Articles tagged with Catalysis
Researchers create new catalytic approach to prepare compounds essential to drug discovery with high selectivity and 20 times less solvent than alternative methods. The new strategy was used to prepare the anti-cancer agent pacritinib, which is now in advanced clinical trials.
Researchers at MIT have found that some catalysts produce oxygen from within their crystal structure, contrary to previous assumptions. The study's findings could help fine-tune metal-oxide catalysts for enhanced energy storage processes.
The UNC Catalyst initiative aims to create and share research tools to study rare diseases, addressing the lack of resources and expertise in this area. The partnership with Genetic Alliance and Structural Genomics Consortium will provide researchers with access to necessary tools and talent to accelerate solutions.
Researchers at Southern Methodist University have discovered a new catalyst that can efficiently break the tough molecular bond between carbon and hydrogen. This breakthrough could lead to a cleaner, easier, and cheaper way to derive products from petroleum, with copper-based catalysts showing great promise in oxidizing C-H bonds.
Princeton researchers have discovered a method to expand enzyme reactivity through light activation, allowing access to high selectivities. They successfully catalyzed non-natural reactions, including dehalogenation reactions, by irradiating enzymes with light.
Researchers at KAUST have developed a simpler way to assemble silver nanoclusters, opening up new opportunities for catalysis and opto-electronics. The clusters can be modified with atom-by-atom control, allowing their properties to be tailored for specific applications.
Osaka University researchers have developed a catalyst that efficiently produces hydrogen from organosilanes at room temperature without additional energy input. The catalyst, composed of gold nanoparticles supported on hydroxyapatite, demonstrated high turnover frequency and recyclability.
Researchers at ICIQ have designed a new strategy for stereoconvergent preparation of trans-cyclopropanes from E/Z alkene mixtures. The 'radical carbenoid' method uses diiodomethane as a commercially available and easy-to-handle reagent.
Researchers at Rice University have discovered a simple way to recycle waste carbon dioxide into valuable fuel using nitrogen-doped graphene quantum dots. The dots proved nearly as efficient as copper in converting CO2 into small batches of ethylene and ethanol, with the ability to keep their catalytic activity for a long time.
Researchers developed catalysts with tensile surface strain, improving oxygen reduction reaction activity and stability. The nanoplates showed minimal decay in catalytic activity after 50,000 voltage cycles.
Researchers aim to understand how particle shape influences catalytic activity and design more efficient catalysts for CO2 recycling reactions. The goal is to convert climate gas CO2 into valuable chemicals and fuels.
A research team at the University of Geneva has discovered that sulfur can act as an effective catalyst, transforming molecules with greater precision than hydrogen. This breakthrough enables chemists to exercise increased control over molecular transformations, paving the way for the creation of new materials and applications.
Researchers found that the position of a molecule on a catalytic surface determines the rate of bond breaking. They observed a 100-fold difference in reactivity between bonds aligned along rows and across rows of copper atoms. The discovery could lead to more selective and efficient catalysts.
Researchers used 3D imaging to study nanoscale details of nickel-cobalt particles, revealing a unique 'Swiss cheese' structure that increases surface area and reactivity. The findings could lead to more efficient and cost-effective catalysts for fuel cells.
A new catalyst developed by researchers at the University of Pittsburgh has the potential to solve two problems at once - reducing net carbon dioxide emissions while generating cleaner fuels. The catalyst, which converts CO2 into methanol, could dramatically reduce the cost of carbon capture and conversion.
Researchers have developed a catalyst that flexibly molds reaction product handedness, ensuring correct enantiomeric form. The system's self-amplifying action enhances stereoselectivity with each cycle, holding promise for biologically active compounds and new insights into biological systems.
Researchers at Waseda University have developed a new method for producing hydrogen, achieving temperatures as low as 150~200°C. This innovation reduces energy input and extends catalyst life, making it suitable for widespread use in fuel cell systems.
Researchers at Caltech use directed evolution to persuade bacteria to create silicon-carbon bonds, which are found in pharmaceuticals, agricultural chemicals, and computer screens. The new process has the potential to be more environmentally friendly and less expensive than current methods.
Researchers successfully created a catalyst that efficiently forms carbon-silicon bonds, which were previously thought impossible. The breakthrough enables the production of a wide range of silicon products.
Researchers at Stanford University have developed a new technique to fine-tune metal catalysts at the atomic scale, leading to a significant boost in performance for platinum catalysts used in fuel cells. By compressing or separating atoms by just 0.01 nanometers, they found that platinum's catalytic activity nearly doubled.
