Articles tagged with Photocatalysis
Researchers have developed a novel photocatalyst system that enables the production of syngas from methane steam reforming under atmospheric pressure. The system harnesses sunlight to split methane and water into hydrogen and carbon monoxide, forming syngas.
Researchers developed new supramolecular and polymeric organic photocatalytic systems to enhance light utilization efficiency and mineralization under solar light. The new system combines in situ H2O2 generation with in situ Fenton reaction, achieving high-flux mineralization under visible light without additional oxidants.
Researchers have created a reliable and efficient method to add fluorine to molecules, increasing pharmaceutical drug efficiency. The iron and sulfur-based reaction enables the release of fluorine from carboxylic acids and its incorporation into alkenes, common building blocks for drugs.
The study reveals sizeable variations and instabilities in electron energies for freshly cleaved MoS2 surfaces, but also shows that atomic hydrogen treatment can effectively neutralize these effects. The findings have potential applications in electronics, photonics, sensors, and catalysis.
Researchers have developed a dinuclear ruthenium complex that efficiently reduces CO2 to carbon monoxide with over 99% selectivity. The catalyst's self-photosensitizing properties enhance its stability under reaction conditions, allowing it to drive the CO2 reduction process even at low CO2 concentrations.
Researchers at Drexel University developed a titanium oxide material that can break down two common dye pollutants in water under visible light. The material reduced rhodamine 6G and crystal violet concentrations by 90% and 64%, respectively, in just 30 minutes.
Researchers have developed a hybrid silicon photocatalyst that efficiently produces hydrogen and high-value compounds using solar power. The non-toxic catalyst achieves an impressive rate of 14.2 mmol gcat−1 h−1, significantly higher than conventional silicon photocatalysts.
Researchers create process to recycle polypropylene, polyethylene and polystyrene plastics into chemical ingredients useful for energy storage. The new method uses LEDs and a catalyst, reducing greenhouse emissions compared to traditional recycling processes.
Researchers develop a simple, low-cost molybdenum complex for photocatalysis and photon upconversion, overcoming the limitations of expensive precious metal complexes. The complex shows excellent photostability and outperforms traditional compounds in some cases.
Researchers developed a heterogeneous photocatalytic system using cadmium sulfide nanosheets to realize borylation reactions involving N-heterocyclic carbene boranes (NHC-BH3). The process enables the synthesis of high-value transformations under room temperature and light conditions.
Researchers developed a new type of photocatalyst harnessing the visible portion of sunlight spectrum. The photocatalyst achieved high photo-to-chemical conversation efficiency and was found to be extremely stable under various conditions, including high temperatures and different pH levels.
A joint research team from City University of Hong Kong and collaborators developed a stable artificial photocatalytic system that mimics natural chloroplasts to convert carbon dioxide into methane, a valuable fuel, very efficiently using light. The new system achieved a highly efficient solar-to-fuel efficiency rate of 15%, surpassing...
Researchers have developed novel photocatalysts using layered metal-organic frameworks that exhibit improved charge separation properties. These materials are able to efficiently extract charges without structural defects, enabling record values in photocatalytic hydrogen production under visible light.
Prof. Dr. Marta Litter takes over as Editor-In-Chief of Journal of Photocatalysis, bringing her extensive expertise and experience to lead the journal into a new era of excellence. Her research on heterogeneous photocatalysis and iron-based nanomaterials has led to over 250 scientific publications.
Researchers found a solid deposited from ammonia and methane plasma can catalyze reactions to produce early biomolecules, such as imines, using sunlight. Nitrogen-doped graphite was used as the catalyst in these reactions.
Recent research reviews highlight the benefits of metal sulfides in photocatalysis, including enhanced stability through heterojunction formation. Various synthesis methods are discussed, along with applications in simultaneous redox reactions and environmental remediation.
An international team of chemists has successfully used structural editing to insert a four-membered molecular ring into an aromatic ring, creating a complex bicyclic ring system. The new process utilizes visible-light photocatalysis, providing environmentally friendly and atom-economical conditions.
Researchers at KAUST have developed a simple technique to create highly porous organic polymers, known as poly(aryl thioether), for applications in photocatalysis and optoelectronics. The material exhibits high surface area and tunable porosity, making it suitable for removing organic micropollutants and toxic mercury ions from water.
A team of researchers at Münster University has developed a photocatalytic process to split water into hydrogen and oxygen under mild reaction conditions. The process uses triaryl phosphines to activate water, enabling the easy transfer of hydrogen atoms to various compounds.
Researchers at KIT have developed highly efficient photoreactor panels that can be inserted into inexpensive modules for mass production of hydrogen or fuels. The technology could make the use of fossil energy carriers superfluous and provide a climate-neutral alternative, with costs estimated to be around $22 per square meter.
