene, a key chemical building block for plastics. The breakthrough catalyst uses a thin copper-based material and improves energy efficiency and selectivity.
Researchers at TU Vienna found that support materials can significantly impact chemical reactions on large palladium grains. The discovery could lead to the development of more effective automotive catalytic converters by reinforcing the weak point of the grain, where carbon monoxide poisoning starts.
Scientists have developed a new catalyst that can integrate fluorine atoms into organic molecules, improving pharmaceuticals and medical imaging technology. The catalyst is specifically tuned to perform the same function as biological enzymes but is more widely applicable and has been designed using computational analysis.
Nebraska researchers have identified a simple equation to design less costly and more efficient catalysts for producing renewable hydrogen fuel. The team found that surrounding certain transition metals with specific environments can elevate their performance, making them viable alternatives to precious metals.
Scientists at KAUST have created a 3D porous material with repeating patterns of interconnected pores using a simple method. The film, made from polystyrene-b-poly(tertbutyl acrylate), shows promise for applications such as virus filtration and biological scaffolds.
Scientists investigate vibration energy of a single molecule on a surface, measuring the current generated by applying voltage between a probe tip and the surface. The study uses a classical model to reproduce experimental results, shedding light on interaction between molecules and surfaces.
Scientists at the University of Tsukuba have created an electrode based on 'holey' graphene that efficiently catalyzes the hydrogen evolution reaction in acidic electrolyte, making it cheaper and more effective. The new system outperforms regular non-holey graphene electrodes in acid conditions.
Researchers developed a novel catalyst design by incorporating Pd interlayers into an icosahedral core shell. The Au60Pd40@Pt electrocatalyst showed remarkably enhanced activities and durabilities towards ORR in acid environment compared to commercial Pt/C and Au75Pd25@Pt icosahedra.
Peter Wasserscheid receives second Advanced Investigator Grant from European Research Council to explore fundamental new concept in catalysis based on metal droplets with low melting point. This research has the potential to replace expensive precious metals with cost-effective alternatives.
A team of Russian chemists has developed a new rhodium catalyst for organic synthesis, enabling the creation of complex molecular frameworks of antifungal agents. The catalyst's asymmetrical design allows for full spatial control over reaction outcomes.
Researchers at Oak Ridge National Laboratory have discovered a new type of catalytic reaction that generates ammonia from nitrogen and water using an electric field and nanoscale carbon spikes. The process occurs at room temperature and could lead to more energy-efficient and environmentally friendly methods for fertilizer production.
ORNL researchers developed a method to uniquely identify vehicles using roadside sensors and improved predictive Earth system models for plants' heat wave responses. Computational modeling also aided in filling gaps of olefins breakdown and catalyzation process.
Researchers at Kumamoto University developed a new catalyst that improves NH3 combustibility and suppresses NOx generation. The catalyst allows for the decomposition of NH3 into H2 with low ignition temperature and purification through oxidation.
A new natural gas catalyst aims to reduce methane emissions from vehicle exhaust, a potent greenhouse gas. The US Department of Energy-funded project will develop and optimize a lower-cost, more efficient catalyst to eliminate unreacted methane, making natural gas a cleaner-burning fuel option.
Researchers have developed a new theory to explain why stretching or compressing metal catalysts can make them perform better. The theory suggests that applying a strain to a catalyst's atomic lattice can tune its reactivity, enabling fine-tuning of catalyst performance throughout different reaction steps.
Researchers found that smaller Ru particles increase the TOF of the reaction, while maintaining selectivity towards GVL. The smallest metal particle size (1.2 nm) showed high activity at both room and elevated temperatures.
UCR researchers have developed a cost-effective way to improve the removal of pollutants from wastewater using Advanced Oxidation Processes. By adding a co-catalyst, they can dramatically reduce the amount of hydrogen peroxide and ferrous catalyst needed, preventing the formation of an iron-containing sludge.
Researchers at Swansea University's Energy Safety Research Institute have found a way to convert CO2 into ethylene, the basis of making plastics, at room temperature. This process has the potential to offset global carbon emissions and utilise half a billion tonnes of emitted CO2 annually.
Researchers have developed a hybrid system combining inorganic semiconductor nanocrystals with a molecular catalyst, achieving efficient hydrogen production. The system shows remarkable catalytic activity in water without the use of toxic metals like cadmium.
