Articles tagged with Catalysis
A new method enhances electrochemical surface area in calcium-doped perovskite, La0.6Ca0.4MnO3, overcoming common bottlenecks in hydrogen fuel cell applications. The activated material demonstrates superior oxygen reduction reaction performance.
Scientists have developed a method to convert waste carbon dioxide into formic acid, a colorless and pungent liquid with potential as a transportation fuel and petrochemical industry enhancer. The new method efficiently converted CO2 for over 5,000 hours, suggesting cost-effective scalability.
A team of researchers at McMaster University uncovered the elusive bottleneck hindering the conversion of carbon dioxide into fuels and chemicals. The study provides new insights into the degradation process of catalysts, enabling the development of strategies to improve their operational lifetimes.
Researchers at the University of Tokyo discovered a way to improve gold catalysts' durability by creating a protective layer of metal oxide clusters. The enhanced gold catalysts can withstand a greater range of physical environments, increasing their range of possible applications and reducing energy consumption.
A new process for degrading fluoroarenes was developed, combining photolysis defluorination with •OH-initiated oxidation processes. The results showed efficient degradation of FAs under mild conditions, achieving high defluorination and TOC removal rates over 99.9%.
A new bifunctional water electrolysis catalyst made from ruthenium, silicon, and tungsten enables the efficient production of high-purity green hydrogen. The catalyst demonstrates exceptional durability in acidic environments, making it an attractive alternative to traditional precious metal catalysts.
Researchers at Chung-Ang University have developed a low-cost catalyst for green hydrogen production through proton exchange membrane water electrolysis. The new catalyst, SA Zn-RuO2, has improved stability and reactivity compared to commercial RuO2, with reduced energy consumption and increased durability.
Researchers from Osaka University have developed an operationally simple way to synthesize the intricate beta-lactam scaffold characteristic of beta-lactam antibiotics. The new catalytic system generates Fischer-carbene complexes in small quantities, eliminating toxic chromium waste and requiring only a small amount of catalyst.
Researchers identified key enzymes for protoberberine production, revealing a collaborative network of modifying enzymes that give rise to diverse compounds. The study sheds light on the biosynthetic mechanism and potential applications in targeted synthesis.
Researchers have developed a new catalyst that exceeds 30% yield for the production of ethylene through oxidative coupling of methane, a more sustainable and economically viable method. The core-shell Li2CO3-coated mixed rare earth oxides catalyst enables sequential oxygen switching, replenishing its ability to provide oxygen for the r...
A new catalyst developed by researchers at Nagoya University successfully synthesized a key intermediate for the incontinence drug oxybutynin in 5-30 minutes, significantly faster than existing methods. The discovery represents a major advance in chiral drug synthesis and holds great promise for future drug discovery efforts.
Scientists at Brookhaven National Laboratory and Columbia University developed a tandem electrocatalytic-thermocatalytic conversion method to convert CO2 into carbon nanofibers. This approach can occur at relatively low temperatures, around 400°C, making it a more practical and industrially achievable process.
Researchers at Stockholm University have successfully studied the surface of iron and ruthenium catalysts during ammonia production, shedding light on the reaction mechanism. The findings open up possibilities for developing more efficient materials, which could contribute to a green transition in the chemical industry.
Researchers from City University of Hong Kong developed a novel strategy to engineer stable and efficient ultrathin nanosheet catalysts using Turing structures. This approach effectively resolves the instability problem associated with low-dimensional materials in catalytic systems, enabling efficient and long-lasting hydrogen production.
Researchers at UChicago find a way to use electricity to boost chemical reactions, improving yields and enabling sustainable synthesis. The study uses electrochemistry to control molecular interactions, offering a unique design lever for greener chemistry.
Researchers developed a highly active, selective, and durable copper nanoparticle catalyst for converting CO2 into dimethyl ether. The hydrophobic catalyst surface efficiently hinders the sintering of Cu nanoparticles, maintaining performance over 100 hours.
A team of scientists from Ruhr-University Bochum and the Fraunhofer Institute has developed a novel catalyst system for converting carbon dioxide into raw materials. The system, which uses homogeneous electrocatalysts, can efficiently convert CO2 under industrial conditions and maintains stability over 100 hours without decay.
A new NSF-supported collaboration aims to improve liquid organic hydrogen carriers and use AI to identify novel approaches for a global renewable energy supply chain. The team is developing a new class of molecules, chemistries, and chemical processes to better store and transport green energy across the globe.
A new 'one-pot' method for producing palladium nanosheets could significantly improve the efficiency of clean energy production. This breakthrough enables the use of less rare metals, reducing environmental impact.
Researchers developed a high-efficiency mercury removal photocatalyst by constructing a Z-scheme heterojunction of g-C3N5 and Bi5O7I. The unique structure enhances the separation and migration of electrons and holes, improving photocatalytic activity.