A team of researchers from China and the UK has developed new ways to optimise the production of solar fuels by creating novel photocatalysts. These photocatalysts, such as titanium dioxide with boron nitride, can absorb more wavelengths of light and produce more hydrogen compared to traditional methods.
A team of Japanese researchers has successfully developed a recycling photoreactor that enables the synthesis of optically pure compounds with high yields, achieving an optical purity of 98-99%. The system uses a two-step rapid photoracemization process and can produce enantiomerically pure chiral sulfoxides in yields higher than 80%.
Researchers at Ritsumeikan University demonstrate quasi-reversible displacement of organic ligands on nanocrystal surfaces under visible light irradiation. This finding opens up new avenues for enhancing the tunability and functionality of inorganic materials with aromatic molecules.
Researchers have developed a novel tin-based MOF that can selectively reduce CO2 to formate in the presence of visible light, achieving high selectivity and quantum yield. The material, called KGF-10, was found to be efficient, precious-metal-free, and single-component.
Researchers developed a novel method for photocatalytic water splitting by regulating the built-in electric field of nitrogen-deficient polymeric carbon nitride (PCN) on polyhedral SrTiO3. This synergistic approach improves charge transfer and light absorption, leading to enhanced overall water splitting efficiency.
A new strategy has been developed to enhance photocatalytic water oxidation by introducing a charge-transfer mediator. The mediator, partially oxidized graphene, reduces charge recombination and prolongs the lifetime of photogenerated charges.
A new type of floatable photocatalytic platform composed of hydrogel nanocomposites efficiently proceeds hydrogen evolution reaction. The platform exhibits clear advantages over conventional systems, including efficient solar energy conversion and easy gas diffusion.
Scientists at the National University of Singapore have developed a new method for synthesizing organosilanes using eosin Y, a low-cost and readily available dye molecule. This enables stepwise customised functionalisation of multihydrosilanes to access fully substituted silicon compounds.
By doping liquid crystals with azobenzene molecules, researchers can induce reversible changes in thermal conductivity under ultraviolet light. This breakthrough opens up new possibilities for designing materials with tunable thermal conductivity to address challenges in microelectronics.
Recent advances in catalytic methane oxidation via thermocatalysis and photocatalysis demonstrate promising results for environmental remediation. The development of efficient catalysts, improved reactor designs, and fundamental studies on surface chemistry are key findings.
Researchers at Tokyo Institute of Technology developed a novel visible light-driven single transition metal catalyst that combines high light harvesting abilities and broad applicability. The SFI-Rh(I) complexes overcome previous limitations, enabling versatile photocatalytic reactions with increased stability.
Researchers have developed a practical method to generate green hydrogen using natural enzymes, which contain only earth-abundant elements. The new approach enables the efficient production of green hydrogen from sunlight, making it a promising solution for decarbonizing transportation and industries.
Researchers have developed a new simulation method to study polarons in 2D materials, which could lead to breakthroughs in OLED TVs and hydrogen fuel production. The study uses quantum mechanical theory and computation to determine the fundamental properties of polarons in 2D materials.
Researchers synthesized a new orthorhombic Sn3O4 polymorph with a narrower bandgap, indicating higher efficiency for visible light absorption. The discovery is significant for photocatalytic reactions such as water splitting and CO2 reduction.
Researchers have successfully developed chemically stable, tunable-bandgap 2D nanosheets from perovskite oxynitrides, opening new possibilities for sustainable technologies such as photocatalysis, electrocatalysts, and electronics. The nanosheets exhibit superior proton conductivity and excellent photocatalytic activity.
Researchers at Oregon State University have developed a dual-purpose catalyst that can both purify herbicide-tainted water and produce hydrogen. The catalyst, derived from metal-organic frameworks, shows promise in tackling global water pollution and provides a sustainable alternative to conventional hydrogen production methods.
Researchers propose a 'C-C bond-first' strategy to convert biomass into liquid hydrogen carriers, releasing H2 on site. The approach prioritizes C-C bond breaking for high photocatalytic hydrogen production and storage.
Researchers have developed a novel technique to produce hydrogen peroxide without releasing carbon dioxide, reducing greenhouse gas emissions. The method uses photocatalysis and carbon nitride as a catalyst, making it more cost-effective and environmentally friendly.
Researchers at City University of Hong Kong have developed a lead-free perovskite photocatalyst for highly efficient solar energy-to-hydrogen conversion. The study uncovers the interfacial dynamics between halide perovskite molecules and electrolytes, enabling better photoelectrochemical hydrogen generation.
Researchers at Rice University have developed a photochemical process that simplifies the manufacture of essential precursors for drugs and agricultural chemicals. By illuminating reagents with visible light, they can form diazides in conditions far gentler than current industrial processes.