Researchers used a combination of measurements to gather detailed information on problematic carbon-based deposits in catalysts, known as coke. They found that uneven distribution of aluminum in zeolite catalysts caused coke buildup, which blocks chemical reactions vital to fuel production and other processes.
A team of organic chemists developed a new reaction to directly install amines into carbonyl compounds, resulting in the rapid formation of optically active α-aminocarbonyls. This method enables access to chiral α-aminocarbonyls from readily available carbonyl compounds and hydroxylamines.
Massive simulations reveal intrinsic disorder and dynamic surface rearrangements in certain polar surfaces, affecting mechanical, catalytic and sensor properties.
Researchers at Ulsan National Institute of Science and Technology (UNIST) have created a new delafossite-based catalyst that converts CO2 into liquid hydrocarbon-based fuels, including diesel. This breakthrough process removes harmful CO2 from the atmosphere and offers a potential solution to reduce greenhouse gas emissions.
A novel Fe-N/C catalyst with a silica-protective-layer approach has shown high oxygen reduction reaction activity comparable to platinum-based catalysts. The research paves the way for the commercialization of hydrogen fuel cells, potentially reducing costs and increasing efficiency.
Researchers have developed a biocompatible heterogeneous copper catalyst that can assemble building blocks in a living system, enabling the creation of anti-tumor drugs. The catalyst was tested in biological systems and found to be effective in stopping cell growth and initiating programmed cell death.
Dr. Wachs' research aims to identify fundamental structure-activity/selectivity relationships for catalysts, guiding the design of advanced catalysts. His team explores direct conversion of natural gas into liquid fuels without oxidizing reagents, offering a promising solution to overcome stranded gas.
Researchers at Berkeley Lab integrated a water-splitting catalyst onto semiconductor to create more stable and efficient artificial photosystems. The composite film successfully supported chemical reactions without damaging sensitive semiconductors, achieving a three-day run time.
Researchers at Kazan Federal University have achieved a significant breakthrough in in-situ combustion, increasing the combustion front speed by 10 times. The team has also developed a new understanding of catalysts' work mechanisms, making them more stable and efficient.
The US Department of Energy's Brookhaven National Laboratory has received three 2016 R&D 100 Awards for its innovative technologies in microscopy, catalysis, and nanomaterials. The lab's custom-built x-ray microscope has advanced imaging capabilities, while the MoSoy Catalyst produces hydrogen in an environmentally friendly way.
Researchers observed a significant increase in photocatalysis rates after recycling catalysts, with rates up to 1.7 times higher in the second cycle and 3.1 times higher in the third cycle.
Researchers at Washington State University have developed a new catalyst that efficiently produces hydrogen from water, a crucial step in making renewable energy production and storage viable. The catalyst, made from low-cost materials, outperforms precious metal-based catalysts used today.
Researchers at Goethe University Frankfurt have developed a new non-metal catalyst that can split the hydrogen molecule under mild conditions. The process requires only an electron source and has potential applications in energy production, chemical synthesis, and the semiconductor industry.
A new discovery by scientists at the universities of Oxford, Cambridge and Cardiff has shown that hydrocarbon wax rapidly releases large amounts of hydrogen when activated with catalysts and microwaves. This breakthrough could pave the way for widespread adoption of hydrogen-fuelled cars.
Researchers have developed a highly active and stable catalyst for ammonia synthesis under low reaction temperatures. The flat-shaped Ru nanoparticles anchored on Ca(NH2)2 exhibit high catalytic performance and long-term stability.
Researchers at Toyohashi University of Technology developed a novel synthetic method to create chiral polymers containing cinchona sulfonamide repeating units. These polymers showed high catalytic activity in asymmetric reactions, enabling the enantioselective desymmetrization of cyclic anhydrides.
A team of chemists has developed a process to identify new catalysts for synthesizing drugs more efficiently and cheaply. By examining libraries of drugs, they found highly effective ligands that can improve reactions beyond those reported nearly four years ago.
Researchers at ORNL developed a nanoscale catalyst that converts carbon dioxide directly into ethanol with high selectivity. The process uses low-cost materials and operates at room temperature in water, making it suitable for industrially relevant applications.
Researchers develop new microwave-assisted thermolysis method to produce highly crystalline g-C(3)N(3) catalysts with remarkably few defects. This results in improved photocatalytic activity for hydrogen generation from sunlight.
A new method for creating industrial chemicals has been developed by researchers at Washington State University, potentially lowering production costs and energy requirements. The Fischer-Tropsch process is used to produce alcohols and aldehydes, which can be used as fuel additives and feedstock for various industries.