Researchers developed a gradient F-doping hydroxyapatite core-shell structure with flexoelectricity and piezoelectricity, exhibiting enhanced degradation of phenanthrene in soil. The catalyst showed optimized piezocatalytic activity, outperforming pristine HAP and F-HAP.
Recent advances in built-in electric-field-assisted photocatalytic dry reforming of methane focus on enhancing charge transfer dynamics and reducing greenhouse gases. The review article introduces fundamental reaction mechanisms, advantages, and potential photocatalytic materials for dry reforming application.
A team of researchers developed a hexagonal BaTiO3−xNy oxynitride catalyst with basicity comparable to that of superbases. The substitution of nitride ions and oxygen vacancies into face-sharing Ti2O9 dimer sites increases the electron density, resulting in a highly basic catalyst.
A new catalyst developed by Northwestern University chemists can break down Nylon-6, a common plastic found in fishing nets, carpet, and clothing, in just minutes. The process does not generate harmful byproducts and is practical for everyday applications.
Researchers developed a novel laser-induced hydrothermal reaction method to grow binary metal oxide nanostructures and layered-double hydroxides on nickel foams. This technique improves the production rate by over 19 times while consuming only 27.78% of the total energy required by conventional methods.
Researchers have successfully observed the operating principle of promoters in a catalytic reaction in real-time. Using high-tech microscopy methods, they visualized individual La atoms' role in hydrogen oxidation. The study revealed that two surface areas of the catalyst act as pacemakers, controlled by promoter lanthanum.
The American Heart Association's National Hispanic Latino Cardiovascular Collaborative aims to bridge the gap in healthcare disparities affecting underrepresented groups. By empowering Hispanic Latino leaders, the program seeks to eliminate health inequities and improve overall well-being.
Researchers from GIST have developed a new electrode using Schottky junctions to overcome the conductance limit of active catalysts, achieving high-performance water splitting and hydrogen evolution reactions. The electrode demonstrated remarkable current density and durability during continuous operation for 10 days.
An international team at DTU has increased the durability of CO2 electrolyzers, enabling the conversion of captured CO2 into valuable green chemicals like ethylene and ethanol. The breakthrough could play a significant role in the green transition by reducing global CO2 emissions
Researchers have created a reliable and efficient method to add fluorine to molecules, increasing pharmaceutical drug efficiency. The iron and sulfur-based reaction enables the release of fluorine from carboxylic acids and its incorporation into alkenes, common building blocks for drugs.
A research team developed a modularized catalytic system using covalent organic frameworks and commercial Cu2Cr2O5 to mimic enzyme active sites, achieving enhanced activity in transfer hydrogenation reactions. Hydrogen bonds between COFs and isopropyl alcohol facilitate dehydrogenation and promote hydride transfer.
Scientists have developed a new method to create catalysts for hydrogen fuel cells, making them cheaper and more efficient. The breakthrough could lead to the widespread adoption of clean energy and reduce greenhouse gas emissions.
Researchers at the University of Sydney have developed a new technique using liquid metals to replace energy-intensive chemical engineering processes. The method reduces greenhouse gas emissions by up to 15% and enables the production of high-energy fuels like propylene, crucial for various industries.
Researchers have developed catalysts that combine iridium and ruthenium, preserving their excellent attributes and improving activity and stability. The study also explores the importance of carefully selecting candidate materials and retaining superior properties even after nanostructure formation.
Researchers will investigate high-entropy materials to create more sustainable and durable catalysts. The goal is to improve the efficiency of electrocatalysis, paving the way for a new generation of catalysts and reducing the reliance on rare and expensive materials.
Kyushu University researchers have developed a new material that can store hydrogen energy for up to three months at room temperature, using an inexpensive element like nickel. This innovation could potentially reduce the cost of future compounds and contribute to the transition to alternative energy sources.
Researchers develop a new migration strategy that enhances CO2 reduction to CO via reverse water-gas shift reaction in Ru/(TiOx)MnO catalysts. The approach boosts catalytic activity by 3.3 times and improves H-spillover for efficient hydrogen transportation.
Researchers from BSC and CSIC have developed an artificial protein capable of degrading PET micro- and nanoplastics with efficiency between 5 and 10 times higher than current PETases. The protein can be used as filters to purify or recycle plastics, offering a potential solution to environmental pollution.
Researchers have created a hierarchically porous bifunctional catalyst that enhances the transport of reactants and products in zinc-air batteries. The pyrolysis-free strategy allows for improved durability and efficiency, making it an important step towards commercializing this technology.
Researchers have created biobased polyesters with superior mechanical properties, exceeding those of polyethylene and polypropylene. The new material can be easily recycled and exhibits increased tensile strength and elongation at break with molecular weight.