Researchers from City University of Hong Kong and Australia developed a new method to enhance charge mobility in metal oxide catalysts, leading to improved water splitting efficiency. The method involves phosphorus doping, which reduces energy losses and increases charge separation efficiency.
Researchers at HKU-CAS Joint Laboratory have developed a protonation process to enhance the efficiency of photocatalysts in generating hydrogen using visible solar light. The discovery could lead to more efficient and stable solar energy utilization, paving the way for 'net-zero' green hydrogen production.
Researchers have developed a metal-free photon upconversion system that transforms readily available visible light into UVB photons, enabling sustainable photochemical processes. The breakthrough enables efficient generation of high-energy UV photons without relying on mercury lamps or other inefficient alternatives.
Researchers have discovered that nanodiamonds can emit solvated electrons in water when exposed to visible light, a crucial step towards using them as photocatalysts. This discovery could lead to the development of inexpensive and metal-free processes for converting CO2 into valuable hydrocarbons or converting N2 into ammonia.
The new catalyst uses energy from light to convert ammonia into clean-burning hydrogen fuel, breaking the need for heat and potentially reducing greenhouse gas emissions. The discovery paves the way for sustainable, low-cost hydrogen production locally rather than in massive centralized plants.
Scientists have recorded photocatalysis charge separation processes experimentally on Cu2O particles, revealing rapid electron transfer and slower hole trapping, enabling better understanding of photocatalytic water splitting limitations. The technique allows for spatiotemporal imaging of charge transfer in photocatalyst particles.
Rice University engineers have developed a method to convert hydrogen sulfide into high-demand hydrogen gas and sulfur in a single step using gold nanoparticles. The process gets all its energy from light, offering a cost-effective alternative to traditional remediation methods.
Scientists have revealed the complex mechanisms behind charge transfer in photocatalyst particles, providing insights into designing more efficient photocatalysts. The research used multiple techniques to map the spatiotemporal evolution of charge transfers, showing that built-in electric fields and defects can aid in charge separation.
Researchers introduced a new method to analyze dynamic processes in photoelectrocatalytic reactions using carbon dots. The technique, TPV technology, provides detailed information on charge transfer and reaction kinetics, enabling the discovery of new catalytic properties.
A new titanium-based photocatalyst overcomes production inefficiencies in polyethylene furandicarboxylate (PEF), a biobased plastic replacement for PET. The catalyst increases efficiency by shifting light absorption to the visible range, reducing unwanted byproducts and requiring less UV light.
Scientists have found a novel structure in bismuth oxychloride, featuring a sextuple Bi-O layer composed of rock-salt and fluorite units, which enhances photocatalytic activity. This discovery could lead to improved hydrogen production material designs.
Researchers at Tokyo Institute of Technology have developed a novel, inexpensive catalyst that efficiently reduces carbon dioxide to formate under visible light. The new photocatalyst, KGF-9, boasts high performance and simplicity, with potential applications in reducing greenhouse gas emissions.
Researchers from Tokyo Institute of Technology have developed a surface-modified dye-sensitized nanosheet catalyst that can suppress undesirable back electron transfer and improve water splitting activity. This results in an efficient Z-scheme overall water splitting system with improved hydrogen production.
Chemists at the University of Münster developed a novel method for synthesizing complex organic molecules using visible light. The method produces biologically valuable β-amino acids, including a bifunctional oxime oxalate ester with both amine and ester functionalities.
Researchers have developed a method to convert methane into methanol under ambient conditions, reducing carbon dioxide emissions and paving the way for alternative fuels. The process uses photocatalysts and has potential to mitigate climate change by utilizing methane reserves.
Researchers created a composite of boron nitride and titanium dioxide that harnesses UV-A energy to break apart PFOA molecules in water, degrading 99% of the pollutant in less than three hours. The catalyst is more efficient than existing methods, offering new hope for removing PFOA from drinking water.
A new nanosheet-laminated photocatalytic membrane has been successfully developed by Kobe University researchers, demonstrating excellent water permeance and photocatalytic activity. The membrane's photocatalytic properties make it easier to clean, reducing fouling and increasing its potential for tackling global environmental issues.
A KAUST-led team developed organic semiconductor-based photocatalysts to store solar energy as clean hydrogen fuel. These catalysts can absorb visible light and generate long-lived charges, improving efficiency for hydrogen evolution.
Researchers developed yolk-shell nanocrystals containing metallic gold yolk with semiconductor shells, exhibiting high photocatalytic activity. The structures were synthesized using a sequential ion-exchange process and evaluated using XPS and PL spectroscopy, revealing electronic interactions favorable for photocatalysis.
Researchers anchored Mo2C nanoparticles onto MAPbI3 to enhance photocatalytic activity for hydrogen evolution. The composite exhibits superior performance, surpassing pristine MAPbI3 and Pt-deposited MAPbI3.