Researchers developed alternative catalysts made of cheaper and more readily available materials with equally high efficiency. The study found that the structure and composition of iron-nickel sulphide influence its electrocatalytic properties.
Researchers at the University of Notre Dame are developing a renewable energy approach for synthesizing ammonia, which is essential for fertilizers and food production. The new process utilizes plasma in combination with non-noble metal catalysts to generate ammonia at milder conditions than the traditional Haber-Bosch process.
Scientists have developed a method to combine up to eight different metals in a single nanoparticle, creating stable alloys with useful applications in the chemical and energy industries. The new technique uses shock waves to heat and cool the metals, producing homogeneous nanoparticles with broad catalytic properties.
Scientists at the University of Maryland have created nanoparticles composed of up to eight distinct elements, greatly expanding the landscape of nanomaterials. This breakthrough enables a wide range of applications in catalysis, energy storage, and bio/plasmonic imaging.
Researchers develop a heat-shock process to form high entropy alloyed nanoparticles from multiple elements. The resulting nanoparticles exhibit homogeneous crystal structures and potential applications as catalysts in emerging energy technologies.
Researchers at DESY's NanoLab found that nanoparticles with a large number of edges are more efficient in catalytic reactions. The study revealed that the different facets of the nanoparticles become inactive due to growing oxide islands, leaving active sites for the reaction.
The team developed a process to make sequential polymers by switching light on and off, allowing precision control over physical properties. This method simplifies existing synthesis methods and has potential for creating new polymers with desired functionality.
Northwestern University researchers have discovered a new design approach for creating catalysts that can accelerate chemical reactions and processes, including clean energy conversion and storage. The method has the potential to impact various industries such as pharmaceuticals, optical data storage, and petroleum products.
Researchers found that bonds based on antimony yield powerful new catalysts, enabling precise molecular transformations and opening up untried prospects. The discovery puts antimony back into the spotlight, highlighting its exceptional qualities for molecular transformation.
A new study from the University of Bristol and the University of Waikato reveals how enzymes 'choreograph' their atomic movements to work optimally at specific temperatures. This finding provides insights into enzyme structure and function, which can inform the design of better biocatalysts for industrial processes.
The researchers used cryo-electron microscopy to provide a high-resolution view of the NuA4/TIP60 complex. The structure reveals that Tra1/TRRAP serves as a scaffold for NuA4/TIP60 assembly and that human TRRAP mutations are largely centered on interaction surfaces mediating this assembly.
A new biocompatible catalyst selectively oxygenates and degrades amyloid-β peptide under near-infrared light irradiation, reducing its pathogenic properties. The catalyst is applicable for treating peripheral amyloid diseases and Alzheimer's disease.
A new catalyst developed by Georgia Institute of Technology researchers can significantly improve the efficiency of fuel cells by speeding up oxygen processing. This breakthrough could enable the widespread adoption of clean energy technology and reduce costs associated with producing hydrogen fuel, a key ingredient for fuel cells.
Researchers at Ruhr-University Bochum have developed a new catalyst with a self-defense mechanism against oxygen damage, using DuBois-type complexes based on abundant metals. The protection system involves an immobilization matrix that electrically disconnects the catalyst from the electrode surface.
The chemical topology of silica surfaces can significantly impact the effectiveness of various chemical processes, including catalysis, filtration, and nanofabrication. Researchers found that hydrophilic silanol groups attract water molecules, forming a barrier that reactants must overcome to proceed with the desired process.
Researchers at TSRI have developed a new desulfonylative cross-coupling reaction that simplifies the synthesis of drug-like molecules, including alkyl-fluorinated compounds. This method paves the way for creating new types of compounds and facilitating the synthesis of pharmaceuticals.
Scientists at Washington State University and Tufts University have demonstrated that a single metal atom can act as a catalyst in converting carbon monoxide into carbon dioxide. This breakthrough could lead to more efficient and cost-effective catalytic converters, essential for reducing harmful emissions from car exhaust.
A team at Nagoya University developed a metal-free catalyst, tetramethylammonium methyl carbonate (TMC), that expands the substrate range of trans-esterification. TMC reacts with alcohols to form alkoxide ions, which attack esters to produce complex target esters in high yields.
Researchers from the US and China developed a dispersed iridium catalyst with two active metal centers for artificial photosynthesis. The catalyst demonstrates high stability and activity in water oxidation, a crucial process in natural and artificial photosynthesis.