A new study developed a mixed metal catalyst that enables both charge and discharge reactions in lithium-air batteries, overcoming key barriers to their development. This breakthrough offers opportunities for future research and potential applications in sustainable energy storage.
A team of researchers from the University of Houston has reported a more efficient catalyst for producing hydrogen gas by splitting water. The new hybrid catalyst requires significantly less energy than existing methods, making it a promising alternative to traditional platinum-based catalysts.
Nanocatalysts display significant catalytic capability due to increased surface area and multiple catalytic centers. They play a crucial role in enhancing yield and TON in specific chemical products, including chemo-selective and coupling reactions.
Researchers have created a new, degradable synthetic rubber that can be easily recycled and reused in tires and other products. The material, made from cyclopentene, is produced using low-energy conditions and can recover 100% of its starting material.
A critical review article discusses the issues and prospects of photocatalytic reduction of carbon dioxide, highlighting the lack of a standard procedure as a major bottleneck. Recent advances in this field are also detailed, providing insights into the ongoing research.
Physicists watched a silver catalyst at work using an atomic force microscope, calculating energy turnover and optimizing catalysis. The Ullmann reaction was observed at atomic resolution, revealing unusual spatial arrangements of intermediate products.
Researchers used advanced computational methods to demystify complex catalytic chemistry in fuel cells, bringing cost-effective alternatives closer to reality. The study reveals that water plays a huge role in dictating which hydrogen atom breaks free from methanol first.
Researchers at Vanderbilt University have developed a new nanofiber mat technology that increases fuel cell power output by 30 percent while reducing costs and improving durability. The technology is part of a $13 million DOE program to advance fuel cell performance and hydrogen storage technologies.
Scientists at Argonne National Laboratory have discovered a self-healing diamond-like carbon film generated by an automotive engine's heat and pressure. The tribofilm reduces friction by 25-40% and wear to unmeasurable values, enabling more efficient and reliable engines.
Researchers at UWM create a solid chiral catalyst that preferentially forms one enantiomer of a molecule, addressing the issue of inconsistent handedness in pharmaceuticals. This breakthrough could lead to safer and more effective medications.
Research by Stefano Fabris and colleagues reveals that moisture boosts the efficiency of a catalyst in fuel cells by creating a 'proton pinball game' that facilitates molecular transport. This breakthrough could lead to more efficient fuel cell designs.
Researchers have developed iron catalysts that can diversify chiral amino acids into 21 different structures while preserving their handedness. This technology allows for the creation of modified peptides or entirely new structures, expanding the pool of unnatural chiral amino acids available to researchers.
Researchers at the University of Illinois Chicago have developed a solar cell that captures CO2 and sunlight to produce hydrocarbon fuel. The 'artificial leaf' technology solves two crucial problems simultaneously by converting atmospheric carbon dioxide into fuel, making it a game-changer for energy production.
Researchers have found a new, sustainable catalyst for hydrogen production in the form of pentlandite, a mineral composed of iron, nickel, and sulfur. The study shows that artificial pentlandite produces hydrogen more efficiently than naturally occurring variants, with stable performance and a high active surface area.
The IBS team successfully detected hot electrons in a liquid interface, expanding the possibilities for catalytic reactions. This breakthrough may lead to highly efficient devices for applications such as fuel cells and artificial photosynthesis.
Scientists at the University of Bath will monitor chemical reactions in real-time with a new £1.3 million facility. This allows researchers to develop more efficient catalysts for producing hydrogen fuel and synthesizing paracetamol from waste citrus fruit.
Researchers have developed a unique approach to trapping platinum atoms, reducing the need for expensive platinum in chemical reactions. The new method uses cerium oxide to create nano-scale traps that keep platinum atoms stable, improving catalyst efficiency and performance.
Two researchers have discovered a single-step chemical process that creates both alcohols and esters without generating any waste or using harmful reagents. The process is more straightforward and simpler than existing methods, offering an economical and sustainable alternative for industrial applications.
A team of researchers at Nagoya Institute of Technology has developed a method to synthesize complex, versatile materials from starting materials with low reactivity. The synthesis uses the catalytic Mannich reaction to produce chiral imidazolines with high yield and stereoselectivity.
Researchers have discovered a highly selective catalyst that converts carbon dioxide into ethylene, producing more ethylene and fewer unwanted side products. The catalyst, made from plasma-treated copper, offers new possibilities for designing nanoscale catalysts with specific activity and selectivity.