Researchers at NUS developed a new class of heterogeneous geminal atom catalysts promoting sustainable manufacturing processes for fine chemicals and pharmaceuticals. The novel catalyst improves reaction efficiency, selectivity, and recyclability.
Researchers at UTSA have been awarded a grant to develop a new technology that converts carbon dioxide into a raw material for producing chemical products. The project has the potential to create a productive area of catalysis research and reduce greenhouse emissions.
Researchers at Lund University have demonstrated a method for converting isopropanol into hydrogen using a solid catalyst, paving the way for a liquid fuel that can be delivered at a pump. The process has the potential to reduce greenhouse gas emissions and could be used in larger vehicles such as buses and aircraft.
A new electrochemical route converts N2 and O2 in air to HNO3 with high efficiency, avoiding traditional high-temperature processes. The process produces 141.83 μmol·h−1·g−1 of HNO3 productivity.
A team of scientists constructed micro-mesoporous metal-organic framework and carbon nanotube-based composite catalysts showing excellent oxygen reduction reaction electrocatalytic activity. The presence of MNx sites was found responsible for the enhanced electrocatalytic activity.
Researchers at Washington State University have made a groundbreaking discovery about the Fischer Tropsch process, a key step in converting coal, natural gas, and biomass into liquid fuels. The team found that the process exhibits self-sustained oscillations, which can be harnessed to enhance reaction rates and product yields.
Researchers have discovered a way to make solar hydrogen production economically viable by co-producing high-value chemicals like methylsuccinic acid. By coupling the photoelectrochemical (PEC) process with hydrogenation, the cost of hydrogen drops significantly, making it competitive with fossil gas.
Researchers developed direct conversion of methane with oxygen at room temperature using edge-rich MoS2 catalyst, achieving up to 4.2% conversion rate and 99% selectivity for C1 oxygenates. The unique binuclear molybdenum site facilitates O2 dissociation and activates C-H bond.
A team of researchers elucidated how hydrogen peroxide affects the degradation of a carbon-based catalyst named N-G/MOF. The study examined changes in the catalyst's elemental composition, major chemical bonds, crystal structure, and morphology under varying concentrations of hydrogen peroxide.
Researchers developed a new catalyst using bismuth selenide, a topological insulator, to synthesize organoureas at room temperature with almost 100% yield. The catalyst's unique properties allow for stable surface states and recyclability.
Researchers at Rice University developed a way to convert carbon dioxide into methane using copper-based catalysts. The method relies on electrolysis and involves modifying the distances between copper atoms in polymer templates, which improves the chemical conversion rate.
Researchers investigate the impact of cathode catalyst layer platinum loading on PEMFC electrode-membrane assembly durability. Low Pt content impairs oxygen reduction activity but doesn't affect degradation mechanisms.
Scientists have introduced a novel approach to change the shape of azobenzenes using visible light, enabling efficient and practical applications. The new supramolecular complex, called DESC, harnesses the power of red wavelengths to prompt molecular transformations.
Researchers have successfully developed a catalytic system to efficiently synthesize beta-lactam structures using abundant hydrocarbons as raw materials. The new catalyst eliminates the need for auxiliary attachment and removal, reducing the synthesis process from approximately eight steps to three steps.
Zeolite-encapsulated metal catalysts show improved hydrogen-related catalytic reactions due to confinement effect, reducing sintering and leaching. Advanced characterization techniques are used to study fine structure of metal sites, enabling better understanding of catalytic performance.
Scientists at Chiba University developed novel ligands for transition metal complex photocatalysis, successfully catalyzing specific photoreactions like transfer hydrogenation. The newly designed ligands allow platinum complex to catalyze reactions in the presence of visible light, streamlining industrial processes.
A UH research team is developing innovative chemical processes to transform plastic waste into useful materials, aiming to create new ways to reuse and recycle polyolefins. The project seeks to produce durable thermoset materials that can be recycled multiple times, reducing environmental impact and promoting a circular plastics economy.
A research team at City University of Hong Kong has developed a highly efficient electrocatalyst that enhances hydrogen generation through electrochemical water splitting. The catalyst, composed of transition-metal dichalcogenide nanosheets with unconventional crystal phases, exhibits superior activity and stability in acidic media.
A novel method to obtain acetone has been developed by a scientific collaboration between researchers in Brazil and Germany, using only light and photoactive iron chloride. The process is direct, safer, and cheaper than traditional methods, with fewer stages and no high temperatures or flammable intermediaries.
Researchers at USTC developed a new anode catalyst with high activity and high resistance to ammonia poisoning for AEMFC. The Cr-doped MoNi4 catalyst showed significant improvement over traditional Pt/C catalysts, maintaining peak power density under 10 ppm NH3.